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What mechanism does the dynamic release of borate ions (BO32-3) from the synthesized composite hydrogels follow?
What mechanism does the dynamic release of borate ions (BO32-3) from the synthesized composite hydrogels follow?
Which factor primarily contributes to the slow release of boron from the hydrogel composites?
Which factor primarily contributes to the slow release of boron from the hydrogel composites?
What is the role of borax in the preparation of CMC-g-cl-poly(AAm) hydrogel composites?
What is the role of borax in the preparation of CMC-g-cl-poly(AAm) hydrogel composites?
What technique was used to develop the boron delivery device in the hydrogel composites?
What technique was used to develop the boron delivery device in the hydrogel composites?
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Why is the use efficiency of boron considered low in agricultural practices?
Why is the use efficiency of boron considered low in agricultural practices?
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What is one significant characteristic of the borax-loaded hydrogel composites indicated by the characterization techniques used?
What is one significant characteristic of the borax-loaded hydrogel composites indicated by the characterization techniques used?
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Which of the following properties was NOT studied in the synthesized borax-loaded hydrogel composites?
Which of the following properties was NOT studied in the synthesized borax-loaded hydrogel composites?
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Which agricultural challenge does the development of boron delivery devices specifically address?
Which agricultural challenge does the development of boron delivery devices specifically address?
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What is the primary purpose of conducting strain tests on the borax loaded CMC-g-cl-poly(AAm) composites?
What is the primary purpose of conducting strain tests on the borax loaded CMC-g-cl-poly(AAm) composites?
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How is the weight of the swollen BSAPCs calculated during the swelling investigation?
How is the weight of the swollen BSAPCs calculated during the swelling investigation?
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What parameters are primarily used to calculate the grafting yield (Gy) of the BSAPCs?
What parameters are primarily used to calculate the grafting yield (Gy) of the BSAPCs?
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Which mechanism is predominantly responsible for the release of water in the borax loaded CMC-g-cl-poly(AAm) composites?
Which mechanism is predominantly responsible for the release of water in the borax loaded CMC-g-cl-poly(AAm) composites?
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At what constant temperature are the BSAPCs kept for swelling equilibrium?
At what constant temperature are the BSAPCs kept for swelling equilibrium?
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What is the significance of using a controlled strain mode in the frequency sweep tests?
What is the significance of using a controlled strain mode in the frequency sweep tests?
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What role does MBA play in the synthesis of borax loaded CMC-g-cl-poly(AAm) composites?
What role does MBA play in the synthesis of borax loaded CMC-g-cl-poly(AAm) composites?
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Which equation is used to calculate the water absorption capacity (QH2O) of the BSAPCs?
Which equation is used to calculate the water absorption capacity (QH2O) of the BSAPCs?
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How does the incorporation of borax influence the mechanical properties of BSAPCs?
How does the incorporation of borax influence the mechanical properties of BSAPCs?
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Which factor is critical in determining the release kinetics of borate ions from BSAPCs?
Which factor is critical in determining the release kinetics of borate ions from BSAPCs?
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What is the implication of the mechanical properties comparison between BSAPC-E1 and BSAPC-E4?
What is the implication of the mechanical properties comparison between BSAPC-E1 and BSAPC-E4?
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What kind of synthesis is depicted in the schematic diagram provided for the polymer composites?
What kind of synthesis is depicted in the schematic diagram provided for the polymer composites?
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Which characteristic is primarily influenced by the loading of borax in the BSAPC composites?
Which characteristic is primarily influenced by the loading of borax in the BSAPC composites?
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What can be inferred about the FT-IR spectra of BSAPC-E3?
What can be inferred about the FT-IR spectra of BSAPC-E3?
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Which composite demonstrates the lowest elasticity value according to the data provided?
Which composite demonstrates the lowest elasticity value according to the data provided?
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What does the synthesis process of BSAPC involve, according to the schematic?
What does the synthesis process of BSAPC involve, according to the schematic?
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Study Notes
Borax Loaded CMC-g-cl-poly(AAm) Composites
- Borax loaded CMC-g-cl-poly(AAm) composites were synthesized by in situ grafting of acrylamide (AM) onto sodium carboxymethyl cellulose (NaCMC) in the presence of borax.
- The composites were prepared using free radical polymerization, where AM, MBA, APS, and borax were dissolved in distilled water.
- The grafting yield (Gy) and grafting efficiency (Ge) were calculated to characterize the composites synthesis process.
- Composites with higher borax content showed greater mechanical toughness, indicated by higher E values and higher r values.
Swelling Investigation
- Swelling investigations were conducted using accurately weighed BSAPCs (0.1 g, particle size < 63μm) immersed in distilled water at 30°C.
- The water absorption capacity (QH2O) was calculated using the equation: QH2O = (We - Wx)/Wx
- Here, Wx represents the weight of xerogel or BSAPCs in glassy state, while We denotes the weight of swollen BSAPCs at equilibration.
Characterization by FT-IR and XRD
- FT-IR spectroscopy revealed the presence of characteristic bands related to borate ion (BO32−3), indicating successful loading of borax in the composite matrix of BSAPCs.
- This suggests that partial in situ hydrolysis of borax occurs during the polymerization reaction.
- XRD and FT-IR analysis confirmed the successful loading of borax in the BSAPC matrix and the formation of BO32−3.
Viscoelastic Properties
- Viscoelastic properties of borax loaded CMC-g-cl-poly(AAm) hydrogel composites were studied using dynamic shear rheometry.
- The viscoelastic properties were dependent on the borax content.
- Composites with higher borax content exhibited higher E values and higher r values, indicating increased mechanical toughness.
Boron Nutrient Release Behavior
- Boron (B) release from the synthesized composites followed a Fickian diffusion mechanism.
- Composites with higher mechanical strength resulted in slower release of B.
- The study aimed to develop a slow boron (B) delivery device using these composites.
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Description
This quiz covers the synthesis and properties of borax loaded CMC-g-cl-poly(AAm) composites. It includes methodologies for grafting acrylamide onto sodium carboxymethyl cellulose as well as swelling investigations to determine water absorption capacities. Prepare to explore the mechanical properties and the effects of borax content in the composites.