Chemistry Multiple Choice Quiz - Electrolysis
37 Questions
0 Views

Choose a study mode

Play Quiz
Study Flashcards
Spaced Repetition
Chat to Lesson

Podcast

Play an AI-generated podcast conversation about this lesson

Questions and Answers

Which of the following metals reacts with hot concentrated aqueous alkali to evolve hydrogen?

  • Copper
  • Sodium
  • Iron
  • Aluminium (correct)

Which of the following statements is TRUE about the electrolysis of dilute common salt?

  • Hydrogen is obtained at the cathode because hydrogen ions have a higher concentration than sodium ions.
  • Sodium ions have a lesser tendency to get reduced than hydrogen ions. (correct)
  • Sodium is solid and hydrogen is a gas.
  • Both A and C.

What is the reason for the observation that concentrated sulfuric acid reacts with ethanol to produce a gas that decolorizes bromine water?

  • Concentrated sulfuric acid is a strong oxidizing agent.
  • Concentrated sulfuric acid is a strong dehydrating agent.
  • Ethanol is a reducing agent.
  • All of the above. (correct)

Which of the following solutions can be used to chemically distinguish dilute HCl from dilute HNO3?

<p>FeSO4 solution (B)</p> Signup and view all the answers

Which of the following particles is responsible for electrical conductivity in a metal X that cannot displace hydrogen from dilute hydrochloric acid?

<p>Free electrons (D)</p> Signup and view all the answers

What is the balanced chemical equation for the reaction between excess ammonia and chlorine?

<p>$2NH_3 + 3Cl_2 \longrightarrow N_2 + 6HCl$ (D)</p> Signup and view all the answers

What is the name of the process used to manufacture nitric acid on a large scale?

<p>Ostwald process (A)</p> Signup and view all the answers

What is the balanced chemical equation for the first step in the Ostwald process?

<p>$4NH_3 + 5O_2 \longrightarrow 4NO + 6H_2O$ (D)</p> Signup and view all the answers

What is the chemical formula for the electrolyte used in the Hall-Héroult process for the extraction of aluminium?

<p>$Na_3AlF_6$ (A)</p> Signup and view all the answers

What is the balanced chemical equation for the reaction that occurs at the cathode during the electrolytic reduction of alumina?

<p>$Al^{3+} + 3e^- \longrightarrow Al$ (D)</p> Signup and view all the answers

What is the empirical formula of the inorganic compound with the following composition: Na = 14.31%, S = 9.97%, H = 6.22%, and O = 69.5%?

<p>$Na_2SO_4.10H_2O$ (B)</p> Signup and view all the answers

Which of the following is the correct observation when ethene gas is passed through bromine in CCl4?

<p>The bromine solution turns colorless. (A)</p> Signup and view all the answers

What do you observe when dilute sulfuric acid is added to a solution of lead (II) nitrate?

<p>A white precipitate is formed. (A)</p> Signup and view all the answers

Which of the following compounds will NOT conduct electricity when dissolved in water?

<p>Glycerol (A)</p> Signup and view all the answers

What is the general formula of the homologous series to which C4H6 belongs?

<p>C_nH_(2n-2) (D)</p> Signup and view all the answers

What is the atomic number of the element whose hydride contains 6 hydrogen atoms?

<p>16 (B)</p> Signup and view all the answers

Which of the following statements accurately describes the position of Carbon-13 (C-13) in the periodic table relative to Carbon-12 (C-12)?

<p>C-13 is placed at the same place as C-12. (B)</p> Signup and view all the answers

Which metal will give a white precipitate with NaOH solution, but no precipitate with NH4OH solution?

<p>Zinc (D)</p> Signup and view all the answers

Which of the following electronic configurations corresponds to the MOST non-reactive element?

<p>2 (A)</p> Signup and view all the answers

Which of the following statements accurately represents the relationship between the assertion (A) and the reason (R)?

Assertion (A): Halogens form uni-negative ions. Reason (R): After gaining one electron, halogens achieve an octet and stability.

<p>Both A and R are true, and R is the correct explanation of A. (C)</p> Signup and view all the answers

What is the ratio between the number of atoms in 2.24 liters of Nitrogen gas (N2) and 0.4 grams of Helium gas (He)? (Atomic weight of N = 14, He = 4)

<p>2:1 (C)</p> Signup and view all the answers

What is the percentage purity of the impure sample of Pb3O4 used in the experiment discussed?

<p>75% (D)</p> Signup and view all the answers

What is the anode reaction during the electrolysis of dilute NaCl solution using graphite electrodes?

<p>2Cl- --&gt; Cl2 + 2e- (C)</p> Signup and view all the answers

What is the anode reaction during the electrolysis of sodium argentocyanide solution using Ag electrodes?

<p>Ag --&gt; Ag+ + e- (C)</p> Signup and view all the answers

Which of the following is the balanced chemical equation for the preparation of methane in the laboratory?

<p>CH3COONa + Ca(OH)2 --&gt; CH4 + CaCO3 + H2O (D)</p> Signup and view all the answers

Which of the following structural formulas represents a chain isomer of the organic compound with the molecular formula C4H10?

<p>CH3CH(CH3)CH3 (D)</p> Signup and view all the answers

Which of the following is the balanced chemical equation for the reaction of ethanol and metallic sodium?

<p>2CH3CH2OH + 2Na --&gt; 2CH3CH2ONa + H2 (D)</p> Signup and view all the answers

Which of the following is a reason why a graphite anode is preferred over a platinum anode during the electrolysis of molten lead bromide?

<p>Graphite is less reactive than platinum and does not react with the products of electrolysis. (C)</p> Signup and view all the answers

Which of these statements about the solubility and electrical conductivity of carbon tetrachloride and sodium chloride is CORRECT?

<p>Carbon tetrachloride is insoluble in water and does not conduct electricity, while sodium chloride is soluble in water and conducts electricity. (C)</p> Signup and view all the answers

What should be connected to the negative terminal of the battery?

<p>Cathode (D)</p> Signup and view all the answers

Which reaction takes place at the cathode during electrolysis?

<p>Reduction reaction (D)</p> Signup and view all the answers

What type of bond is formed when a metal bonds with a nonmetal?

<p>Ionic bond (D)</p> Signup and view all the answers

Which of the following is a characteristic of hydrochloric acid?

<p>It is a strong acid (C)</p> Signup and view all the answers

What is the kind of reaction that converts an alkyne to an alkane?

<p>Hydrogenation reaction (B)</p> Signup and view all the answers

Which of the following compounds is soluble in excess ammonium hydroxide but insoluble in sodium hydroxide?

<p>Copper hydroxide (A)</p> Signup and view all the answers

Which method is used to concentrate an ore containing lighter impurities?

<p>Froth flotation (D)</p> Signup and view all the answers

What is an element with one electron in the valence shell likely to act as?

<p>Reducing agent (B)</p> Signup and view all the answers

Flashcards

Electrolysis of Dilute Salt Water: Why Hydrogen at Cathode?

Hydrogen is produced at the cathode during the electrolysis of dilute salt water because hydrogen ions have a stronger tendency to gain electrons (reduction) compared to sodium ions. This is based on their relative positions in the reactivity series, where hydrogen is more reactive than sodium.

Which Metal Reacts with Hot Alkali to Form Hydrogen?

Aluminum reacts with hot and concentrated alkalis, like sodium hydroxide (NaOH), to produce hydrogen gas. This reaction involves the formation of aluminate ions [Al(OH)4]- and the release of hydrogen. Other metals like sodium, iron, and copper don't show this behavior.

How to Distinguish Dilute HCl and HNO3?

Dilute hydrochloric acid (HCl) and dilute nitric acid (HNO3) can be distinguished using a solution of ferrous sulfate (FeSO4). FeSO4 reacts with HNO3 to form a brown ring, while it doesn't change color with HCl.

Conduction of Electricity in a Metal (HCl-Resistant)

In a metal that conducts electricity but doesn't react with dilute hydrochloric acid (HCl), free electrons are responsible for conducting electricity. This is because the metal's atoms form a metallic lattice with delocalized electrons that can easily move and carry charge.

Signup and view all the flashcards

Reaction of Concentrated Sulfuric Acid with Ethanol

Concentrated sulfuric acid (H2SO4) reacts with ethanol (C2H5OH) to form a gas called ethene (C2H4). Ethene decolorizes bromine water because it readily reacts with bromine and breaks its double bond. H2SO4 is not a drying agent in this case, it acts as a dehydrating agent.

Signup and view all the flashcards

What is connected to the negative terminal of a battery in an electrolytic cell?

The negative terminal of a battery is usually connected to the cathode in an electrolytic cell. This is because the cathode attracts positive ions, which are reduced (gaining electrons) during electrolysis.

Signup and view all the flashcards

What is connected to the positive terminal of a battery in an electrolytic cell?

The positive terminal of the battery is connected to the anode in an electrolytic cell. The anode attracts negative ions, which are oxidized (losing electrons) during electrolysis.

Signup and view all the flashcards

What is an electrolyte used for in an electrolytic cell?

Electrolytes are substances that conduct electricity when dissolved in water, like acids, bases, and salts. In electrolytic cells, electrolytes provide the ions needed for the chemical reactions at the electrodes.

Signup and view all the flashcards

What reaction occurs at the cathode in an electrolytic cell?

During electrolysis, the cathode is the electrode where reduction occurs. This involves the gain of electrons, leading to the formation of a new species with a lower oxidation state. In this case, a metal cation accepts electrons and is deposited as a neutral metal atom on the cathode.

Signup and view all the flashcards

What reaction occurs at the anode in an electrolytic cell?

The anode is the electrode where oxidation occurs during electrolysis, resulting in the loss of electrons. In this case, the anode will be made of the metal, which loses electrons to form a positively charged metal ion that dissolves into the electrolyte.

Signup and view all the flashcards

What is a universal indicator used for?

A universal indicator is a mixture of dyes that change color based on the pH of a solution. It helps identify the pH range of a solution quickly.

Signup and view all the flashcards

What is froth flotation used for?

Froth flotation is a process used to separate sulfide ores from impurities. It involves creating a froth that selectively attaches to the desired mineral and floats to the surface.

Signup and view all the flashcards

What type of reaction does ethane undergo with chlorine?

Ethane undergoes a substitution reaction with chlorine to form chloroethane. This means that a hydrogen atom in the ethane molecule is replaced by a chlorine atom.

Signup and view all the flashcards

Percentage Purity

The process of determining the percentage of a desired component in a mixture, often used in analyzing the purity of a substance.

Signup and view all the flashcards

Decomposition of Pb3O4 Equation

A chemical equation that represents the reaction involving the decomposition of lead(II,IV) oxide (Pb3O4) into lead(II) oxide (PbO) and oxygen gas (O2).

Signup and view all the flashcards

Anode Reaction (Dilute NaCl)

The reaction occurring at the positive electrode (anode) during the electrolysis of a dilute sodium chloride (NaCl) solution using graphite electrodes. This reaction involves the oxidation of chloride ions (Cl-) to chlorine gas (Cl2).

Signup and view all the flashcards

Anode Reaction (Sodium Argentocyanide)

The reaction occurring at the positive electrode (anode) during the electrolysis of a sodium argentocyanide solution using silver electrodes. This reaction involves the oxidation of silver ions (Ag+) from the complex ion to form solid silver metal (Ag).

Signup and view all the flashcards

Laboratory Preparation of Methane

A chemical reaction in the laboratory where methane (CH4) is produced from the reaction of a suitable reactant with a specific reagent.

Signup and view all the flashcards

Laboratory Preparation of Ethanol

A chemical reaction in the laboratory where ethanol (C2H5OH) is produced from the reaction of a suitable reactant with a specific reagent.

Signup and view all the flashcards

Laboratory Preparation of Ethyne

A chemical reaction in the laboratory where ethyne (C2H2) is produced from the reaction of a suitable reactant with a specific reagent.

Signup and view all the flashcards

Chain Isomerism

The ability of two or more organic compounds with the same molecular formula to have different arrangements of atoms within the molecule, leading to different chemical and physical properties. For example, butane (C4H10) can exist as n-butane and isobutane, which differ in their branching.

Signup and view all the flashcards

Dehydrating property of sulphuric acid

A chemical property of sulphuric acid indicating its ability to act as a dehydrating agent, removing water molecules from hydrated compounds like blue vitriol (CuSO4.5H2O) to form anhydrous copper sulphate (CuSO4).

Signup and view all the flashcards

Oxidizing property of sulphuric acid

A property of concentrated sulphuric acid reflecting its ability to act as a strong oxidizing agent, causing the oxidation of sodium nitrate (NaNO3) to nitric acid (HNO3) while itself getting reduced.

Signup and view all the flashcards

Distinguishing between CuO and MnO2

To distinguish between copper(II) oxide (CuO) and manganese dioxide (MnO2), add dilute hydrochloric acid (HCl) to both. CuO reacts with HCl to form a blue-green solution of copper chloride, while MnO2 does not react.

Signup and view all the flashcards

Differentiating dilute and concentrated H2SO4

Concentrated sulphuric acid is more viscous and heavier than dilute sulphuric acid. Add a small amount of sugar to a test tube containing both forms of acid - the sugar will char in the presence of concentrated acid, showing its strong dehydrating property.

Signup and view all the flashcards

Distinguishing between Na2CO3 and Na2SO3

Sodium carbonate (Na2CO3) reacts with dilute hydrochloric acid (HCl) to produce brisk effervescence of carbon dioxide, while sodium sulphite (Na2SO3) reacts with HCl to liberate sulphur dioxide, which has a pungent smell.

Signup and view all the flashcards

Steps of the Ostwald process

The Ostwald process involves three main steps: first, ammonia (NH3) is oxidized with air to form nitrogen monoxide (NO), which is then further oxidized to nitrogen dioxide (NO2), finally, NO2 is dissolved in water to form nitric acid (HNO3).

Signup and view all the flashcards

Reaction of ammonia and chlorine

Addition of excess ammonia (NH3) to chlorine (Cl2) results in a reaction that produces nitrogen gas (N2) and ammonium chloride (NH4Cl).

Signup and view all the flashcards

Reaction of Ethyne and Chlorine

The reaction of ethyne (C2H2) with chlorine (Cl2) in carbon tetrachloride (CCl4) leads to the formation of 1,1,2,2-tetrachloroethane (C2H2Cl4).

Signup and view all the flashcards

What is a non-electrolyte?

Glycerol is a non-electrolyte, meaning it does not conduct electricity when dissolved in water. This is because glycerol does not dissociate into ions in solution.

Signup and view all the flashcards

What type of hydrocarbon is C4H6?

C4H6 is an alkyne due to the presence of a triple bond between two carbon atoms. Alkyne formulas follow the general formula CnH2n-2.

Signup and view all the flashcards

How many hydrogen atoms are in the hydride of element 13?

The atomic number of an element is the number of protons in its nucleus. The element with atomic number 13 is Aluminum (Al). Aluminum forms a hydride, AlH3, with three hydrogen atoms per molecule.

Signup and view all the flashcards

Where is C-13 located relative to C-12 in the periodic table?

Isotopes of the same element have the same number of protons but differ in the number of neutrons. The position of an element in the periodic table is determined by its proton number. As C-13 and C-12 have the same number of protons, they occupy the same position on the periodic table.

Signup and view all the flashcards

Which metal forms a white precipitate with NaOH but not NH4OH?

Calcium forms a white precipitate with NaOH solution because calcium hydroxide (Ca(OH)2) is insoluble in water. However, calcium hydroxide is soluble in ammonium hydroxide (NH4OH) solution.

Signup and view all the flashcards

Which electron configuration indicates the most non-reactive element?

A highly stable element has a full outermost electron shell, achieving a noble gas configuration. The configuration 2,8,8,1 has one electron in its outermost shell, making it highly reactive. The configuration 2,8,8, is most stable and non-reactive as it has a complete outermost shell.

Signup and view all the flashcards

Why do halogens form uni-negative ions?

Halogens are located in group 17 of the periodic table and have 7 electrons in their outermost shell. They gain one electron to achieve a stable octet configuration, resulting in the formation of uni-negative ions.

Signup and view all the flashcards

What is the ratio of atoms in 2.24 litres of Nitrogen gas and 0.4g of Helium?

The ratio of atoms in a given volume of gas is proportional to the number of moles present. 2.24 L of Nitrogen gas at STP (standard temperature and pressure) is equal to one mole of Nitrogen, containing 6.022 x 10^23 molecules of Nitrogen. 0.4g of Helium at STP is equal to 0.1 moles, corresponding to 6.022 x 10^22 Helium atoms. The ratio of Nitrogen atoms to Helium atoms is 10:1.

Signup and view all the flashcards

Study Notes

Section A - Multiple Choice Questions

  • Question 1(i): In dilute common salt electrolysis, hydrogen is produced at the cathode due to a higher concentration of hydrogen ions than sodium ions. Sodium ions are less likely to reduce than hydrogen ions. Also, sodium is a solid and hydrogen is a gas.

  • Question 1(ii): An element reacting with hot concentrated aqueous alkali to release hydrogen is likely to be aluminium.

  • Question 1(iii): Distinguishing dilute hydrochloric acid from dilute nitric acid can be done using barium chloride solution.

  • Question 1(iv): Free electrons are responsible for electricity conduction in solutions when metal X doesn't displace hydrogen from hydrochloric acid.

  • Question 1(v): Concentrated sulphuric acid reacting with Ethanol produces a gas decolourising bromine water because it's a drying agent. Both assertions are true, and the reason correctly explains the assertion.

  • Question 1(vi): Glycerol is a non-electrolyte

  • Question 1(vii): C4H6 belongs to the homologous series of Alkynes.

  • Question 1(viii): The number of hydrogen atoms in the hydride of an element with atomic number 13 is 3.

  • Question 1(ix): Carbon-13 will be placed to the right of carbon-12 on the periodic table.

  • Question 1(x): A soluble salt of copper gives a white precipitate with NaOH but not NH4OH.

  • Question 1(xi): The electronic configuration 2,8,8,1 suits the least reactive element.

  • Question 1(xii): Halogens form uni-negative ions after gaining one electron to achieve an octet configuration and stability. Both assertion and reason are correct, and the reason explains the assertion

  • Question 2 (xiv): The catalyst used in the Haber process for ammonia production is finely divided iron.

  • Question 2 (xiii): The ratio between the number of atoms in Nitrogen gas (2.24 liters) and Helium gas (0.4g) is 3:1.

Question 2

  • Question 2(i): Copper electrorefinement involves connecting the impure copper to the positive terminal of a battery, a copper electrode to the negative terminal, a copper(II) sulfate solution as an electrolyte, and reactions during cathode and anode. At the cathode, copper ions reduce to copper metal (Cu2+ → Cu) and at the anode, copper metal oxidizes to copper ions (Cu → Cu2+).
  • Question 2(ii): A matching of terms in column A with column B is provided (this is not a summaryable detail).

Section B - Further Questions

Other Questions

  • (Additional questions are present, but a complete summary of all questions is too large for a concise note.)

Studying That Suits You

Use AI to generate personalized quizzes and flashcards to suit your learning preferences.

Quiz Team

Related Documents

Description

Test your understanding of electrolysis and acid-base reactions with this multiple-choice quiz. Each question explores critical concepts such as hydrogen production, element reactions, and distinguishing between acids. Perfect for refining your chemistry knowledge.

More Like This

Use Quizgecko on...
Browser
Browser