Chemistry: Percentage Composition and Empirical Formula
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Questions and Answers

What is the ratio of the masses of oxygen that combine with a fixed mass of hydrogen to form water and hydrogen peroxide?

  • 3:1
  • 2:1
  • 1:1
  • 1:2 (correct)
  • What is the ratio of the volumes of hydrogen and oxygen that combine to form water vapor?

  • 2:1 (correct)
  • 3:2
  • 1:2
  • 1:1
  • What is the name of the law that states that if two elements can combine to form more than one compound, the masses of one element that combine with a fixed mass of the other element are in the ratio of small whole numbers?

  • Gay Lussac's law of gaseous volumes
  • Law of definite proportions
  • Law of multiple proportions (correct)
  • Law of conservation of mass
  • According to Gay Lussac's law of gaseous volumes, what is the volume of water vapor formed when 100 mL of hydrogen combines with 50 mL of oxygen?

    <p>100 mL</p> Signup and view all the answers

    What is the significance of Gay Lussac's discovery of the integer ratio in volume relationship?

    <p>It is the law of definite proportions by volume</p> Signup and view all the answers

    Study Notes

    Percentage Composition of Elements

    • The percentage composition of an element in a compound can be calculated using the formula: Mass % of an element = (mass of that element in the compound × 100) / molar mass of the compound
    • Knowing the mass percentage of various elements present in a compound can help determine its empirical formula, and further, its molecular formula if the molar mass is known

    Empirical and Molecular Formula

    • An empirical formula represents the simplest whole number ratio of various atoms present in a compound
    • A molecular formula shows the exact number of different types of atoms present in a molecule of a compound

    Law of Definite Composition

    • Also known as the Law of Constant Composition
    • States that a chemical compound always contains the same proportion of elements by mass, regardless of its source or method of preparation

    Law of Multiple Proportions

    • Proposed by Dalton in 1803
    • States that if two elements can combine to form more than one compound, the masses of one element that combine with a fixed mass of the other element are in the ratio of small whole numbers

    Gay Lussac's Law of Gaseous Volumes

    • Given by Gay Lussac in 1808
    • States that when gases combine or are produced in a chemical reaction, they do so in a simple ratio by volume, provided all gases are at the same temperature and pressure

    Calculation of Mass Percentage

    • To calculate mass percentage, take 100 g of the compound as the starting material
    • Divide the masses of each element by their respective atomic masses to get the number of moles of each element
    • Divide each mole value by the smallest number amongst them to get the ratio of elements
    • If the ratios are not whole numbers, convert them into whole numbers by multiplying by the suitable coefficient

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    Description

    Learn how to calculate the percentage composition of elements in a compound and determine its empirical formula based on the mass percent of the elements. Understand the process with the example of water (H2O).

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