Chemistry - Key Concepts - (2) Bonding and Structure

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Questions and Answers

What holds the ions together in an ionic compound?

  • Strong covalent bonds
  • Strong electrostatic forces of attraction (correct)
  • Van der Waals forces
  • Weak intermolecular forces

Which property distinguishes metals from ionic compounds in terms of conductivity?

  • Both conduct electricity equally in any state
  • Ionic compounds conduct in molten state, metals do not
  • Ionic compounds conduct in solid state, metals do not
  • Metals conduct electricity in both solid and molten states, ionic compounds do not when solid (correct)

What is the primary reason for the high melting and boiling points of covalent compounds?

  • Formation of giant lattice structures
  • Weak intermolecular forces require less energy to break
  • Strong covalent bonds between molecules (correct)
  • Weak intermolecular forces result in low melting points

Which allotrope of carbon is described as soft and conducts electricity?

<p>Graphite (A)</p> Signup and view all the answers

What structural feature distinguishes Diamond from Graphite?

<p>Diamond has a three-dimensional network with four bonds per carbon atom (B)</p> Signup and view all the answers

Which property is characteristic of metallic compounds?

<p>Malleable and ductile (B)</p> Signup and view all the answers

Covalent compounds typically form giant lattice structures.

<p>False (B)</p> Signup and view all the answers

What type of bonding occurs in diamond?

<p>Covalent bonding</p> Signup and view all the answers

Ionic compounds conduct electricity in __________ form.

<p>molten or aqueous</p> Signup and view all the answers

Match the following carbon allotropes with their characteristics:

<p>Diamond = Hard and does not conduct electricity Graphite = Soft and conducts electricity Buckyballs = Soft and has weak intermolecular forces Allotropes = Different structural forms of the same element</p> Signup and view all the answers

What is a key characteristic of the lattice structure of ionic compounds?

<p>Electrostatic forces of attraction (A)</p> Signup and view all the answers

Graphite consists of layers that can slide over each other.

<p>True (A)</p> Signup and view all the answers

What property of metals allows them to conduct electricity?

<p>Free-moving electrons</p> Signup and view all the answers

Covalent compounds generally have __________ melting and boiling points.

<p>low</p> Signup and view all the answers

Which of these is a use of diamond?

<p>Cutting tools (A)</p> Signup and view all the answers

Which of the following accurately describes the structure of diamond?

<p>Three-dimensional network of carbon atoms (C)</p> Signup and view all the answers

Graphite has a high melting point due to weak intermolecular forces.

<p>False (B)</p> Signup and view all the answers

What characteristic allows graphite to conduct electricity?

<p>Free non-bonding electrons</p> Signup and view all the answers

Diamond is hard and is used for making cutting tools because of its __________.

<p>strong covalent bonds</p> Signup and view all the answers

Match the following descriptions with the appropriate carbon allotrope:

<p>Diamond = Very hard, high melting point Graphite = Soft, conducts electricity Amorphous Carbon = Non-crystalline, low strength Fullerenes = Spherical structures of carbon</p> Signup and view all the answers

Which model best represents the actual relative sizes of atoms in a molecule?

<p>3D Space Filling Model (B)</p> Signup and view all the answers

A structural formula does not show the number of atoms of each element in a molecule.

<p>False (B)</p> Signup and view all the answers

What is a defining feature of a polymer?

<p>Long chain molecule made by joining smaller molecules</p> Signup and view all the answers

The reason metals conduct electricity is due to the presence of __________.

<p>free electrons</p> Signup and view all the answers

What does not occur in the metallic model?

<p>Positive metal ions vibrating constantly (D)</p> Signup and view all the answers

Which of the following accurately describes a limitation of dot and cross diagrams?

<p>Does not show the accurate shape of the molecule. (D)</p> Signup and view all the answers

Ball and stick models accurately represent the sizes of atoms and their bonds.

<p>False (B)</p> Signup and view all the answers

What is the arrangement of carbon atoms in a diamond structure?

<p>Tetrahedral arrangement.</p> Signup and view all the answers

Graphite is soft and used as lubricants because the layers can __________.

<p>slide past each other</p> Signup and view all the answers

Match the following properties with their corresponding carbon allotropes:

<p>Diamond = High melting point and hard Graphite = Soft and conducts electricity Amorphous Carbon = Non-crystalline structure Fullerenes = Spherical structures</p> Signup and view all the answers

What explains why metals conduct electricity?

<p>Free electrons able to move. (B)</p> Signup and view all the answers

The metallic model shows how positive metal ions vibrate constantly.

<p>False (B)</p> Signup and view all the answers

Why do longer polymers typically have higher boiling and melting points than shorter ones?

<p>Greater intermolecular forces.</p> Signup and view all the answers

Carbon allotropes are different structural forms of the same element called __________.

<p>allotropes</p> Signup and view all the answers

What is a primary limitation of a structural formula?

<p>Does not show how bonds formed. (A)</p> Signup and view all the answers

Flashcards

Ionic Compound

A substance with a giant lattice structure where positive and negative ions are strongly held together by electrostatic forces.

Metallic Structure

Metals have a giant metallic lattice where metal atoms lose outer electrons, forming a 'sea' of delocalized electrons that surround positively charged ions.

Covalent Bond

A bond formed by the sharing of electrons between two atoms, usually resulting in a molecular structure.

Diamond

A three-dimensional network of carbon atoms, each covalently bonded to four others. Known for its extreme hardness and high melting point.

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Graphite

Another allotrope of carbon, where each atom is covalently bonded to three others, forming layers stacked together. Soft, good conductor of electricity.

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What holds ionic compounds together?

The strong electrostatic forces between positively and negatively charged ions in a lattice structure.

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What holds metal atoms together?

The strong attraction between positive metal ions and delocalized electrons in a giant metallic lattice.

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What is a covalent bond?

The sharing of a pair of electrons between two atoms, creating a strong bond.

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Why do covalent compounds have low melting points?

They have low melting and boiling points because the weak intermolecular forces between molecules are easily broken.

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Why don't covalent compounds conduct electricity?

Because they lack free-moving electrons to carry charge.

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What is an allotrope?

A pure element that exists in multiple forms with different structures and properties.

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Why is diamond so hard?

Diamond is hard because each carbon atom is bonded to four other carbons, creating a strong, rigid structure.

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Why doesn't diamond conduct electricity?

Diamond does not conduct electricity because all the electrons are tightly bound in covalent bonds, preventing electron flow.

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Why is graphite soft?

Graphite's layers are held together weakly, allowing them to slide over each other, resulting in its softness.

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Why does graphite conduct electricity?

Graphite conducts electricity because its structure allows delocalized electrons to move freely within the layers.

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Ball and Stick Model

A model showing the 3D structure of molecules using spheres for atoms and sticks for bonds.

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Allotropes

Different forms of the same element with distinct structures and properties.

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Compound

When a substance can be split into simpler substances because it contains two or more elements joined together.

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Molecule

A substance formed by the covalent bonding of two or more atoms.

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Polymer

A long chain molecule formed by joining many smaller molecules (monomers) together.

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Low melting point

Substances with low melting and boiling points have weak intermolecular forces.

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Why longer polymers have higher boiling/melting points

Longer polymers have more intermolecular forces, requiring more energy to break the bonds, thus increasing their boiling and melting points.

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Diamond Structure

A three-dimensional network of many carbon atoms, each covalently bonded to four other carbon atoms. This structure is responsible for diamond’s hardness.

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Graphite Structure

In graphite, each carbon atom is covalently bonded to three other carbon atoms, forming layers that are held together by weak forces. These layers can slide over one another, making graphite soft.

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Low melting/boiling point (covalent compounds)

Covalent compounds have low melting and boiling points because the weak intermolecular forces between molecules are easily broken.

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Bigger molecule, higher melting/boiling point

Substances with large molecules have higher melting and boiling points because they experience stronger intermolecular forces, which require more energy to break.

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Doesn’t conduct electricity (covalent compounds)

Covalent compounds don’t conduct electricity because they lack free-moving electrons. Their electrons are fixed within the covalent bonds.

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Study Notes

Ionic Compounds

  • Ionic compounds are composed of positive and negative ions held together by electrostatic forces of attraction
  • These forces are strong, resulting in high melting and boiling points
  • Ionic compounds do not conduct electricity in the solid state but do in the liquid or dissolved states

Metallic Structure

  • Metals have a giant structure of atoms arranged in a regular lattice
  • Metal atoms lose their outer electrons, creating a "sea" of delocalised electrons
  • The delocalised electrons are free to move throughout the structure, explaining their good electrical and thermal conductivity

Covalent Bonding

  • Covalent bonds form between non-metal atoms.
  • A covalent bond involves the sharing of electron pairs between atoms
  • This sharing allows each atom to achieve a stable electron configuration

Diamond

  • Diamond has a giant covalent structure
  • Each carbon atom is covalently bonded to four other carbon atoms in a tetrahedral arrangement
  • This strong bonding leads to extremely high melting and boiling points; also not electrical conductivity

Graphite

  • Graphite has a giant covalent structure where each carbon atom forms covalent bonds with three other carbon atoms
  • This structure creates layers of carbon atoms that are held together by weak forces of attraction
  • The delocalised electrons in the layers allow graphite to conduct electricity
  • The layers can slide over each other, making graphite a good lubricant

Bucky Balls (Fullerenes)

  • Fullerene molecules are hollow cages made of carbon atoms, connected by covalent bonds
  • They have a unique cage-like structure
  • Weak intermolecular forces result in low melting and boiling points
  • They conduct electricity poorly
  • Buckyballs are also known as fullerenes

Allotropes of Carbon

  • Allotropes are different structural forms of the same element
  • Carbon has several allotropes, including diamond, graphite, and fullerenes
  • The different structures lead to different properties and applications
  • Allotropes of carbon show the variety of structures and properties that are possible from a single element.

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