Chemistry Exam Paper 10th Class
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Questions and Answers

Ammonolysis of ethyl chloride followed by reaction of the amine so formed with 1 mole of methyl chloride gives an amine that:

  • Does not react with Hinsberg reagent.
  • On reaction with nitrous acid, produces nitrogen gas.
  • Reacts with Hinsberg reagent to form a product soluble in an alkali.
  • Reacts with benzenesulphonyl chloride to form a product that is insoluble in alkali. (correct)
  • Which one of the following alkyl halides has the highest dipole moment?

  • $CH_3I$
  • $CH_3F$
  • $CH_3Br$
  • $CH_3Cl$ (correct)
  • Match the properties given in Column I with the metals in Column II:

    Column I (i) Actinoid having configuration [Rn] 5f 76d17s2 (ii) Lanthanoid which has 4f14 electronic configuration in +3 oxidation state. (iii) Lanthanoid which shows +4 Oxidation state

    Column II (A) Ce (B) Lu (C) Cm

  • (i)-(A), (ii)-(B), (iii)-(C)
  • (i)-(C), (ii)-(B), (iii)-(A) (correct)
  • (i)-(C), (ii)-(A), (iii)-(B)
  • (i)-(B), (ii)-(A), (iii)-(C)
  • Considering only the provided graph of boiling points of bromoalkanes and assuming a linear relationship with increasing carbon number within each series (primary, secondary and tertiary), what is the most plausible explanation for the observed trend?

    <p>Boiling point increases with increasing molar mass and decreases with increased branching due to decreased Van der Waals forces. (A)</p> Signup and view all the answers

    Considering haloalkanes, which of the following options correctly orders the compounds from lowest to highest boiling point?

    <p>1 = Bromomethane, 2= 2-Bromo-2-methylpropane, 3=2- Bromobutane, 4= 1-Bromobutane (A)</p> Signup and view all the answers

    For the reaction $R \rightarrow P$, the initial concentration of R is $4.62 \times 10^{-2}$ mol/L, and the rate constant $k = 2.31 \times 10^{-2}$ mol L$^{-1}$s$^{-1}$. What is the half-life of this reaction?

    <p>10 s (A)</p> Signup and view all the answers

    What products are obtained when $C_6H_5COOCOCH_3$ is treated with $H_2O$?

    <p>Benzoic acid and ethanoic acid (B)</p> Signup and view all the answers

    In the context of coordination compounds, if 'X' represents a coordination complex with the formula $[Co(NH_3)_4Cl_2]Cl$ and 'Y' represents the ratio of complex ions to counter ions, then which of the following options correctly identifies ‘X’ and ‘Y’?

    <p>X=$[Co(NH_3)_4Cl_2]^+Cl^-$, Y= 1:1 (A)</p> Signup and view all the answers

    Which polysaccharide consists exclusively of $\beta$-D-glucose monosaccharide units?

    <p>Cellulose (C)</p> Signup and view all the answers

    Flashcards

    Haloalkanes and Boiling Points

    2-Bromo-2-methylpropane has the highest boiling point among the listed haloalkanes.

    Half-Life Calculation

    The half-life of a reaction can be calculated using the formula related to rate constant k.

    Hydrolysis of Esters

    C6H5COOCOCH3 with H2O yields Benzoic acid and ethanol.

    β-D-Glucose in Polysaccharides

    Cellulose is made exclusively from β-D-glucose monosaccharides.

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    Paramagnetic Properties of Ions

    The order of increasing paramagnetism in ions is Ti3+ < Fe2+ < Cr3+ < Mn2+.

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    Ammonolysis of ethyl chloride

    A reaction where ethyl chloride reacts with ammonia to form an amine.

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    Dipole moment

    A measure of the polarity of a molecule due to the distribution of charge.

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    Actinoid configuration

    The arrangement of electrons in actinoids, typically in the 5f, 6d, or 7s orbitals.

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    Lanthanoid oxidation states

    Lanthanoids can exhibit +3 and +4 oxidation states based on electron removal.

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    Hinsberg reagent

    A chemical used to distinguish between primary, secondary, and tertiary amines.

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    Boiling points of bromoalkanes

    The temperature at which bromoalkanes transition from liquid to gas phase.

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    Noble gas configurations

    The electron configuration pattern of noble gases that other elements may mimic.

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    Lanthanoid +4 oxidation state

    Occurs when a lanthanoid loses an electron from the 4f orbital.

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    Study Notes

    General Instructions

    • The exam paper has 33 questions.
    • Some questions have internal choice.
    • Section A has 16 multiple-choice questions (1 mark each)
    • Section B has 5 short answer questions (2 marks each)
    • Section C has 7 short answer questions (3 marks each)
    • Section D has 2 case-based questions (4 marks each)
    • Section E has 3 long answer questions (5 marks each)
    • All questions are compulsory.
    • Using log tables and calculators is not permitted.

    Section A - Multiple Choice Questions

    • Question 1: Ammonolysis of ethyl chloride followed by reaction with methyl chloride forms an amine that reacts with Hinsberg reagent to form a product that is insoluble in alkali.
    • Question 2: CH3F has the highest dipole moment.
    • Question 3: Matching properties with metals: (i) Actinoid [Rn]5f76d17s2 matches to Cerium (Ce), (ii) Lanthanoid 4f14 in +3 oxidation state corresponds to Lutetium (Lu), (iii) Lanthanoid showing +4 oxidation state matches to Californium (Cm).

    Section B - Short Answer Questions (2 marks each)

    • Question 17: Nitrogen gas solubility decreases at temperatures above 293 K if the Henry's constant increases. Chloroform and Acetone form an azeotrope with a mole fraction of 0.339 for acetone, and a boiling point of approximately 60 °C. The soda bottle will go flat faster in Srinagar than Delhi due to lower atmospheric pressure. Sugar increases product shelf life by inhibiting microbial growth.
    • Question 18: IUPAC name: K[Cr(H2O)2(C2O4)2]H2O. Metal ion in hemoglobin is iron, in vitamin B-12 is cobalt.

    Section C - Short Answer Questions (3 marks each)

    • Question 22: Electrolysis of copper chloride on inert electrodes results in the formation of copper at the cathode and chlorine gas at the anode. Replacing concentrated copper sulphate with copper chloride would lead to chlorine gas production instead of oxygen.

    Section D - Case-Based Questions (4 marks each)

    • Question 29: Chemical reaction rate depends on reactant concentrations, temperature, and other factors. A mechanism is a series of elementary steps that lead to the overall reaction.

    Section E - Long Answer Questions (5 marks each)

    • Question 31: Purple compound used for bleaching is generally potassium permanganate.
    • Question 32: (i) Isomerism type: Coordination isomerism is possible, and structural formula is required. (ii) Ionic equations: reaction of acidified K2Cr2O7 with H2S or FeSO4
    • Question 33: In the HVZ reaction formic acid gives a positive test due to greater acidity while acetic acid does give the test but is weaker than formic acid. Alcohols are weaker acids than water with reactivity order: tert- > sec- > primary.

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    Prepare for your 10th class chemistry exam with this comprehensive quiz featuring multiple-choice, short answer, and long answer questions. Each section is designed to test your understanding of key chemical concepts and reactions. Make sure to tackle all questions to strengthen your knowledge!

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