Chemistry Chapter: Self-Ionization of Water
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Questions and Answers

What is the self-ionisation equation of water?

The self-ionisation equation of water is H₂O ↔ H⁺ + OH⁻.

What is the ionic product of water (Kw) at 25°C?

At 25°C, the ionic product of water (Kw) is 1 × 10⁻¹⁴.

How do you calculate pH from hydrogen ion concentration?

pH is calculated using the formula pH = -log₁₀[H⁺].

What is the pH of a solution with a hydrogen ion concentration of 7.1 x 10^-7 mol/L?

<p>The pH of that solution is approximately 6.15.</p> Signup and view all the answers

Define a neutral solution in terms of pH.

<p>A neutral solution has a pH equal to 7.</p> Signup and view all the answers

What is the equation to calculate pH from hydrogen ion concentration?

<p>pH = -log<del>10</del>[H^+^]</p> Signup and view all the answers

Calculate the hydrogen ion concentration when the pH of a solution is 3.7.

<p>[H^+^] = 1.995 x 10^-4^ mol/L</p> Signup and view all the answers

What differentiates strong acids from weak acids using the dissociation constant Ka?

<p>Strong acids have large K<del>a</del> values, while weak acids have small K<del>a</del> values.</p> Signup and view all the answers

Provide an example of a strong base and explain its characteristic.

<p>Sodium hydroxide (NaOH) is a strong base because it readily accepts protons.</p> Signup and view all the answers

Explain the relationship between strong acids and their conjugate bases.

<p>A strong acid has a weak conjugate base, such as HCl and Cl^-.</p> Signup and view all the answers

How does adding OH^- affect the equilibrium of the indicator reaction?

<p>Adding OH^- shifts the equilibrium to the left, favoring the reverse reaction and resulting in Colour 1 being seen.</p> Signup and view all the answers

What is the significance of the pH range for an indicator?

<p>The pH range indicates the interval over which the indicator changes color, allowing for effective monitoring of pH changes during titrations.</p> Signup and view all the answers

Describe the setup of a pH titration experiment.

<p>The setup includes a burette filled with a base, a beaker containing an acid and a magnetic stir bar, and a pH sensor connected to a computer to record pH changes.</p> Signup and view all the answers

What would you observe if H^+ is added to the indicator solution?

<p>Adding H^+ would react with OH^-, decreasing its concentration and shifting the equilibrium right, resulting in Colour 2 being seen.</p> Signup and view all the answers

How do indicators like methyl orange and phenolphthalein differ in terms of pH range and color change?

<p>Methyl orange has a pH range of 3-5, changing from red to yellow, while phenolphthalein has a range of 8-10, changing from colorless to pink.</p> Signup and view all the answers

What is the pH of a 0.04 M H2SO~4 solution?

<p>The pH is 0.097.</p> Signup and view all the answers

Calculate the pH of a 0.15 M NaOH solution.

<p>The pH is 13.18.</p> Signup and view all the answers

Identify the limitations of the pH scale.

<p>The pH scale is limited to 0.1-14, only applicable at 25°C, and does not work at extremely low concentrations.</p> Signup and view all the answers

How do you calculate the pH of a weak acid or weak base?

<p>You must know the dissociation constant (K<del>a</del> or K<del>b</del>) for the substance.</p> Signup and view all the answers

What is the formula for calculating the concentration of H^+ ions from a weak acid?

<p>[H^+] = \sqrt{K_a \times M_{acid}}.</p> Signup and view all the answers

Calculate the pH of a 0.1 M solution of methanoic acid with Ka of 2.1 x 10^-4.

<p>The pH is 2.34.</p> Signup and view all the answers

Describe the action of an acid-base indicator in a solution.

<p>An acid-base indicator changes color based on the pH of the solution.</p> Signup and view all the answers

What happens to an acid-base indicator when H^+ ions are added to the solution?

<p>Adding H^+ ions favors the reverse reaction, resulting in Colour 1 being seen.</p> Signup and view all the answers

Explain the role of indicators in acid-base titrations and provide an example.

<p>Indicators change color at a specific pH range, signaling the endpoint of a titration. For example, methyl orange is suitable for titrating a strong acid against a weak base.</p> Signup and view all the answers

What characterizes a strong acid when titrated against a strong base?

<p>A strong acid dissociates almost completely in water, resulting in a sharp increase in pH at the equivalence point of the titration.</p> Signup and view all the answers

Describe the pH change observed during the titration of a weak acid and a strong base.

<p>The pH rises gradually, becoming almost vertical around the equivalence point, indicating a significant change but not a sudden jump.</p> Signup and view all the answers

What is the significance of the conjugate acid-base pair?

<p>A conjugate pair consists of an acid and its corresponding base that differ by one hydrogen ion, indicating the reversible nature of acid-base reactions.</p> Signup and view all the answers

How does the strong dissociation of sulfuric acid differ from that of a weak monobasic acid?

<p>Sulfuric acid almost completely dissociates in water to produce more hydrogen ions, while a weak acid only partially dissociates.</p> Signup and view all the answers

Calculate the pH of a 0.5 M NaOH solution and explain your steps.

<p>pOH = -log10[OH⁻] = -log10(0.5) ≈ 0.3, thus pH = 14 - pOH = 14 - 0.3 = 13.7.</p> Signup and view all the answers

Why is it not possible to detect the endpoint in a titration of a weak acid with a weak base?

<p>The gradual pH rise does not yield a sudden change, making it difficult to pinpoint the endpoint with common indicators.</p> Signup and view all the answers

State the observed color change when a weak acid indicator is added to a strong base.

<p>The solution turns purple as hydroxide ions remove hydrogen ions from the indicator, shifting the equilibrium.</p> Signup and view all the answers

Study Notes

Self-Ionization of Water

  • Water conducts electricity when it contains dissolved ions.
  • Pure water has a very small current due to self-ionization.
  • Water self-ionizes as follows: H₂O → H⁺ + OH⁻
  • The concentration of H⁺ and OH⁻ ions in pure water is very small.
  • The equilibrium in the self-ionization reaction is strongly to the left.
  • The concentration of H₂O remains relatively constant.
  • Equilibrium constant (K) can be written as: K = [H⁺][OH⁻]/[H₂O]
  • Since [H₂O] is effectively constant, the expression can be simplified to: Kw = [H⁺][OH⁻]
  • At 25°C, Kw = 1 x 10⁻¹⁴
  • To find [H⁺] given Kw, use the fact [H⁺]=[OH⁻]: [H⁺] = √(1 x 10⁻¹⁴) = 1 x 10⁻⁷ mol/L

pH Scale

  • pH is defined as: pH = -log₁₀[H⁺]
  • Square brackets indicate concentration in moles per litre.
  • pH is the negative logarithm to the base 10 of hydrogen ion concentration.
  • pH of a solution is measured in moles per litre.
  • pH values range from 0 to 14.
  • pH values below 7 are acidic; above 7 are alkaline; 7 is neutral.

Strengths of Acids and Bases

  • Strong acid: A good proton donor (e.g., HCl, H₂SO₄)
  • Weak acid: A poor proton donor (e.g., ethanoic acid)
  • Strong base: A good proton acceptor (e.g., NaOH, KOH)
  • Weak base: A poor proton acceptor (e.g., NH₃)
  • Acid dissociation constants (Ka) measure acid strength.
  • Larger Ka values indicate stronger acids.
  • Base dissociation constants (Kb) measure base strength.
  • Larger Kb values indicate stronger bases.

Calculating pH of Strong Acids and Bases

  • Strong acids and bases are fully dissociated in water.
  • The pH of a strong acid solution can be calculated by using the concentration of H+ ions in solution.
  • The pH of a strong base solution can be calculated by using the concentration of OH-ions in solution.

Calculating pH of Weak Acids and Bases

  • Calculating the pH of a weak acid solution requires consideration of the dissociation constant (Ka).
  • The approach uses the equilibrium constant (Ka) and the initial concentration of the weak acid to find the concentration of H+.
  • To calculate the pH of a weak acid solution, we must know its dissociation constant.

pH Indicators

  • Acid-base indicators: Substances that change color depending on the pH of the solution.
  • Indicators have a specific pH range where their color changes.
  • Choosing the correct indicator depends on the pH range of the solution being tested.
  • Indicator color changes are affected by adding H⁺ or OH⁻ ions according to Le Chatelier's principle.

pH Titration

  • A pH titration is an experiment to track pH changes during a titration.
  • The process involves adding a base (from a burette) to an acid (in a beaker).
  • pH is monitored continuously.
  • The pH data is typically plotted as a graph.
  • The graph (titration curve) shows how pH changes as the base is added.
  • Titration curves for strong acid-strong base, weak acid-strong base and weak acid-weak base reactions have typical shapes.

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Explore the self-ionization of water and understand the pH scale through this quiz. You'll learn about the equilibrium constants, the formation of H⁺ and OH⁻ ions, and how pH values indicate acidity or alkalinity. Test your knowledge and see how well you grasp these fundamental concepts in chemistry.

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