Chemistry Chapter 5 Quiz
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Questions and Answers

Which statement about the trends in density is true?

  • Density only increases in the first group of the periodic table.
  • Density reaches a peak at Aluminum (group 3, period 3). (correct)
  • Density is constant across a period.
  • Density decreases as you move down group 7.

The atomic size decreases as you move down a group in the periodic table.

False (B)

What is the covalent radius?

Half the distance between the nuclei of two bonded atoms.

Which element is known to have the highest melting point among those mentioned?

<p>Carbon (A)</p> Signup and view all the answers

Density measures mass per unit __________.

<p>volume</p> Signup and view all the answers

Melting and boiling points generally increase as you move down group 1 of the periodic table.

<p>False (B)</p> Signup and view all the answers

Match the following elements with their density trends:

<p>Boron = Highest peak density in group 3, period 2 Aluminum = Peak density in group 3, period 3 He = Lowest density in group 0 Fr = Lowest density in group 1</p> Signup and view all the answers

Who invented the periodic table?

<p>Dimitri Mendeleev</p> Signup and view all the answers

The modern periodic table is based on _____ instead of atomic mass.

<p>atomic number</p> Signup and view all the answers

Match the following trends with their descriptions:

<p>Melting points peak = Occurs at carbon for period 2 Boiling points peak = Occurs at silicon for period 3 Decreasing trend down a group = Melting and boiling points in group 1 Strength of attraction = Stronger on the left side of the table</p> Signup and view all the answers

Who introduced the concept of electronegativity?

<p>Linus Pauling (B)</p> Signup and view all the answers

How does electronegativity change across a period?

<p>It increases (C)</p> Signup and view all the answers

Fluorine is the least electronegative element.

<p>False (B)</p> Signup and view all the answers

In the compound hydrogen iodide, which atom has a stronger attraction for the shared electrons?

<p>Iodine</p> Signup and view all the answers

Electronegativity increases as you move down a group in the periodic table.

<p>False (B)</p> Signup and view all the answers

In chlorine gas (Cl2), the electrons are shared __________.

<p>equally</p> Signup and view all the answers

What causes the decrease in electronegativity when moving down a group?

<p>Shielding and increased distance from the nucleus.</p> Signup and view all the answers

Electronegativity decreases going down a group due to increased __________.

<p>shielding</p> Signup and view all the answers

Match the elements with their electronegativity characteristic:

<p>Fluorine = Most electronegative element Chlorine = Equal sharing of electrons Hydrogen = Slight positive charge in hydrogen iodide Iodine = Slight negative charge in hydrogen iodide</p> Signup and view all the answers

Match the following factors with their effect on electronegativity:

<p>Increased nuclear charge = Increases electronegativity Increased shielding = Decreases electronegativity Distance from nucleus = Decreases electronegativity Number of electron shells = Decreases electronegativity</p> Signup and view all the answers

What is the first ionisation energy?

<p>Amount of energy required to remove one mole of electrons from one mole of atoms in the gaseous state (A)</p> Signup and view all the answers

Why does ionisation energy decrease down a group?

<p>The outer electrons are further away from the nucleus due to increased electron shells. (C)</p> Signup and view all the answers

Ionisation energy decreases across a period due to an increase in nuclear charge.

<p>False (B)</p> Signup and view all the answers

The first ionisation energy is always less than the second ionisation energy for any element.

<p>True (A)</p> Signup and view all the answers

What is the process that occurs during the second ionisation energy?

<p>The removal of one mole of electrons from one mole of gaseous 1+ ions.</p> Signup and view all the answers

What happens to the ionisation energy as successive electrons are removed from an atom?

<p>It increases.</p> Signup and view all the answers

The noble gas has the highest value for the __________ ionisation energy within each period.

<p>first</p> Signup and view all the answers

Match the following terms with their definitions:

<p>First Ionisation Energy = Energy required to remove one mole of electrons from one mole of gaseous atoms Second Ionisation Energy = Energy required to remove one mole of electrons from one mole of gaseous 1+ ions Noble Gas = Element with full outer electron shell and highest ionisation energy within a period Ionisation Energy Trend Across Period = Increases due to greater nuclear charge</p> Signup and view all the answers

The large jump in ionisation energy occurs when an electron is removed from a new ______.

<p>shell</p> Signup and view all the answers

Match the elements with their respective ionisation energy trends:

<p>Potassium = Higher second ionisation energy due to stable electron configuration Magnesium = Lower second ionisation energy as it tends toward stable arrangement Lithium = Decreases in ionisation energy down the group Sodium = Experiences increased attraction on removal of electrons</p> Signup and view all the answers

Flashcards

Periodic Trends in Melting/Boiling Points

Melting and boiling points of elements vary in a predictable pattern across the periodic table, influenced by intermolecular forces.

Peak Melting/Boiling Points

Elements like carbon (period 2) and silicon (period 3) have higher melting and boiling points than their neighbors.

Left-Right Melting/Boiling Point Trend

Attractive forces between particles tend to be stronger for elements on the left side of the periodic table.

Down Group 1 Melting/Boiling Trend

Moving down group 1 (alkaline metals), melting and boiling points generally decrease.

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Intermolecular Forces

Forces of attraction between particles which influence melting and boiling properties of elements.

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Density Trend: Across a Period

Density typically increases from Group 1 to the middle of a period, then decreases toward Group 0. This is because of increasing nuclear charge and number of outer electrons.

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Density Trend: Down a Group

As you move down a group, density generally increases. This is due to the increasing number of electron shells and the resulting larger atomic size.

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Covalent Radius

Covalent radius is half the distance between the nuclei of two bonded atoms. It is a way to measure atomic size, expressed in picometers.

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Atomic Size Trend: Across a Period

Atomic size generally decreases across a period. This is due to increasing nuclear charge pulling the electrons closer to the nucleus.

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Atomic Size Trend: Down a Group

Atomic size increases down a group because the number of electron shells increases. The outermost electrons are farther from the nucleus.

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First Ionisation Energy

The energy required to remove one mole of electrons from one mole of gaseous atoms.

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Second Ionisation Energy

The energy required to remove one mole of electrons from one mole of gaseous 1+ ions.

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Ionization Energy Trend Across a Period

Ionization energies increase across a period because the nuclear charge increases, attracting outer electrons more strongly.

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Ionization Energy Trend Down a Group

Ionization energies generally decrease down a group because the outermost electron is farther from the nucleus.

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Noble Gas Ionization Energy

Noble gases have the highest 1st ionization energies within their periods due to their stable full electron shells.

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Electronegativity

A measure of an atom's attraction for the shared pair of electrons in a bond. The stronger the attraction, the more electronegative the atom.

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What is the most electronegative element?

Fluorine (F) is the most electronegative element.

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Equal Electronegativity

When two atoms have the same electronegativity, the electrons are shared equally between them.

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Unequal Electronegativity

When two atoms have different electronegativities, the electrons are pulled closer to the more electronegative atom, creating a slightly negative (-) charge on that atom and a slightly positive (+) charge on the other.

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Who invented electronegativity?

Linus Pauling, an American chemist, introduced the concept of electronegativity in 1932.

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Electronegativity Trend

The tendency of an atom to attract electrons towards itself in a chemical bond.

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Electronegativity Across a Period

Electronegativity increases across a period due to increasing nuclear charge, leading to stronger attraction of electrons to the nucleus.

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Electronegativity Down a Group

Electronegativity decreases down a group, even though nuclear charge increases. This is because electron shielding and increased distance between the nucleus and outer electrons weaken the attraction.

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Shielding Effect

The inner electrons block the outer electrons from the full pull of the nucleus, reducing the attraction between the nucleus and outer electrons.

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How does electronegativity affect bonding?

Electronegativity difference between atoms determines the type of bond formed. Large difference: ionic, small difference: covalent.

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Why is the second ionisation energy greater than the first?

The second ionisation energy is greater because it involves removing an electron from a positively charged ion, leading to a stronger attraction between the nucleus and remaining electrons.

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Second ionisation energy of group 1 vs. group 2

The second ionisation energy of potassium (group 1) is greater than magnesium (group 2) because removing the second electron from potassium disrupts a stable electron configuration, requiring more energy. Removing an electron from magnesium results in a stable configuration, requiring less energy.

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Large jump in ionisation energy

A large jump in ionisation energy occurs when an electron is removed from a new shell closer to the nucleus, because it is held more tightly to the nucleus.

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Successive ionisation energies

Successive ionisation energies increase as the atom becomes more positive due to increasing nuclear charge, making it harder to remove further electrons.

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