Chemistry Problem Set 1
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Questions and Answers

Consider the following reaction: 2SO2(g) + O2(g) ↔ 2SO3(g) Keq = 100 With the initial masses of 20 g SO2, 13 g O2, and 25 g SO3 in a 5.0 L container, which way will the reaction progress?

  • There is not enough information to determine which way the reaction will progress.
  • The reaction will progress to the right, favoring the products. (correct)
  • The reaction is already at equilibrium.
  • The reaction will progress to the left, favoring the reactants.
  • Consider the following reaction: cis-C2H2F2↔ trans-C2H2F2 Keq = 0.500. If 1 mol cis-C2H2F2 is mixed with 1 trans-C2H2F2 in a volume of 10-Liters at 623 Kelvin, what would happen to each of these isomers when the mixture is allowed to equilibrate? Note: Equilibrium mixtures of isomers typically contain more of the cis isomer than the trans isomer. What is the value of x (mol) in the table below?

    0.167

    Consider the following reaction: cis-C2H2F2↔ trans-C2H2F2 Keq = 0.500. If 1 mol cis-C2H2F2 is mixed with 1 trans-C2H2F2 in a volume of 10-Liters at 623 Kelvin, what would happen to each of these isomers when the mixture is allowed to equilibrate? What is the equilibrium concentration of [cis-C2H2F2] in the mixture in mol/L?

    0.117

    Two methanol-water mixtures are contained in separate flasks. The first mixture contains 40.0 wt% methanol and the second contains 70.0 wt% methanol. The product stream contains a mixture of methanol and water. If 200 g of the first mixture is combined with 150 g of the second, what is the mass of methanol in the product stream?

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    Two methanol-water mixtures are contained in separate flasks. The first mixture contains 40.0 wt% methanol and the second contains 70.0 wt% methanol. The product stream contains a mixture of methanol and water. If 200 g of the first mixture is combined with 150 g of the second, what is the mass of water in the product stream?

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    Study Notes

    Problem Set 1

    • Problem 1: A chemical reaction involves sulfur dioxide (SO2), oxygen (O2), and sulfur trioxide (SO3). Initial masses are given. Calculate whether the reaction will shift forward or backward to reach equilibrium.

    • Problem 2: A cis-trans isomerization reaction for C2H2F2 is given. An equilibrium constant (Keq) is provided. The reaction involves 1 mole of cis-C2H2F2 and 1 mole of trans-C2H2F2 in 10 liters and a given temperature. A table is provided to track the initial and equilibrium amounts of each isomer.

    • Problem 3: Two methanol-water mixtures with different compositions are combined. Calculate the mass and percentage composition (wt%) of the resultant mixture. Initial masses and percentages of each mixture are given.

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    Description

    This quiz covers key concepts in chemistry related to chemical reactions and equilibrium. It involves calculations for sulfur dioxide and sulfur trioxide reactions, cis-trans isomerization, and mixing compositions of methanol-water. Test your understanding of reaction dynamics and mixture composition.

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