Chemistry Module 1

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Questions and Answers

What is the state of matter characterized by having no definite shape but a definite volume?

  • Solid
  • Plasma
  • Gas
  • Liquid (correct)

How much element B would combine with 12 g of element A if 4.0 g of A combine with 10 g of B?

  • 10 g
  • 12 g
  • 24 g
  • 30 g (correct)

According to the law of conservation of mass, the mass of a compound formed is _____ the sum of the masses of the individual elements.

  • Less than
  • Either greater than or less than
  • Greater than
  • Equal to (correct)

In which state does an electron in a hydrogen atom possess its lowest total energy?

<p>Ground state (C)</p> Signup and view all the answers

Who is generally credited with the idea of arranging the elements in the periodic table based on their properties?

<p>Mendeleev (D)</p> Signup and view all the answers

Which prefix is used to denote three atoms in a covalent compound?

<p>Tri- (A)</p> Signup and view all the answers

What is the correct name for the compound NH₃?

<p>Ammonia (B)</p> Signup and view all the answers

Which of the following compounds is named using the rules for binary acids?

<p>HCl (D)</p> Signup and view all the answers

What happens during an exothermic reaction?

<p>Energy is released. (B)</p> Signup and view all the answers

Which of the following is not a structural formula model?

<p>Covalent model (D)</p> Signup and view all the answers

What is the molecular formula for dinitrogen tetroxide?

<p>Nâ‚‚Oâ‚„ (D)</p> Signup and view all the answers

Which rule states that hydrogen only needs two electrons?

<p>Duet rule (D)</p> Signup and view all the answers

What is the primary purpose of Lewis Structures?

<p>To indicate bonding arrangements. (B)</p> Signup and view all the answers

What is sublimation?

<p>The process of a solid turning into a gas without becoming a liquid first (A)</p> Signup and view all the answers

Which separation method relies on solubility to distinguish mixtures?

<p>Chromatography (B)</p> Signup and view all the answers

Which scientist believed that all matter was made up of four fundamental elements?

<p>Aristotle (A)</p> Signup and view all the answers

Which of the following is a wrong postulate of Dalton's atomic theory?

<p>Each atom is indivisible and indestructible (C)</p> Signup and view all the answers

The Plum Pudding Model was proposed to describe what aspect of atoms?

<p>The distribution of electrons within an atom (A)</p> Signup and view all the answers

What discovery did J.J. Thomson contribute to atomic theory?

<p>The identification of electrons as cathode rays (B)</p> Signup and view all the answers

What is the significance of isoptopes regarding Dalton's atomic theory?

<p>They demonstrate that atoms can have different masses (B)</p> Signup and view all the answers

What occurs during crystallization?

<p>A dissolved solid forms crystals as the solution becomes more concentrated (D)</p> Signup and view all the answers

Which group contains the most stable elements with a complete outer electron shell?

<p>Group 18 (B)</p> Signup and view all the answers

What happens to atomic radius as you move down a group in the periodic table?

<p>It increases because the energy level is higher. (D)</p> Signup and view all the answers

What is the correct definition of a cation?

<p>An atom that loses electrons, resulting in a positive charge. (D)</p> Signup and view all the answers

Which type of elements tends to gain electrons to achieve stability?

<p>Nonmetals (D)</p> Signup and view all the answers

How does ionization energy change as you move from left to right across a period?

<p>It increases due to stronger nuclear attraction. (B)</p> Signup and view all the answers

Which series is classified as inner transition metals?

<p>Lanthanide and actinide series (A)</p> Signup and view all the answers

Which group in the periodic table is the most reactive?

<p>Alkali metals (B)</p> Signup and view all the answers

How do metalloids differ from nonmetals?

<p>Metalloids have properties of both metals and nonmetals. (B)</p> Signup and view all the answers

What is the charge of the cation in the ionic compound NaCl?

<p>+1 (D)</p> Signup and view all the answers

When writing the formula for Iron(III) Oxide, which of the following is true?

<p>The total charge from the cations and anions must equal zero. (C)</p> Signup and view all the answers

What should you do when using multiple polyatomic ions in a formula?

<p>Use parentheses for each polyatomic ion. (B)</p> Signup and view all the answers

Which statement accurately describes the role of delocalized electrons in metallic bonding?

<p>They move freely around metal atoms, holding them together. (C)</p> Signup and view all the answers

When naming the anion in an ionic compound, what suffix should be used?

<p>-ide (D)</p> Signup and view all the answers

Which formula represents a correctly balanced ionic compound?

<p>MgClâ‚‚ (C)</p> Signup and view all the answers

What is the correct way to write an ionic compound with more than one polyatomic ion?

<p>Use parentheses around the polyatomic ion followed by the subscript. (D)</p> Signup and view all the answers

What characterizes the electron sea model in metals?

<p>Electrons are loosely held, allowing free movement around the lattice. (D)</p> Signup and view all the answers

What is the maximum number of electrons that can occupy the n=3 energy level?

<p>18 (A)</p> Signup and view all the answers

Which of the following statements about Hund's rule is correct?

<p>Single electrons must occupy equal energy orbitals before pairing up (A)</p> Signup and view all the answers

In the context of electron configuration, what does the Pauli exclusion principle indicate?

<p>No more than two electrons can occupy the same orbital with opposite spins (A)</p> Signup and view all the answers

Which energy levels possess both s and p sublevels?

<p>n=2 and n=3 (A)</p> Signup and view all the answers

What is the significance of the noble gas notation in electron configuration?

<p>It provides a shorthand for writing electron configurations (B)</p> Signup and view all the answers

What is the total number of valence electrons in Strontium (Sr)?

<p>2 (D)</p> Signup and view all the answers

According to the periodic law, what occurs when elements are arranged in increasing atomic number?

<p>There is a periodic repetition of properties (A)</p> Signup and view all the answers

What is the electron configuration for Bromine (Br)?

<p>1s2, 2s2, 2p6, 3s2, 3p6, 4s2, 3d10, 4p6, 5s2 (B)</p> Signup and view all the answers

Flashcards

Sublimation

A process where a substance changes directly from a solid to a gas without becoming a liquid.

Electron Configuration

Arrangement of electrons in an atom at its ground state.

Aufbau Principle

Electrons occupy the lowest energy level available.

Chromatography

A technique for separating mixtures by taking advantage of different substances' speeds of movement through a stationary phase.

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Pauli Exclusion Principle

A maximum of two electrons can occupy each atomic orbital, only if they have opposite spins.

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Crystallization

A method for separating a solid from a liquid by dissolving the solid in a liquid, then allowing the liquid to evaporate, leaving behind crystals of the solid.

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Hund's Rule

Single electrons with the same spin must occupy each equal energy orbital before electrons with opposite spins can occupy the same energy orbital.

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Aristotle's Theory

Ancient Greek philosopher who believed matter was made of four elements: earth, water, air, and fire. He did not believe in atoms or empty space.

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Democritus's Atomic Theory

Greek philosopher who proposed that matter was made up of tiny, indivisible particles called atoms.

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Valence Energy Level

The outermost energy level of an atom.

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Valence Electrons

The electrons in the valence energy level.

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Dalton's Atomic Theory

Atomic theory proposed by John Dalton: Matter is composed of atoms, atoms of a given element are identical, atoms combine in specific ratios.

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Dalton's Atomic Theory - Incorrect Postulate 1

Atoms are not indivisible and indestructible. Atoms are made up of subatomic particles (protons, neutrons, electrons) and can be split in nuclear reactions.

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Group

Elements in the same vertical column of the periodic table.

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Dalton's Atomic Theory - Incorrect Postulate 2

Atoms of a given element are not always identical. Isotopes of the same element exist, differing in the number of neutrons and thus their mass.

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Period

Elements in the same horizontal row of the periodic table.

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Alkali Metals

Elements in Group 1 of the periodic table, known for their high reactivity due to their single valence electron.

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Alkaline Earth Metals

Elements in Group 2 of the periodic table, also highly reactive but less so than alkali metals, due to their two valence electrons.

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Inner Transition Metals

Elements that form the lanthanide and actinide series, located at the bottom of the periodic table. They have similar chemical properties.

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Halogens

Elements in Group 17 of the periodic table, highly reactive due to their strong tendency to gain one electron to achieve a stable octet.

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Noble Gases

Elements in Group 18 of the periodic table, known for their extremely low reactivity due to their complete octet of valence electrons, making them very stable.

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Atomic Radius

The distance between the nucleus of an atom and its outermost electron shell, essentially representing the atom's size.

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Ion

An atom that gains or loses electrons to achieve a stable electron configuration.

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Ionization Energy

The energy required to remove an electron from a gaseous atom, measured in electron volts (eV).

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Charge balance in ionic compounds

In a neutral compound, the total positive charge from cations equals the total negative charge from anions.

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What is a polyatomic ion?

A group of atoms that together have a net electric charge.

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How to write formulas with polyatomic ions

The subscripts in a chemical formula indicate the number of each type of ion needed to balance the charges.

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What are oxyanions?

Ions formed by a nonmetal and oxygen.

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What is the electron sea model?

Metals in their solid state form a lattice of tightly packed atoms, with a sea of delocalized electrons surrounding them.

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What is a metallic bond?

The strong attraction between positive metal ions and a sea of delocalized electrons.

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Why are valence electrons delocalized in metals?

Valence electrons are not bound to specific atoms in metals, but are free to move throughout the entire metal lattice.

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How does the electron sea model explain conductivity?

The ability of metals to conduct electricity is due to the free movement of delocalized electrons.

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Liquid State of Matter

A state of matter where the material has a definite volume but no definite shape. It can flow and take the shape of its container.

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Ground State of Hydrogen Atom

The total energy of the hydrogen atom is lowest when the electron is in its ground state. This state is the most stable state for the atom.

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Law of Conservation of Mass

The idea that matter cannot be created or destroyed, only changed from one form to another. The total mass of the reactants before a chemical reaction is equal to the total mass of the products after the reaction.

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Periodic Table Arrangement

The process of arranging elements based on their properties. This arrangement helps predict properties of elements and understand their relationships.

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Basic Research

The process of research focused on gaining fundamental knowledge and understanding about the natural world. It's often driven by curiosity and the desire to expand scientific knowledge.

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Molecular Compound

A chemical compound that consists of two or more atoms bonded together covalently.

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Naming Covalent Compounds

A system for naming covalent compounds using prefixes to denote the number of atoms of each element.

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Exothermic Reaction

A chemical reaction that releases energy into the surroundings, usually as heat or light.

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Endothermic Reaction

A chemical reaction that absorbs energy from its surroundings.

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Structural Formula

A visual representation of the arrangement of atoms in a molecule, showing the bonds connecting them.

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Lewis Structure

A method for drawing structures of molecules to show bonds and electron pairs, often used for covalent compounds.

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Octet Rule

A rule stating that atoms tend to gain, lose, or share electrons to achieve a stable electron configuration with eight electrons in their outermost shell.

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Study Notes

Module 1

  • Chemistry: The study of matter and its changes, including organic, inorganic, physical, analytical, and biochemistry.

  • Matter: Anything that takes up space.

  • Mass: A measurement of the amount of matter.

  • Science: Using evidence to develop testable explanations of natural phenomena.

  • Hypothesis: A testable expectation or prediction of a phenomena.

  • Theory: An explanation of a phenomena based on observations. It can be modified as new evidence arises.

  • Scientific Law: A relationship in nature supported by human experiments.

  • Pure Research: Aims to expand knowledge.

  • Applied Research: Focuses on solving specific problems.

  • Model: A visual or verbal explanation of data.

  • Units: A system of measurements.

  • Base Units: A system of fundamental measurements.

  • Derived Units: Units derived from the combination of base units. (e.g., meters per second).

  • Weight: A measure of the amount of matter and the gravitational force exerted on an object.

  • Time: Measured in seconds.

  • Length: Measured in meters.

  • Mass: Measured in kilograms.

  • Temperature: Measured in Kelvin.

  • Volume: The space occupied by an object, measured in liters.

Module 2

  • Density: Mass per unit volume (mass/volume).
  • Physical Properties: Properties observed without altering a substance (e.g., color, odor, density, mass, solubility, state, melting point, boiling point).
  • Chemical Properties: Properties observed when a substance undergoes a chemical change (e.g., reactivity, flammability, acidity/basicity, chemical composition).
  • States of Matter:
    • Solids: Have a fixed shape and volume. Particles are tightly packed.
    • Liquids: Have a definite volume but take the shape of their container. Particles move past each other.
    • Gases: Have no fixed shape or volume; they take the shape and volume of their container. Particles are widely dispersed.
    • Plasma: A highly energized ionized gas.

Module 3

  • Element: A pure substance that cannot be broken down into simpler substances by physical or chemical means.

  • Periodic Table: A table that organizes elements based on their atomic number and recurring chemical properties. Elements are arranged in horizontal rows (periods) and vertical columns (groups).

  • Compound: A substance composed of two or more elements chemically combined in a fixed ratio.

  • The Law of Definite Proportions: A compound has the same elements in the same proportions by mass, regardless of the sample size.

  • The Law of Multiple Proportions: When elements combine to form more than one compound, the ratios of the masses of one element that combine with a fixed mass of the other element will be small whole numbers.

  • Mixtures: A combination of two or more substances not chemically bonded,

  • Homogenous Mixture: The different substances are evenly mixed and not easily distinguishable (e.g., salt water).

  • Heterogeneous Mixture: Different substances are not evenly mixed, and the components are typically visible (e.g., sand and water).

  • Separation Techniques: Techniques used to separate substances in mixtures, such as filtration and distillation.

Module 4

  • Atomic Theory: Dalton's atomic theory: Elements are composed of extremely small particles called atoms, atoms of a given element are identical, atoms of different elements have different properties, in chemical reactions, atoms are combined, separated, or rearranged to form new substances, atoms cannot be divided, created, or destroyed.

Module 5

  • Cathode Rays: Streams of negatively charged particles emitted from a cathode in a vacuum tube (later identified as electrons).
  • Plum Pudding Model (Thomson): Atoms are made up of a positively charged sphere with negatively charged electrons embedded within it, like "plums in a pudding".
  • Rutherford's Gold Foil Experiment: Aimed at testing the plum pudding model. Showed, that atoms have a small, dense, positively charged nucleus at their center with negative electrons surrounding it in a largely empty space.
  • Rutherford's Nuclear Model: Atoms have a dense, positively charged nucleus containing most of the mass, with electrons orbiting the nucleus.
  • Alpha Particles: Particles consisting of two protons and two neutrons with a positive charge.
  • Helium Nucleus: Essentially an alpha particle.

Module 6

  • Bonding: Atoms form compounds by interacting in order to become more stable

  • Ionic Bonds: Electrons are transferred from one atom to another, forming positive and negative ions that are attracted to each other.

  • Covalent Bonds: Atoms share electrons to achieve a stable electron configuration.

  • Lewis Structures: Diagrams that show the arrangement of atoms and their bonds in a molecule.

Module 7

  • Bond Energy: The energy required to break or form a chemical bond.

  • Covalent Bond Stability: Bonds formed between atoms in order to attain a more stable electron configuration.

  • Atomic Orbitals: Regions in an atom where electrons are most likely to be found.

  • Quantum Numbers: Numbers that describe the properties of atomic orbitals.

Module 8 (Questions)

  • Periodic Law: The properties of elements are periodic functions of their atomic numbers.

  • Intensive Properties: Properties that are independent of the amount of matter (e.g., density, melting point, boiling point).

  • Extensive Properties: Properties that depend on the amount of matter (e.g., mass, volume, amount of energy).

  • Atom: The smallest unit of an element that maintains its chemical identity.

  • Electron Configuration: The arrangement of electrons in an atom.

  • Quantum: The minimum amount of energy a photon can have or be absorbed by an electron.

  • Periodic Groups: Columns of elements organized in the periodic table that share similar properties.

  • Periods: Rows of elements organized in the periodic table. Elements on a period share increasing atomic numbers.

  • Electron Affinity: The ability of an atom to accept an electron.

  • Electronegativity: The ability of an atom to attract electrons in a chemical bond.

  • Metallic Character: Tendency of an element to lose electrons.

  • Radioactive Elements: elements that decay by emitting radioactive particles.

  • Unstable Elements: Elements that decay and change over time.

  • Chemical Bond: The force of attraction that holds two or more atoms together. (28)

  • Distillation: Separation technique of substances with different boiling points based on their phase changes (liquids to gases).

  • Filtration: Separation technique using a barrier that allows liquids to pass through but traps solids (e.g., through a filter paper).

  • Homogenous Mixtures: Solutions that have uniform composition throughout (e.g., salt water).

  • Heterogeneous Mixtures: Mixtures where the components are not uniformly spread out (e.g., sand and water).

  • Polyatomic ions: A set of several atoms that act as a single unit (e.g., SO42- or hydroxide ion).

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