Chemistry II Exam 3 Flashcards

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Questions and Answers

What is the conjugate acid of HCO3-?

H2CO3

What is the conjugate base of H2PO4-?

HPO4^2-

Which of the following is an Arrhenius acid? (Select all that apply)

  • NH2CH3
  • H2SO4 (correct)
  • LiOH
  • CH3CCl3

Which of the following is an Arrhenius base? (Select all that apply)

<p>LiOH (A)</p> Signup and view all the answers

Which of the following represents a conjugate acid-base pair from the equilibrium NH3(aq) + H2O(l) ⇌ NH4+(aq) + OH−(aq)?

<p>H2O and OH(−)</p> Signup and view all the answers

What is the conjugate base of HSO4−?

<p>SO4^(2)−</p> Signup and view all the answers

What is the conjugate acid of HPO42−?

<p>H2PO4(−)</p> Signup and view all the answers

Identify as an acid or a base: NH4+

<p>Acid</p> Signup and view all the answers

Identify as an acid or a base: HCl

<p>Acid</p> Signup and view all the answers

Identify as an acid or a base: hc2h3o2

<p>Acid</p> Signup and view all the answers

Identify as an acid or a base: KOH

<p>Base</p> Signup and view all the answers

Write a chemical equation for HCl(aq) showing how it is an acid according to the Arrhenius definition.

<p>HCl(aq) → H+(aq) + Cl−(aq)</p> Signup and view all the answers

Write a chemical equation for NH4+(aq) showing how it is an acid according to the Arrhenius definition.

<p>NH4+(aq) → H+(aq) + NH3(aq)</p> Signup and view all the answers

Write a chemical equation for KOH(aq) showing how it is a base according to the Arrhenius definition.

<p>KOH(aq) → K+(aq) + OH−(aq)</p> Signup and view all the answers

Write a chemical equation for HC2H3O2(aq) showing how it is an acid according to the Arrhenius definition.

<p>HC2H3O2(aq) + H2O(l) → H3O+(aq) + C2H3O2−(aq)</p> Signup and view all the answers

Which of the following solutions is a good buffer system? (Select all that apply)

<p>A solution that is 0.10 M HC2H3O2 and 0.10 M LiC2H3O2 (D)</p> Signup and view all the answers

What is the Henderson-Hasselbalch equation?

<p>pH = pKa + log[base]/[acid]</p> Signup and view all the answers

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Study Notes

Conjugate Acids and Bases

  • Conjugate acid of HCO3- is H2CO3.
  • Conjugate base of H2PO4- is HPO4^2-.
  • Conjugate base of HSO4- is SO4^2-.
  • Conjugate acid of HPO4^2- is H2PO4-.
  • Conjugate acid-base pair example: H2O and OH− from the ammonia equilibrium reaction.

Arrhenius Acids and Bases

  • H2SO4 is identified as an Arrhenius acid.
  • LiOH is an Arrhenius base.
  • Notable Arrhenius acids: HCl and HC2H3O2.
  • Notable Arrhenius bases: KOH.

Chemical Equations for Arrhenius Definitions

  • HCl dissociates in water: HCl(aq) → H+(aq) + Cl−(aq).
  • Ammonium ion acts as an acid: NH4+(aq) → H+(aq) + NH3(aq).
  • KOH dissociates in water: KOH(aq) → K+(aq) + OH−(aq).
  • HC2H3O2 in water: HC2H3O2(aq) + H2O(l) → H3O+(aq) + C2H3O2−(aq).

Buffer Systems

  • Effective buffer system example: 0.10 M HC2H3O2 and 0.10 M LiC2H3O2, containing a weak acid and its conjugate base.

Henderson-Hasselbalch Equation

  • Formula: pH = pKa + log[base]/[acid].

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