Chemistry Chapter on Metals and Ionic Compounds
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Questions and Answers

Which of the following is a characteristic property of metals?

  • High strength (correct)
  • Brittle
  • Electrical insulator
  • Thermal insulator
  • What is the term used to describe compounds that do dissolve in water?

  • Soluble (correct)
  • Non-polar
  • Insoluble
  • Aqueous
  • Non-metallic oxides are typically basic in nature.

    False (B)

    What type of charge do ions of metals typically have?

    <p>positive charge</p> Signup and view all the answers

    Ionic compounds do not separate into ions when they dissolve in water.

    <p>False (B)</p> Signup and view all the answers

    Metals are said to be ______, meaning they can be beaten into shape.

    <p>malleable</p> Signup and view all the answers

    Name an example of an ionic compound.

    <p>NaCl</p> Signup and view all the answers

    Match the following elements with their state at room temperature:

    <p>Bromine = Liquid Oxygen = Gas Iodine = Solid Mercury = Liquid</p> Signup and view all the answers

    Compounds that do not dissolve in water are described as ______.

    <p>insoluble</p> Signup and view all the answers

    What is the term used to describe the bonding that occurs within a sample of a metal?

    <p>Metallic bonding (D)</p> Signup and view all the answers

    Match the following terms with their definitions:

    <p>Soluble = Dissolves in water Insoluble = Does not dissolve in water Ionic bond = Electrostatic attraction between oppositely charged ions Crystal lattice = Orderly arrangement of ions in a solid</p> Signup and view all the answers

    All metals are solids at room temperature.

    <p>False (B)</p> Signup and view all the answers

    In the structure of a typical metal, what surrounds the closely packed metal ions?

    <p>A sea of delocalised, mobile valence electrons (C)</p> Signup and view all the answers

    What type of bond is formed between cations and electrons in metals?

    <p>Metallic bond (A)</p> Signup and view all the answers

    What gas is identified by the pop-test?

    <p>Hydrogen (D)</p> Signup and view all the answers

    Metals tend to gain electrons in chemical reactions.

    <p>False (B)</p> Signup and view all the answers

    What is the electron configuration of a Na^+ ion?

    <p>2, 8</p> Signup and view all the answers

    Oxygen gas can be identified by its reaction with a glowing wooden splint which relights in oxygen.

    <p>True (A)</p> Signup and view all the answers

    What happens to limewater when carbon dioxide is passed into it?

    <p>It gives a milky solution.</p> Signup and view all the answers

    The cations in a metallic lattice are surrounded by a sea of ______ electrons.

    <p>delocalized</p> Signup and view all the answers

    Which of the following metals is considered highly reactive?

    <p>Potassium (B)</p> Signup and view all the answers

    The chemical reaction for burning hydrogen is represented as 2H2 + O2 → 2H2O + _____

    <p>Energy</p> Signup and view all the answers

    Match the following metals with their electron loss characteristics:

    <p>Sodium = Loses 1 electron Calcium = Loses 2 electrons Aluminium = Loses 3 electrons Potassium = Loses 1 electron easily</p> Signup and view all the answers

    Match the metals with their corresponding flame test colors:

    <p>Barium = Pale green Calcium = Yellow - red Copper = Green - blue Sodium = Orange Potassium = Lilac Lithium = Red</p> Signup and view all the answers

    What is the by-product of the combustion of hydrogen?

    <p>Water (B)</p> Signup and view all the answers

    Aluminium loses one electron to become Al^3+.

    <p>False (B)</p> Signup and view all the answers

    Calcium bicarbonate is insoluble in water.

    <p>False (B)</p> Signup and view all the answers

    What is the electron arrangement for a Ca^2+ ion?

    <p>2, 8, 8</p> Signup and view all the answers

    What is the purpose of a flame test?

    <p>To identify the presence of metal ions.</p> Signup and view all the answers

    Which of the following describes covalent lattices?

    <p>Very high melting point and hard (C)</p> Signup and view all the answers

    All atoms in a covalent lattice are freely mobile.

    <p>False (B)</p> Signup and view all the answers

    What is a property of substances with strong covalent bonds that affects their electrical conductivity?

    <p>They are non-conductors of electricity.</p> Signup and view all the answers

    Covalent lattices may be ______ or layered structures.

    <p>3D</p> Signup and view all the answers

    Which of the following is a characteristic of hydrogen bonding?

    <p>It is a type of dipole-dipole interaction. (C)</p> Signup and view all the answers

    Match the type of bond or interaction with its characteristic.

    <p>Covalent bonds = Strong bonds holding atoms in a lattice Hydrogen bonds = Weak attractive forces between molecules Ionic bonds = Transfer of electrons between atoms Dispersion forces = Weakest intermolecular forces</p> Signup and view all the answers

    What is the significance of delocalized electrons in graphite?

    <p>Delocalized electrons allow graphite to conduct electricity.</p> Signup and view all the answers

    The formula for sulfur dioxide is ______.

    <p>SO2</p> Signup and view all the answers

    How many valence electrons does carbon have?

    <p>4 (A)</p> Signup and view all the answers

    O=C=O represents a molecule where carbon has a full valence shell.

    <p>True (A)</p> Signup and view all the answers

    What problem arises when distributing the valence electrons around the carbon atom?

    <p>Carbon does not have 8 electrons.</p> Signup and view all the answers

    In order for a carbon atom to achieve a full valence shell, it needs to move a non-bonding electron pair from a __________ atom.

    <p>peripheral</p> Signup and view all the answers

    Match the following descriptions to their corresponding processes:

    <p>Distributing valence electrons = Using available electrons in pairs around peripheral atoms. Moving non-bonding electrons = Creating shared, bonding pairs with the central atom. Checking the diagram = Ensuring complete valence shells for all atoms. Forming double bonds = Resulting in structures like O=C=O.</p> Signup and view all the answers

    What happens to the non-bonding electron pairs during the bonding process?

    <p>They become shared bonding pairs. (C)</p> Signup and view all the answers

    The total number of electrons used in this process is less than 16.

    <p>False (B)</p> Signup and view all the answers

    What is the structural formula when double bonds are formed in this example?

    <p>O=C=O</p> Signup and view all the answers

    Flashcards

    Metals as conductors

    Metals are good conductors of heat and electricity.

    Non-metals as insulators

    Non-metals are thermal and electrical insulators.

    Strength of metals

    Metals typically have high strength.

    Brittleness of non-metals

    Solid non-metals tend to be brittle.

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    Malleability and ductility of metals

    Metals are malleable and ductile, meaning they can be shaped and stretched.

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    Metallic oxides

    Metallic oxides are basic in nature.

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    Non-metallic oxides

    Non-metallic oxides are acidic.

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    Ionic charges of metals

    Ions of metals carry a positive charge.

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    Metallic Bonding

    The attraction between cations and delocalized electrons in metals.

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    Cations

    Positively charged ions formed by losing electrons.

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    Delocalized Electrons

    Electrons that are free to move throughout the metal lattice.

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    Electron Configuration

    The arrangement of electrons in an atom or ion.

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    Reactivity of Metals

    Metals' tendency to lose electrons during reactions.

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    Noble Gas Configuration

    An electron arrangement similar to noble gases after losing electrons.

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    Valence Electrons

    Electrons in the outermost shell of an atom that can be lost.

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    Chemical Reactivity Patterns

    The predictable behavior of metals in chemical reactions.

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    Carbon's Valence Electrons

    Carbon has 4 valence electrons, allowing it to form four bonds.

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    Total Electrons in Carbon Compound

    For carbon with 4 valence electrons and 4 peripheral atoms, total is 16 electrons.

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    Distributing Electrons

    Distribute valence electrons in pairs around peripheral atoms first.

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    Full Valence Shell

    An atom is stable when it has 8 electrons in its outer shell.

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    Non-bonding Electron Pair

    A pair of electrons that is not involved in bonding; can be moved to share with others.

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    Double Bonds

    Two pairs of electrons shared between two atoms, enhancing stability.

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    Electron Dot Diagram

    A graphical representation showing the bonding between atoms and lone pairs.

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    Ionic Compounds

    Compounds formed from metal cations and non-metal anions.

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    Dissolution of NaCl

    NaCl dissolves in water, breaking its ionic lattice into Na^+ and Cl^− ions.

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    Soluble vs Insoluble

    Soluble compounds dissolve in water; insoluble do not, effectively considered zero.

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    Ionic Bonds

    Strong attractions between oppositely charged ions in a crystal lattice.

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    Solubility Table

    A summary of which ionic compounds are soluble or insoluble in water.

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    Pop test for hydrogen

    The pop-test indicates the presence of hydrogen gas (H₂).

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    Limewater test for CO₂

    Carbon dioxide (CO₂) creates a milky solution in limewater due to calcium carbonate.

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    Oxygen ignition test

    A glowing splint relights in the presence of oxygen (O₂).

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    Unknown ionic compound detection

    Identify unknown ionic compounds using solubility charts and precipitation tests.

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    Flame test for metals

    The flame test identifies metal ions by the color of the flame produced.

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    Barium flame test color

    In flame tests, barium produces a pale green color.

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    Calcium flame test color

    Calcium gives a yellow-red flame during tests.

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    Flame Emission Spectroscopy

    A method using high temperatures to analyze ions and their quantities.

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    Covalent Bonds

    Strong bonds formed when atoms share electrons.

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    Intermolecular Forces

    Weak forces that attract molecules to each other.

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    Hydrogen Bonding

    A type of strong dipole-dipole interaction involving hydrogen.

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    Covalent Lattices

    Structures with high melting point and hard, covalent bonds.

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    Conductivity in Lattices

    Covalent lattices are typically non-conductors, except graphite.

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    MP and BP in Lattices

    Covalent lattices have very high melting points and boiling points.

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    3D and 2D Structures

    Covalent lattices can be three-dimensional or two-dimensional.

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    Study Notes

    Chemical Structures and Properties (Criterion 7)

    • Chemical properties and the structures of atoms
      • The Periodic Table is structured based on electron configuration.
      • Elements in the same period or group have similar properties and reactivity.
      • Elements are organized into metals and non-metals.
      • Groups 1, 2, 17, and 18 have similar properties and common ionic charges.
      • Reactivity trends are observed in periods 2 and 3, and groups 1, 2, and 17.
      • Atomic properties, including bond formation, are explained by electron configurations.

    Properties and Structures of Materials

    • The type of bonding determines the physical properties of a substance.
    • Metallic, ionic, and covalent substances have different structures and properties.
      • Chemical bonds form due to electrostatic attractions resulting from electron sharing or transfer.
      • Valency is a measure of the number of bonds an atom can form.
      • Ions are electrically charged atoms. Ionic bond formulas show constituent elements and charge.
      • Ionic compounds have high melting points, are brittle, and conduct electricity when molten or dissolved.
      • Metallic bonding involves a lattice of positively charged ions surrounded by mobile electrons.
      • Metallic properties (malleability, thermal/electrical conductivity) are due to this model.
      • Covalent substances are molecules or networks.
      • Intramolecular forces (strong bonds) are within molecules, while intermolecular forces (weak bonds) are between molecules.
      • Electron dot diagrams represent simple molecular compounds.

    Chemical Properties of Metals

    • Metals tend to lose electrons to form positive ions (cations), reacting with various chemical compounds.
    • Losing electrons results in a similar electron configuration to a noble gas.
    • Reactivity varies among metals; some lose electrons more easily (highly reactive).

    Comparing Metals and Nonmetals

    • Metals are lustrous, typically solid at room temperature, with high densities.
      • Good conductors of heat and electricity
      • Malleable and ductile.
      • Metallic oxides are basic.
    • Nonmetals are not lustrous, can be solids, liquids, or gases, with low densities.
      • Poor conductors of heat and electricity.
      • Brittle in solid form.
      • Nonmetallic oxides are acidic.

    Metallic Bonding

    • Metallic bonding describes the bonding in metals.
    • A metal lattice structure consists of closely packed metal ions surrounded by a 'sea' of delocalised electrons.
    • Electrostatic attractions between these ions and electrons result in strong bonding, explaining high melting points, malleability, and ductility.

    Properties of Metals

    • Malleability and ductility are possible because of the delocalised electrons.
    • Metals can conduct heat due to the delocalised electrons.
    • Lustre is caused by the presence of free electrons.

    Chemical Properties of Metals

    • Metals react by losing electrons forming positive ions. (Cations)
    • The result is the same electron configuration as a noble gas.
    • Some metals lose electrons more easily than others, resulting in wide variance in reactivity.

    Reactivity of Metals

    • Reactivity of metals generally increases as you move down a group, like group 1 (alkali metals).
    • As atomic radius increases down a group in metals, the valence electrons are further away from the nucleus, causing less attraction, making the metals more reactive.

    Elements and the Periodic Table: Semi-metals

    • Semi-metals have properties that are intermediate between metals and nonmetals.
    • Some examples of semi-metals include boron, silicon, germanium, etc.

    Elements and the Periodic Table: Nonmetals

    • Nonmetals are generally poor electrical and thermal conductors and are typically not lustrous or malleable.
    • They exist as solids, liquids or gases at room temperature.
    • The reactivity of nonmetals varies considerably as you move down a given group.

    Bonding and Chemical Compounds

    • Chemical compounds are composed of two or more elements chemically bonded together.
    • Chemical compounds have constant composition and properties.
    • Ionic compounds are formed by the attraction between positive and negative ions.
    • Covalent compounds contain covalent bonds and are formed when atoms share electrons.

    Ionic Compounds (Naming and Formulae)

    • Naming involves writing the cation (metal) first, followed by the anion (non-metal) with an ‘ide’ ending, sometimes with Roman Numerals for transition metals.
    • Formulas balance positive and negative charges. Use the number of each ion in the chemical formula.

    Ionic Compounds Containing Polyatomic Ions

    • Polyatomic ions are groups of atoms with a charge.
    • Names for polyatomic ions are fixed (for example, sulfate (SO42-), nitrate (NO3-), ammonium (NH4+)).
    • For compounds with polyatomic ions, place the polyatomic ion in parentheses if there is more than one of the polyatomic ion in the formula.

    Covalent Compounds (Naming and Formulae)

    • Naming prefixes denote the number of atoms. Use prefixes to denote the number of atoms in the chemical formula. e.g. CO2 = carbon dioxide and N₂O₄ = dinitrogen tetroxide.

    The Structure of Ionic Compounds

    • Ionic compounds are 3-dimensional crystal lattices, not molecules, with repeating arrays of alternating cations and anions held together by electrostatic attraction.
    • High melting and boiling points due to strong electrostatic forces.
    • Hard but brittle. Not good conductors in solid form. Good conductors when dissolved in liquid or as aqueous solutions.

    Covalent Compounds – Structures and Bonding

    • Most covalent compounds are molecules that consist of discrete atoms.
    • Covalent molecules have weak intermolecular forces (e.g., dispersion forces, sometimes dipole-dipole interactions, and hydrogen bonds) between molecules that influence melting and boiling points and other properties.
    • Covalent lattices may form 3-dimensional networks.
    • Strong covalent bonds throughout the lattice give them high melting points and inertness, like diamond.

    Covalent Bonding: Different Elements

    • The sharing of electrons in covalent bonds leads to molecules of specific shapes, and these have properties that are different from ionic or metallic compounds.
    • Diatomic nonmetals form molecules in which two atoms share electron pairs to achieve a full outer shell. For instance, chlorine forms Cl2 molecules via a single electron pair shared between chlorine atoms.
    • Oxygen forms O2 molecules by sharing two pairs of electrons (double bond).

    Covalent Bonding: Drawing Diagrams (Lewis diagrams)

    • Lewis structures use valence electrons only to show bonding atoms and unbonded electron pairs.
    • The goal is to achieve a full outer electron shell (octet rule) for each atom, except hydrogen.

    Forces in Covalent Molecular Bonding

    • Dispersion forces are weak attractive forces that emerge from temporary changes in electron density within molecules.
    • Polar molecules additionally have dipole-dipole attractions resulting from permanent partial positive and negative charges, and these often lead to higher boiling points than non-polar compounds.

    Types of Formulae

    • Molecular formula shows the exact number of atoms.
    • Empirical formula shows the simplest ratio of atoms.
    • Structural formula shows the bonds.
    • Semi-structural formula shows some bonds but not all

    Isomerism

    • Isomers have the same molecular formula but different structures.
    • Variations arise from differing arrangements of atoms. Different isomer forms result in difference of properties.

    Homologous Series of Hydrocarbons

    • A homologous series of hydrocarbons shows a pattern of recurring structural units, which leads to similar chemical and physical properties within the homologous series.
    • These are classified as alkanes, alkenes, or alkynes, depending on whether they have single, double, or triple bonds, respectively.

    Combustion of Hydrocarbons

    • Complete combustion in plentiful oxygen produces carbon dioxide and water.
    • Incomplete combustion in limited oxygen yields carbon monoxide and potentially carbon, as well as water.

    Tests for Unsaturation

    • Bromine water decolorization is used to distinguish saturated from unsaturated hydrocarbons.
    • Saturated hydrocarbons typically do not decolorize bromine water, while unsaturated ones react rapidly, producing a colorless compound.

    Naming Organic Compounds (IUPAC Nomenclature)

    • Organic compounds are systematically named using the IUPAC system, which uses prefixes, stems, and suffixes.
    • Prefixes specify the number of carbon atoms.
    • Stems indicate the longest continuous chain of carbon atoms.
    • Suffixes indicate the types of bonds (ane, ene, or yne).
    • Side groups (substituents) are named and located with regard to the longest chain.

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    Description

    Test your knowledge on the properties of metals, non-metallic oxides, and ionic compounds. This quiz covers essential concepts in chemistry, including the behavior of metals, types of bonding, and the characteristics of compounds. Perfect for reinforcing your understanding of these foundational topics in chemistry.

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