Chemistry Exam Study Guide

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Questions and Answers

How many valence electrons are present in K2S?

  • 16
  • 4
  • 2
  • 8 (correct)

What happens in an exothermic reaction?

  • Chemical bonds are broken without energy change
  • The temperature remains constant
  • Energy is absorbed from the surroundings
  • Energy is released into the surroundings (correct)

What type of bond is primarily formed between atoms with electron configurations 1s²2s² and 1s²2s²2p⁶3s²3p⁶?

  • Ionic bond (correct)
  • Metallic bond
  • Covalent bond
  • Hydrogen bond

Which molecular geometry corresponds to the molecule SO3?

<p>Trigonal planar (C)</p> Signup and view all the answers

Which statement about isotopes is true?

<p>Isotopes differ in the number of neutrons. (A)</p> Signup and view all the answers

What is the shared electron count between the carbon atoms in H2-C=C-H2?

<p>4 (B)</p> Signup and view all the answers

How many electrons can the fifth principal energy level hold when completely filled?

<p>50 (A)</p> Signup and view all the answers

What is an indication of a chemical change?

<p>Color change (A)</p> Signup and view all the answers

Which statement about electronegativity is correct?

<p>Se attracts bonding electrons more strongly than Te. (D)</p> Signup and view all the answers

What is the molecular shape of water (H2O)?

<p>Bent (B)</p> Signup and view all the answers

When an atom loses an electron, what charge does it become?

<p>Positive charge (B)</p> Signup and view all the answers

What type of forces hold AgNO3 together?

<p>Ionic forces (A)</p> Signup and view all the answers

What describes the major portion of an atom's volume?

<p>The electron cloud (D)</p> Signup and view all the answers

Which of the following compounds is considered an ionic compound?

<p>CuSO4 (A)</p> Signup and view all the answers

What is the main factor influencing the shape of a molecule?

<p>Repulsive forces between electron clouds (D)</p> Signup and view all the answers

Which of the following describes electron spin in orbitals?

<p>Electrons in the same orbital must have opposite spins. (C)</p> Signup and view all the answers

Which of the following segments on the heating curve represents liquid phase?

<p>Segment 3 (C)</p> Signup and view all the answers

What occurs when the pressure of a substance is increased at a given temperature?

<p>Condensation (C)</p> Signup and view all the answers

What happens to electrons when they move to a higher energy level?

<p>They absorb energy (B)</p> Signup and view all the answers

What is the strongest type of Van der Waals force?

<p>Hydrogen bonding (D)</p> Signup and view all the answers

In which phase change are intermolecular forces primarily overcome?

<p>Melting (A)</p> Signup and view all the answers

What is the oxidation state of mercury in HgS?

<p>+1 (A)</p> Signup and view all the answers

Which chemical bond occurs specifically between hydrogen and electronegative atoms like O, N, or F?

<p>Hydrogen bond (D)</p> Signup and view all the answers

What happens at the critical point in a substance's phase diagram?

<p>Liquid cannot exist above this point (C)</p> Signup and view all the answers

What charge do halogens in Group 17 typically gain when they form ions?

<p>-1 (A)</p> Signup and view all the answers

Which suffix is commonly used in naming ionic compounds when the nonmetal is the second listed element?

<p>-ide (A)</p> Signup and view all the answers

What is the correct total number of Y atoms in a compound that has the formula X3Y and contains 15 X atoms?

<p>45 (C)</p> Signup and view all the answers

Which of the following compounds is named using the Stock System?

<p>Tin (II) phosphate (B)</p> Signup and view all the answers

Which of the following describes binary molecular compounds?

<p>Compounds consisting of two elements (A)</p> Signup and view all the answers

How do chlorate and chlorite ions differ from each other?

<p>By the number of oxygen atoms (B)</p> Signup and view all the answers

When testing the odor of fumes, what is the correct method?

<p>Gently wave the fumes toward your nose and softly inhale (B)</p> Signup and view all the answers

In a neutral compound formed from ions, what must the total oxidation state equal?

<p>0 (C)</p> Signup and view all the answers

What is the weighted atomic mass of Bromine based on its isotopes X-79 and X-81?

<p>79.9 amu (C)</p> Signup and view all the answers

Which element has the highest electronegativity?

<p>Fluorine (A)</p> Signup and view all the answers

What characterizes the elements in Group 15 as you move down the group?

<p>They progress from nonmetals to metalloids to metals. (B)</p> Signup and view all the answers

Which of the following statements about nonmetals is true?

<p>Bromine is an example of a nonmetal that is solid and brittle. (B)</p> Signup and view all the answers

Which element is known to have the least tendency to lose electrons in Period 4?

<p>Bromine (B)</p> Signup and view all the answers

Which of the following correctly describes the grouping of elements on the periodic table?

<p>Elements in the same group have the same properties and valence electrons. (A)</p> Signup and view all the answers

What determines the organization of the periodic table?

<p>The increasing atomic number and number of protons. (B)</p> Signup and view all the answers

Which statement about electron configurations is true for the element in Period 5?

<p>It contains unpaired electrons in p orbitals. (A)</p> Signup and view all the answers

Flashcards

Endothermic Reaction

A chemical reaction where energy is absorbed from the surroundings, causing the temperature to decrease.

Exothermic Reaction

A chemical reaction where energy is released into the surroundings, causing the temperature to increase.

Elements

Substances that cannot be broken down into simpler substances by ordinary chemical means.

Physical Changes

Changes in matter that only alter its physical appearance, such as shape or state of matter, but do not change its chemical composition.

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Chemical Changes

Changes in matter that result in the formation of new substances with different chemical compositions.

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Atomic Composition

All atoms of the same element have the same number of protons, which defines their atomic number.

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Isotopes

Atoms of the same element that have different numbers of neutrons, resulting in different mass numbers.

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Electron Configuration

The arrangement of electrons in an atom's energy levels and sublevels, indicating the electron's energy and location.

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Weighted Atomic Mass

The weighted average of the masses of an element's isotopes, considering their relative abundance.

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Hund's Rule

States that each orbital within a subshell is singly occupied with one electron before any orbital is doubly occupied.

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Atomic Orbital

A region around the nucleus of an atom that can hold a maximum of two electrons with opposite spins.

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Nucleus

The dense, positively charged center of an atom containing protons and neutrons.

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Group (Periodic Table)

Elements belonging to the same vertical column of the periodic table, sharing similar chemical properties and the same number of valence electrons.

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Electronegativity Trend

Elements in the same period (horizontal row) of the periodic table have increasing electronegativity from left to right.

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Group 15 Trend

Elements in Group 15 (Nitrogen group) transition from nonmetallic properties to metallic properties as you move down the group.

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Valence Electrons

The number of electrons in the outermost energy level of an atom. These electrons participate in chemical bonding.

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Phase Diagram

A representation showing the phases of a substance under different conditions of temperature and pressure, illustrating transitions between solid, liquid, and gas states.

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Triple Point

The point on a phase diagram where all three phases of a substance coexist.

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Critical Point

The point on a phase diagram beyond which a gas cannot be liquefied by increasing pressure, regardless of temperature. Above it, gas and liquid are indistinguishable.

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Sublimation

A change in state from a solid directly to a gas.

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Evaporation

The process by which gas molecules escape from the surface of a liquid.

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Hydrogen Bonding

A strong type of intermolecular force occurring between molecules with H bonded to N, O, or F atoms. These create strong attractive forces between the molecules.

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Intermolecular Forces

The attractive forces between molecules, including hydrogen bonding, dipole-dipole interactions, and London dispersion forces.

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Intramolecular Forces

Forces that hold atoms together within a molecule.

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Metal-Nonmetal Reaction

A chemical bond formed between a metal and a nonmetal, where the metal atom loses electrons and becomes a positively charged ion.

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Electronegativity

A measure of an atom's ability to attract electrons towards itself in a chemical bond.

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Molecular Shape

The shape of a molecule determined by the repulsion between electron pairs in the outer shell of the central atom.

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Ionic Compound

A substance composed of ions held together by electrostatic attraction.

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Shared Electrons

The sharing of electrons between two atoms, resulting in a stable covalent bond.

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Stability

The tendency of atoms to gain or lose electrons to achieve a stable electron configuration, usually with eight valence electrons.

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Chemical Formula Definition

The chemical composition of a compound can be represented by a chemical formula which shows the types and numbers of atoms present in the compound.

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What is a binary molecular compound?

A binary molecular compound is a compound formed by the sharing of electrons between two elements.

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What is the stock system for naming?

The stock system utilizes Roman numerals in parentheses to indicate the charge of a transition metal ion.

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Neutral Compound Oxidation Number

The total oxidation numbers of all elements in a neutral compound must add up to zero.

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Compare Chlorate and Chlorite

Polyatomic ions containing chlorine and oxygen, like chlorate and chlorite, differ in the number of oxygen atoms they contain.

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What are polyatomic ions?

Polyatomic ions are groups of two or more atoms that carry an overall charge.

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What is oxidation number?

The oxidation number of an element in a compound indicates the number of electrons it has gained or lost to form a bond.

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When do we use the suffix 'ide'?

In naming compounds, the ending "ide" is often used when the nonmetal is the second element listed, such as oxide (O-2).

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Study Notes

Exam Study Guide

  • The study guide comprehensively represents the exam, though minor changes may occur.
  • Successful completion of the guide ensures exam success.
  • Resources include: Physical/Chemical Notepacket, Atomic Structure Notepacket, Periodicity Notepacket, Bonding Notepacket, Phase/IMF Notepacket, Nomenclature Notepacket, and Supplementary Packets.

Chemical Reactions

  • Endothermic Reactions: Absorb energy.
  • Exothermic Reactions: Release energy.

Elements and Substances

  • Elements: Substances that can't be decomposed by chemical means.
  • Examples of physical changes (matter): State change, cutting, crushing, dissolving.
  • Examples of chemical changes (matter): Decomposition, rusting, corrosion, combustion.

Atomic Structure

  • Atoms of the same element have the same number of protons.
  • Chlorine-35 isotope composition: 17 protons, 18 neutrons, 17 electrons.

Energy Levels and Sublevels

  • 5d¹⁰: Energy level 5, sublevel d, 10 electrons in orbitals.

Atomic Structure - General

  • The major portion of an atom's volume is empty space (electron cloud).

Atomic Number and Ions

  • Atomic number is equal to the number of protons.
  • Losing an electron creates a positively charged ion.

Chemical Bonding

  • Electronegativity: Increases across a period (except for the noble gases), and decreases down a group.
  • Metals vs. nonmetals The least ionic character is found with nonmetals.

Periodicity

  • Elements in the same group share similar chemical properties.
  • Fluorine (F) is the most active nonmetal.

Electron Configuration

  • Valence electrons: Determine the reactivity of an element.
  • Hund's rule: Each orbital is occupied by one electron before any is occupied by a second.
  • Orbitals with equal energy are singly populated with electrons before filling.

Orbital

  • Each orbital can hold a maximum of 2 electrons.
  • Chemical properties change across a period (row).
  • Electron behavior in different periods: Properties such as ionization energy and tendency to lose electrons change across a period (row).

Chemical Bonding

  • Ionic bonds: Electrostatic attraction between oppositely charged ions.
  • Metallic: Atoms held together in a metal by metallic bonding.
  • Covalent bonds: Electrons are shared.

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