Chemistry of Crude Oil and Hydrocarbons

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Questions and Answers

What is the primary purpose of fractional distillation in the context of crude oil?

  • To reduce the viscosity of crude oil
  • To convert crude oil into biomass
  • To separate crude oil into usable fractions (correct)
  • To refine water from oil

Which of the following best describes hydrocarbons?

  • Compounds containing only carbon atoms
  • Compounds made of hydrogen and carbon only (correct)
  • Compounds containing hydrogen and oxygen
  • Compounds made of nitrogen and hydrogen

What characterizes the homologous series in organic chemistry?

  • A series with decreasing boiling points
  • A collection of compounds made of nitrogen
  • A family of compounds with the same general formula (correct)
  • A group of compounds with no similar properties

In fractional distillation, what happens to the vapors of crude oil as they rise up the column?

<p>They condense at different levels based on boiling points (D)</p> Signup and view all the answers

What does viscosity refer to in the context of liquids?

<p>The ability of a liquid to flow (A)</p> Signup and view all the answers

What functional group is characteristic of alcohols?

<p>-O-H (B)</p> Signup and view all the answers

Which reaction describes the conversion of glucose to ethanol?

<p>Fermentation (A)</p> Signup and view all the answers

What is the primary characteristic of alkenes?

<p>They contain a carbon-carbon double bond. (B)</p> Signup and view all the answers

What is produced when a carboxylic acid reacts with carbonates?

<p>Carbon dioxide (A)</p> Signup and view all the answers

Which of the following explains why alcohols are considered good fuels?

<p>They have very little incomplete combustion. (D)</p> Signup and view all the answers

How can ethanol produced by fermentation be separated from the mixture?

<p>Using fractional distillation (B)</p> Signup and view all the answers

Which statement about carboxylic acids is true?

<p>They have a functional group of -COOH. (B)</p> Signup and view all the answers

Which of the following statements accurately describes the combustion of alkenes?

<p>It results in significant incomplete combustion. (B)</p> Signup and view all the answers

What process involves breaking down long hydrocarbon chains into shorter, more useful chains?

<p>Catalytic cracking (C)</p> Signup and view all the answers

Which statement describes complete combustion of hydrocarbons?

<p>It requires excess oxygen and produces carbon dioxide and water. (D)</p> Signup and view all the answers

What is the general formula for alkanes?

<p>CnH2n+2 (D)</p> Signup and view all the answers

What is formed during incomplete combustion of hydrocarbons?

<p>Water and carbon monoxide or soot (D)</p> Signup and view all the answers

Which of the following correctly identifies a characteristic of alkenes?

<p>Alkenes are unsaturated hydrocarbons. (C)</p> Signup and view all the answers

Why do boiling points of alkanes increase with chain length?

<p>Due to increased intermolecular forces. (B)</p> Signup and view all the answers

What is a disadvantage of incomplete combustion?

<p>It generates toxic carbon monoxide. (B)</p> Signup and view all the answers

Which functional group characterizes alkenes?

<p>C=C double bond (B)</p> Signup and view all the answers

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Study Notes

Crude Oil

  • Finite resource
  • Formed from ancient biomass, mainly plankton buried in mud
  • Mixture of hydrocarbons
  • Separated into fractions by fractional distillation
  • Used as fuels or feedstock for the chemical industry

Fractional distillation

  • Vapourised crude oil passed into the bottom of a column
  • Vapours rise up the column cooling and condensing
  • Hydrocarbons with different boiling points condense at different levels

Cracking

  • Long hydrocarbon chains are broken into shorter chains
  • Makes more useful products
  • Catalytic cracking – high temperature + catalyst
  • Steam cracking – high temperature + steam

Alkanes

  • Saturated hydrocarbons
  • General formula: CnH2n+2
  • Boiling point increases as the length of the chain increases

Alkenes

  • Unsaturated hydrocarbons
  • Contain a carbon-carbon double bond
  • General formula: CnH2n
  • Decolourise bromine water

Combustion of hydrocarbons

  • Complete combustion – excess oxygen – carbon dioxide and water formed
  • Incomplete combustion – limited oxygen – carbon monoxide and/or carbon formed

Alcohols

  • Functional group: -OH
  • Made by fermentation of glucose (sugar)
  • Conditions: warm + anaerobic (no oxygen)

Carboxylic acids

  • Weak acids
  • Functional group -COOH
  • Only slightly dissociated in water

### Reactions of carboxylic acids

  • React with carbonates to produce effervescence (bubbling) and carbon dioxide.
  • React with alcohols to produce esters.

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