Questions and Answers
What can you say about Kb tables?
How do you find Kb from Ka?
Kb = (10^-14)/Ka
What is the relationship between pKa and pKb?
pKa + pKb = 14
If pKa = 10, what is the pKb of sodium phenoxide?
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How do you calculate the concentration of pyridine needed to produce a solution with a pH of 8?
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What does a 0.25M weak base solution with a pH of 9.25 indicate regarding its Kb?
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Which of the following indicates the strongest conjugate base?
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What can be said about the conjugate bases of strong acids?
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What can be said about the conjugate bases of weak acids?
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Where can you find the diagrams of the strength of acid-base pairs?
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Study Notes
Kb and Its Characteristics
- Kb tables are not commonly available despite every acid having a conjugate base, implying a relationship between Ka and Kb.
- Kb can be derived from Ka using the formula: Kb = (10^-14) / Ka.
Relationship Between pKa and pKb
- The relationship is defined by the equation: pKa + pKb = 14.
Example Calculations
- For sodium phenoxide with a pKa of 10:
- pKb is calculated as 14 - 10 = 4.
- Thus, Kb = 10^-4.
Concentration Calculations
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To find the concentration of pyridine needed for a pH of 8:
- Convert pH to [OH-]eq.
- Use the Kb reaction and known values to calculate Kb.
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A 0.25 M weak base with a pH of 9.25:
- Determine [OH-]eq from pH.
- Use the ICE table approach to calculate Kb.
Identifying Conjugate Bases
- The strongest conjugate base is found from the weakest acid:
- E (pKa = 10) has the highest pKa and lowest Ka, indicating it has the strongest conjugate base.
Conjugate Bases of Acids
- The conjugate bases of strong acids are very weak bases and generally incapable of acting as bases. This is due to their complete dissociation in solution.
- The conjugate bases of weak acids are categorized as weak bases.
Visual Aids
- Consult notes for diagrams illustrating the strength of acid-base pairs to enhance understanding.
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Description
Explore the critical relationship between Ka and Kb through our interactive flashcards. Learn how to calculate Kb from Ka and understand the connection between pKa and pKb. Perfect for chemistry students aiming to solidify their understanding of acid-base concepts.