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Questions and Answers
Which acid has the suffix –ous based on the anion that ends in –ite?
Which acid has the suffix –ous based on the anion that ends in –ite?
What is the correct name for HCN?
What is the correct name for HCN?
Which of the following compounds is named correctly?
Which of the following compounds is named correctly?
Which of the following is the correct name for HNO2?
Which of the following is the correct name for HNO2?
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What is the naming rule for acids that contain an anion ending in –ate?
What is the naming rule for acids that contain an anion ending in –ate?
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What did Thomson postulate about electrons?
What did Thomson postulate about electrons?
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What is the primary characteristic of the nucleus of an atom?
What is the primary characteristic of the nucleus of an atom?
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How do isotopes of an element differ?
How do isotopes of an element differ?
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Which particle in an atom has no charge?
Which particle in an atom has no charge?
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What best describes the arrangement of electrons in the atom?
What best describes the arrangement of electrons in the atom?
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What does the charge of a proton equal?
What does the charge of a proton equal?
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What did Rutherford contribute to atomic theory?
What did Rutherford contribute to atomic theory?
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Which of the following statements about isotopes is true?
Which of the following statements about isotopes is true?
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What is the charge of Alkali Metals in Group 1A?
What is the charge of Alkali Metals in Group 1A?
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Which of the following is a correct example of a Binary Ionic Compound (Type I)?
Which of the following is a correct example of a Binary Ionic Compound (Type I)?
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Which naming convention is applied to monatomic anions?
Which naming convention is applied to monatomic anions?
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Which of the following statements is true about Binary Ionic Compounds (Type II)?
Which of the following statements is true about Binary Ionic Compounds (Type II)?
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Which of the following is an example of a Binary Ionic Compound (Type II)?
Which of the following is an example of a Binary Ionic Compound (Type II)?
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What is the characteristic of Noble Gases in Group 8A?
What is the characteristic of Noble Gases in Group 8A?
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What does the mass number of an isotope represent?
What does the mass number of an isotope represent?
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What must be memorized for naming compounds that contain them?
What must be memorized for naming compounds that contain them?
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What distinguishes Type I Binary Ionic Compounds from Type II?
What distinguishes Type I Binary Ionic Compounds from Type II?
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Which of the following statements about ionic bonds is true?
Which of the following statements about ionic bonds is true?
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If an isotope has 54 electrons and 78 neutrons, what is its mass number?
If an isotope has 54 electrons and 78 neutrons, what is its mass number?
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Which of the following compounds contains a polyatomic ion?
Which of the following compounds contains a polyatomic ion?
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Who is considered the first chemist for performing quantitative experiments?
Who is considered the first chemist for performing quantitative experiments?
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Which of the following correctly describes isotopes?
Which of the following correctly describes isotopes?
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How is the second element named in a binary covalent compound?
How is the second element named in a binary covalent compound?
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What distinguishes cations from anions?
What distinguishes cations from anions?
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What prefix is never used for the first element in a binary covalent compound?
What prefix is never used for the first element in a binary covalent compound?
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Which law states that mass is neither created nor destroyed in a chemical reaction?
Which law states that mass is neither created nor destroyed in a chemical reaction?
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What is the significance of groups or families in the periodic table?
What is the significance of groups or families in the periodic table?
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Which of the following best summarizes Dalton's Atomic Theory regarding the composition of compounds?
Which of the following best summarizes Dalton's Atomic Theory regarding the composition of compounds?
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Which of the following is correctly named according to the rules of binary covalent compounds?
Which of the following is correctly named according to the rules of binary covalent compounds?
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Which statement regarding Dalton's atomic theory is incorrect?
Which statement regarding Dalton's atomic theory is incorrect?
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What does the law of definite proportion imply about a compound?
What does the law of definite proportion imply about a compound?
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What is the appropriate naming convention when naming acids that do not contain oxygen?
What is the appropriate naming convention when naming acids that do not contain oxygen?
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What characterizes a molecule formed by covalent bonds?
What characterizes a molecule formed by covalent bonds?
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Which of the following compounds is an example of an acid?
Which of the following compounds is an example of an acid?
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What does Dalton's Atomic Theory state about atoms in a chemical reaction?
What does Dalton's Atomic Theory state about atoms in a chemical reaction?
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Which law describes the ratio of the masses of the second element that combine with 1 gram of the first element?
Which law describes the ratio of the masses of the second element that combine with 1 gram of the first element?
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Which prefix indicates the presence of four atoms in a compound?
Which prefix indicates the presence of four atoms in a compound?
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What is the correct name for the compound Mg(NO3)2?
What is the correct name for the compound Mg(NO3)2?
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According to early chemistry practices, what was a significant focus of alchemists?
According to early chemistry practices, what was a significant focus of alchemists?
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What was one of the primary contributions of Robert Boyle to chemistry?
What was one of the primary contributions of Robert Boyle to chemistry?
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Study Notes
Chapter 2: Atoms, Molecules, and Ions
- This chapter covers the fundamentals of atoms, molecules, and ions, including their history and modern understanding.
Section 2.1: The Early History of Chemistry
- Greeks were the first to attempt to explain chemical changes.
- Alchemy dominated for 2000 years, with several elements being discovered and mineral acids prepared.
- Robert Boyle was a pivotal figure, performing quantitative experiments and developing the first experimental definition for an element.
Section 2.2: Fundamental Chemical Laws
- Law of Conservation of Mass (Lavoisier): Mass is neither created nor destroyed in a chemical reaction.
- Law of Definite Proportion (Proust): A given compound always contains exactly the same proportion of elements by mass.
- Law of Multiple Proportions (Dalton): When two elements form a series of compounds, the ratios of the masses of the second element that combine with 1 gram of the first element can be reduced to small whole numbers.
Section 2.3: Dalton's Atomic Theory
- Dalton's Atomic theory (1808):
- Each element is made up of tiny particles called atoms
- The atoms of a given element are identical, but the atoms of different elements are different in some fundamental way.
- Chemical compounds are formed when atoms of different elements combine with each other. A given compound always has the same relative numbers and types of atoms.
- Chemical reactions involve reorganization of the atoms—changes in the way they are bound together. The atoms themselves are not changed in a chemical reaction.
Section 2.4: Early Experiments to Characterize the Atom
-
J. J. Thomson (1898-1903):
- Postulated the existence of negatively charged particles (electrons) using cathode-ray tubes.
- Determined the charge-to-mass ratio of an electron.
- The atom must also contain positive particles to balance the negative charge of electrons.
-
Ernest Rutherford (1911):
- Explained the nuclear atom.
- The atom has a dense center of positive charge called the nucleus.
- Electrons travel around the nucleus at a large distance relative to the nucleus.
Section 2.5: The Modern View of Atomic Structure
- The atom contains:
- Electrons: negatively charged, found outside the nucleus.
- Protons: positively charged, found in the nucleus, with a magnitude of charge equal to the electron's negative charge.
- Neutrons: no charge, found in the nucleus, with a mass virtually the same as a proton.
- The nucleus is:
- Small compared to the overall size of the atom.
- Extremely dense, accounting for almost all of the atom's mass.
- Isotopes: Atoms with the same number of protons but different numbers of neutrons. They show almost identical chemical properties because the chemistry of an atom is due to its electrons. Most elements contain mixtures of isotopes.
- Isotopes are identified by:
- Atomic Number (Z): the number of protons.
- Mass Number (A): the number of protons plus the number of neutrons.
Section 2.6: Molecules and Ions
-
Chemical Bonds:
- Covalent Bonds: Bonds form between atoms by sharing electrons. The resulting collection of atoms is called a molecule.
-
Ionic Bonds: Bonds form due to the attraction between oppositely charged ions.
- Ion: an atom or group of atoms with a net positive or negative charge.
- Cation: a positive ion; lost electron(s).
- Anion: a negative ion; gained electron(s).
Section 2.7: An Introduction to the Periodic Table
- Metals vs. Nonmetals: A key classification of elements.
- Groups/Families: Vertical columns of elements with similar chemical properties.
- Periods: Horizontal rows of elements.
Section 2.8: Naming Simple Compounds
- Binary Compounds: Compounds composed of two elements (ionic or covalent).
- Binary Ionic Compounds (Type I): The cation is named first, followed by the anion. Monatomic cations take their name from the parent element. Monatomic anions have the element root with -ide added. Examples: KCl (Potassium chloride), MgBr₂ (Magnesium bromide), CaO (Calcium oxide).
- Binary Ionic Compounds (Type II): Metals that can form more than one positive ion. The charge of the metal cation must be specified using a Roman numeral. Examples: CuBr (Copper(I) bromide), FeS (Iron(II) sulfide), PbO₂ (Lead(IV) oxide).
- Polyatomic Ions: Ions containing multiple atoms. Their names need to be memorized. Examples: NaOH (Sodium hydroxide), Mg(NO₃)₂ (Magnesium nitrate), (NH₄)₂SO₄ (Ammonium sulfate).
- Binary Covalent Compounds (Type III): Formed between two nonmetals. The first element is named using its full element name, and the second element is named as an anion, using prefixes to indicate the number of atoms present. Examples: CO₂ (Carbon dioxide), SF₆ (Sulfur hexafluoride), N₂O₄ (Dinitrogen tetroxide).
-
Acids: Molecules with one or more hydrogen ions (H⁺) attached to an anion. If the anion does not contain oxygen, the acid is named with the prefix "hydro-" and the suffix "-ic." If the anion contains oxygen:
- The suffix "-ic" is added if the anion name ends in "-ate."
- The suffix "-ous" is added if the anion name ends in "-ite." (e.g., HNO₃ (Nitric acid), H₂SO₄ (Sulfuric acid), HNO₂ (Nitrous acid), H₂SO₃ (Sulfurous acid).
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Test your knowledge on the basics of chemical nomenclature and atomic theory with this quiz. Explore questions about acids, isotopes, and the historical contributions to atomic theory. Perfect for students reviewing Chapter 6 in their chemistry course.