Chemistry Exam 1 CH 1010 Fall 2022
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Chemistry Exam 1 CH 1010 Fall 2022

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Questions and Answers

Water is classified as which type of substance?

  • An atom
  • A compound (correct)
  • An element
  • A mixture
  • Can a solution of NaCl with a density of 1.05 g/mL separate ABS and PET plastics?

  • No, because both types would float.
  • No, because both types would sink.
  • Yes, because ABS sinks and PET floats. (correct)
  • Yes, because ABS floats and PET sinks.
  • What is the correct atomic mass of titanium in titanium tetrachloride (TiCl4) based on 1.86 × 10^24 molecules?

  • 28.41 amu
  • 50.94 amu
  • 47.87 amu (correct)
  • 48.00 amu
  • Which phase change does the depicted process represent at the particulate level?

    <p>Vaporization</p> Signup and view all the answers

    Which of the following statements is true regarding a sample of krypton and neon with equal moles?

    <p>Krypton has a greater mass than neon.</p> Signup and view all the answers

    In terms of atomic particles, which of the following correctly classifies the element with 17 protons, 18 neutrons, and 18 electrons?

    <p>Neutral atom, 0</p> Signup and view all the answers

    Which sample contains more atoms if a sample of carbon has the same mass as a sample of silicon?

    <p>Carbon sample has more atoms.</p> Signup and view all the answers

    Which type of electromagnetic radiation has the highest energy between gamma radiation and radio waves?

    <p>Gamma radiation has the highest energy.</p> Signup and view all the answers

    Which type of electromagnetic radiation has a shorter wavelength?

    <p>Ultraviolet</p> Signup and view all the answers

    If a sampled element has an abundance of 28.41% at 26 amu, what is most likely true regarding its stability?

    <p>It is likely stable due to relatively high abundance.</p> Signup and view all the answers

    What is the correct classification for Silicon?

    <p>Metalloid</p> Signup and view all the answers

    Which electromagnetic radiation would induce the photoelectric effect with rhodium metal (Φ = 7.98 × 10−19 J)?

    <p>Purple light (ν = 7.21 × 10^14 s−1)</p> Signup and view all the answers

    What is the mass of a sample of titanium tetrachloride that contains 1.86 × 10^24 molecules?

    <p>162 grams</p> Signup and view all the answers

    Which atomic particle classification does not apply to an atom with equal numbers of protons and electrons?

    <p>Anion</p> Signup and view all the answers

    What would be the maximum wavelength of light capable of inducing the photoelectric effect with ytterbium, given that the energy required is 254 kJ/mol?

    <p>553 nm</p> Signup and view all the answers

    What happens to the size of s orbitals as the principal quantum number (n) increases?

    <p>They increase in size</p> Signup and view all the answers

    What happens to the orbital energy as the azimuthal quantum number (l) increases for orbitals in the 4th shell?

    <p>It increases</p> Signup and view all the answers

    What type of electromagnetic radiation has the lowest frequency?

    <p>Infrared</p> Signup and view all the answers

    Which of the following metals is most likely to be a Main Group Non-Metal?

    <p>Sulfur</p> Signup and view all the answers

    How many unpaired electrons are found in the ground state electron configuration of the ion Ni3+?

    <p>1</p> Signup and view all the answers

    Which hydrogen atom transition involves the absorption of a photon with the lowest frequency?

    <p>3s → 4p</p> Signup and view all the answers

    In chromium (Cr), how many electrons are in the 4s subshell in the ground state electron configuration?

    <p>2</p> Signup and view all the answers

    If an element tends to form ions with a charge of (1−), how many valence electrons does a neutral atom of this element have?

    <p>5</p> Signup and view all the answers

    What can be predicted about the group of the periodic table where an element with a charge of (1−) is most likely found?

    <p>Group 15</p> Signup and view all the answers

    What is the quantum number set corresponding to the 4p orbital?

    <p>n = 4, l = 1</p> Signup and view all the answers

    What is the configuration notation for the ion formed when chromium loses three electrons?

    <p>[Ar] 3d³</p> Signup and view all the answers

    Which set of quantum numbers is consistent with the 3d orbital?

    <p>n = 3, l = 2</p> Signup and view all the answers

    Which element in Set I has the greatest affinity for an added electron?

    <p>Na</p> Signup and view all the answers

    Which element in Set II has a greater negative electron affinity?

    <p>Cl</p> Signup and view all the answers

    Which ion would you predict to have the smallest ionic radius?

    <p>Sr2+</p> Signup and view all the answers

    Which ion would you predict to have the largest ionic radius?

    <p>As3−</p> Signup and view all the answers

    Which element would you predict to have the smaller value for the third ionization energy, IE3?

    <p>P</p> Signup and view all the answers

    Which element would have a smaller third ionization energy in Pair II?

    <p>B</p> Signup and view all the answers

    Which of the following electrons subshells corresponds to the element with the lowest effective nuclear charge?

    <p>p subshell with empty occupancy</p> Signup and view all the answers

    Which phenomenon best explains the increasing ionic radius trend down a group in the periodic table?

    <p>Increasing number of electron shells</p> Signup and view all the answers

    Study Notes

    Water Properties and Definitions

    • Water is classified as a compound composed of molecules.
    • Smallest particles still considered water are molecules.

    Temperature Conversion

    • Temperature conversion from Celsius to Kelvin: 381 °C equals 654 K.
    • Report temperature in Kelvin to three significant figures.

    Density and Plastic Separation

    • Two types of plastic: ABS with density 1.15 g/mL and PET with density 1.35 g/mL.
    • A NaCl solution with density 1.05 g/mL will not separate the plastics as both will sink.

    Phase Change and Thermodynamics

    • Thermodynamic processes can be classified as endothermic (absorbing heat) or exothermic (releasing heat).

    Isotope Mass Average

    • Average atomic mass calculation involves isotopes:
      • 25 amu (13.25% abundance), 26 amu (28.41% abundance), and 28 amu.

    Mole and Sample Mass

    • Determine mass of titanium tetrachloride, TiCl4, containing 1.86 × 10^24 molecules.

    Element Classification

    • Elements can be classified as cations, anions, or neutral atoms based on subatomic particle counts.
    • Example: 17 protons, 18 electrons indicates a neutral atom.

    Electromagnetic Radiation

    • Higher energy corresponds to gamma radiation; shorter wavelength corresponds to ultraviolet radiation; lower frequency corresponds to X-rays.

    Photoelectric Effect

    • Energy required for photoelectric effect for ytterbium: 254 kJ/mol.
    • Maximum wavelength inducing this effect calculated in nm.

    Quantum Numbers

    • Accuracy in identifying quantum numbers is necessary for corresponding atomic orbitals.
    • Example combinations:
      • A: n = 3, l = 2
      • B: n = 1, l = 2

    Atomic Radius and Ionic Size

    • Comparison of atomic radius reveals that K has a larger radius than Na.
    • Ionic radius increases in the order of As3− < Sr2+ < Br− < Rb+.

    Ionization Energy

    • Predict lower ionization energy for P over Cl and B over Be.

    Useful Equations and Constants

    • Avogadro's number: NA = 6.0221 × 10^23.
    • One atomic mass unit: 1 u = 1 amu = 1.66054 × 10−24 g.
    • Fundamental equations include:
      • E = h⋅ν (Energy and frequency)
      • c = ν⋅λ (Speed of light relation)
      • φ = h⋅ν0 (Photoelectric work function)

    Answers to Sample Exam Questions

    • Answers include classification, calculations of temperatures, densities, and more based on accurate scientific principles.

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    Related Documents

    Fall2022-Exam 1.pdf

    Description

    This quiz focuses on introductory chemistry concepts covered in CH 1010. It includes questions about water's classification, significant figures, and basic terminology. Test your understanding of fundamental chemistry principles essential for your course.

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