Chemistry Chapter: Nature of Reactants

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Questions and Answers

Which type of compounds typically react faster due to their bonding?

  • Metallic Compounds
  • Ionic Compounds (correct)
  • Covalent Compounds
  • Organic Compounds

Ionic compounds require more energy to break their bonds compared to covalent compounds.

False (B)

What effect does increasing the surface area of solid reactants have on the rate of reaction?

It increases the rate of reaction.

Covalent compounds react _____ compared to ionic compounds due to the need for energy to break their bonds.

<p>slowly</p> Signup and view all the answers

Match the type of compound with its reaction speed:

<p>Ionic Compounds = React fast Covalent Compounds = React slowly</p> Signup and view all the answers

What happens to the rate of reaction as the concentration of reactants increases?

<p>The rate increases. (B)</p> Signup and view all the answers

The equilibrium constant (Kc) is dependent on the concentrations of reactants and products.

<p>True (A)</p> Signup and view all the answers

What is the relationship defined by the Law of Mass Action concerning the rate of a chemical reaction?

<p>The rate of a chemical reaction is directly proportional to the product of the concentrations of the reactants.</p> Signup and view all the answers

At equilibrium, the rate of the forward reaction, $r_1$, is equal to the rate of the _____ reaction, $r_2$.

<p>reverse</p> Signup and view all the answers

Match the following variables with their corresponding meanings in the context of the equilibrium constant equation:

<p>$K_c$ = Equilibrium constant $[NH_3]$ = Concentration of ammonia $[FeCl_3]$ = Concentration of reactant iron (III) chloride $[N_2]$ = Concentration of nitrogen gas</p> Signup and view all the answers

What is the value of $K_c$ that favors the formation of products?

<p>$K_c &gt; 1$ (C)</p> Signup and view all the answers

Solids are included in the expressions for calculating equilibrium constants.

<p>False (B)</p> Signup and view all the answers

What does a reversible reaction allow?

<p>It allows the reaction to proceed in both forward and reverse directions.</p> Signup and view all the answers

In the equation $AgCl(s) ightleftharpoons Ag^{+}(aq) + Cl^{-}(aq)$, AgCl is a __________.

<p>solid</p> Signup and view all the answers

If the stoichiometric coefficients of a balanced chemical equation are doubled, how does this affect the equilibrium constant?

<p>The equilibrium constant is squared. (A)</p> Signup and view all the answers

Increase in concentration of reactants will favor the formation of products.

<p>True (A)</p> Signup and view all the answers

What is the general expression for the equilibrium constant $K_c$?

<p>K_c = \frac{\text{Conc. of products}}{\text{Conc. of reactants}}</p> Signup and view all the answers

Match the following reactions with their equilibrium constants:

<p>$Ag_2O(s) + 2HNO_3(aq) \rightleftharpoons 2AgNO_3(aq) + H_2O(l)$ = $K_c = \frac{[AgNO_3]^2}{[HNO_3]^2}$ $A + B \rightleftharpoons AB$ = General case for $K_c$ $2A + 2B \rightleftharpoons 2AB$ = $K_c = X $\frac{1}{2}A + \frac{1}{2}B \rightleftharpoons \frac{1}{2}AB$ = $K_c = \sqrt{X}$</p> Signup and view all the answers

Flashcards

Ionic vs. Covalent Reaction Speed

Ionic compound reactions are typically faster than covalent compound reactions because ionic compounds are composed of charged particles that react immediately when mixed, while covalent compounds require breaking bonds, which takes time.

Surface Area Effect

Increasing the surface area of a solid reactant increases the reaction rate by increasing the number of collisions between reactants.

Reaction Rate & Collisions

The rate of a reaction depends on the frequency of collisions between reactant particles.

Ionic Compound Reaction

Reaction between ions occurring immediately upon mixing.

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Covalent Compound Reaction

Reaction between molecules requiring energy to break bonds.

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Equilibrium Constant ($K_c$)

The ratio of product concentrations to reactant concentrations at equilibrium. It indicates whether products or reactants are favored.

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What does $K_c > 1$ mean?

The equilibrium constant ($K_c$) is greater than 1. This indicates that at equilibrium, the concentration of products is higher than the concentration of reactants. Therefore, the reaction favors the formation of products.

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What does $K_c < 1$ mean?

The equilibrium constant ($K_c$) is less than 1. This indicates that at equilibrium, the concentration of reactants is higher than the concentration of products. Therefore, the reaction favors the formation of reactants.

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Solids in Equilibrium Constant

Solid substances do not appear in the equilibrium constant expression because their concentrations remain constant during the reaction.

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Effect of Stoichiometry on $K_c$

Changing the stoichiometric coefficients in a balanced chemical equation changes the equilibrium constant. For example, doubling the coefficients squares the $K_c$ value.

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Reversible Reaction

A reaction that can proceed in both forward and reverse directions. Both the formation of products and the reformation of reactants are possible.

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Complete Reaction

A reaction that proceeds to completion (essentially, all reactants are consumed) because the forward rate is much faster than the reverse rate.

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Ionization of Sparingly Soluble Salts

The process where a sparingly soluble salt dissolves to a small extent, producing ions in solution. This results in an equilibrium between the solid salt and its ions in solution.

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Collision Theory

For a reaction to occur, reactant molecules must collide with sufficient energy and correct orientation.

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Concentration & Reaction Rate

Increasing reactant concentration increases the rate of reaction by increasing the frequency of collisions.

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Law of Mass Action

The rate of a reaction is proportional to the product of reactant concentrations, each raised to its stoichiometric coefficient.

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Kc Calculation

The equilibrium constant (Kc) is calculated as the product of product concentrations divided by the product of reactant concentrations, each raised to their stoichiometric coefficients.

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Study Notes

Nature of Reactants

  • Type of bonding in the reactants:

    • Ionic compounds react because the reaction takes place between ions. Those ions are ionized as soon as mixed.
    • Covalent compounds react because the reaction takes place between molecules. An amount of energy is consumed to break the covalent bonds.
  • Surface area of reactants:

    • Increasing surface area (e.g., powder form) increases the chance of collisions, thus increasing the rate of reaction.

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