Chemistry Chapter 10 Flashcards
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Questions and Answers

Arrange the following compounds in order of increasing boiling point temperature: HCl, H2O, SiH4.

  • H2O < SiH4 < HCl
  • SiH4 < HCl < H2O (correct)
  • H2O < HCl < SiH4
  • HCl < SiH4 < H2O
  • Arrange the following compounds in order of increasing boiling point temperature: F2, Cl2, Br2.

  • F2 < Cl2 < Br2 (correct)
  • Br2 < F2 < Cl2
  • Br2 < Cl2 < F2
  • Cl2 < F2 < Br2
  • Arrange the following compounds in order of increasing boiling point temperature: CH4, C2H6, C3H8.

  • CH4 < C2H6 < C3H8 (correct)
  • C3H8 < C2H6 < CH4
  • C2H6 < CH4 < C3H8
  • C2H6 < C3H8 < CH4
  • Arrange the following compounds in order of increasing boiling point temperature: O2, NO, N2.

    <p>N2 &lt; O2 &lt; NO</p> Signup and view all the answers

    The melting point of H2O(s) is 0 °C. The melting point of H2S(s) is -85 °C, and this is due to water having hydrogen bonds.

    <p>True</p> Signup and view all the answers

    Identify the intermolecular forces present in CH3CH2CH3.

    <p>Dispersion forces</p> Signup and view all the answers

    Identify the intermolecular forces present in CH3CH2Cl.

    <p>Dipole-dipole attraction and dispersion forces</p> Signup and view all the answers

    Identify the intermolecular forces present in CH3CH2OH.

    <p>Hydrogen bonding and dispersion forces</p> Signup and view all the answers

    The melting point of a substance increases as the strength of its intermolecular forces increases.

    <p>True</p> Signup and view all the answers

    The enthalpy of vaporization of CO2(l) is 9.8 kJ/mol, and that of CS2(l) is 28 kJ/mol. This is due to the higher molecular weight of CS2 which decreases the amount of intermolecular forces.

    <p>False</p> Signup and view all the answers

    The compounds are listed correctly in order of increasing boiling points: N2 < CS2 < H2O < KCl.

    <p>True</p> Signup and view all the answers

    The compounds are listed correctly in order of increasing boiling points: H2O < N2 < CS2 < KCl.

    <p>False</p> Signup and view all the answers

    How much heat is required to convert 422 g of liquid H2O at 23.5 °C into steam at 150 °C?

    <p>1130 kJ</p> Signup and view all the answers

    From the phase diagram for water, determine the state of water at 35 °C and 85 kPa.

    <p>Liquid</p> Signup and view all the answers

    From the phase diagram for water, determine the state of water at 40 °C and 0.1 kPa.

    <p>Gas</p> Signup and view all the answers

    From the phase diagram for water, determine the state of water at 75 °C and 3 kPa.

    <p>Gas</p> Signup and view all the answers

    From the phase diagram for water, determine the state of water at 15 °C and 0.1 kPa.

    <p>Gas</p> Signup and view all the answers

    From the phase diagram for water, determine the state of water at 60 °C and 50 kPa.

    <p>Liquid</p> Signup and view all the answers

    From the phase diagram for water, determine the state of water at -15 °C and 0.5 kPa.

    <p>Solid</p> Signup and view all the answers

    At very low temperatures, oxygen, O2, freezes and forms an amorphous solid.

    <p>False</p> Signup and view all the answers

    As it cools, olive oil slowly solidifies and forms an amorphous solid over a range of temperatures.

    <p>True</p> Signup and view all the answers

    Identify the type of crystalline solid formed by CaCl2.

    <p>Ionic</p> Signup and view all the answers

    Identify the type of crystalline solid formed by SiC.

    <p>Network covalent</p> Signup and view all the answers

    Identify the type of crystalline solid formed by N2.

    <p>Molecular</p> Signup and view all the answers

    Identify the type of crystalline solid formed by Fe.

    <p>Metallic</p> Signup and view all the answers

    Identify the type of crystalline solid formed by graphite (C).

    <p>Network covalent</p> Signup and view all the answers

    Identify the type of crystalline solid formed by CH3CH2CH2CH3.

    <p>Molecular</p> Signup and view all the answers

    Identify the type of crystalline solid formed by HCl.

    <p>Molecular</p> Signup and view all the answers

    Identify the type of crystalline solid formed by NH4NO3.

    <p>Ionic</p> Signup and view all the answers

    Identify the type of crystalline solid formed by K3PO4.

    <p>Ionic</p> Signup and view all the answers

    Study Notes

    Boiling Points of Compounds

    • Compounds arranged by increasing boiling point: SiH4 < HCl < H2O
    • Series for halogens in increasing boiling points: F2 < Cl2 < Br2
    • Alkanes in order of increasing boiling point: CH4 < C2H6 < C3H8
    • For small nitrogen and oxygen molecules: N2 < O2 < NO

    Melting Points and Intermolecular Forces

    • Melting point of H2O(s) is 0 °C; H2S(s) melts at -85 °C due to stronger hydrogen bonds in water.
    • Intermolecular forces in CH3CH2CH3 detected are dispersion forces.
    • CH3CH2Cl exhibits dipole-dipole attractions and dispersion forces.
    • CH3CH2OH shows hydrogen bonding along with dispersion forces.
    • Increased melting point correlates with stronger intermolecular forces.

    Enthalpy of Vaporization

    • Enthalpy of vaporization: CO2(l) = 9.8 kJ/mol; CS2(l) = 28 kJ/mol.
    • Higher molecular weight of CS2 does not decrease intermolecular forces; claim is false.
    • Correct order of boiling points: N2 < CS2 < H2O < KCl, verified as true.
    • Incorrect order of boiling points: H2O < N2 < CS2 < KCl, verified as false.

    Heat Calculation

    • To convert 422 g of liquid H2O at 23.5 °C into steam at 150 °C requires 1130 kJ of heat.

    States of Water from Phase Diagram

    • Water state at 35 °C and 85 kPa: Liquid.
    • Water state at 40 °C and 0.1 kPa: Gas.
    • Water state at 75 °C and 3 kPa: Gas.
    • Water state at 15 °C and 0.1 kPa: Gas.
    • Water state at 60 °C and 50 kPa: Liquid.
    • Water state at -15 °C and 0.5 kPa: Solid.

    Amorphous Solids and Crystalline Structures

    • At very low temperatures, O2 does not form an amorphous solid; claim is false.
    • Olive oil forms an amorphous solid upon cooling over a range of temperatures; true.
    • Type of crystalline solid for CaCl2: Network covalent.
    • SiC also classified as a network covalent solid.
    • N2 identified as a molecular solid.
    • Fe is categorized as a metallic solid.
    • Graphite (C) is classified as a network covalent solid.
    • CH3CH2CH2CH3 and HCl classified as molecular solids.
    • NH4NO3 and K3PO4 identified as ionic solids.

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