Chemistry Basics Quiz

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Questions and Answers

Which of the following correctly represents sodium sulfide?

  • Na2O
  • NaCl
  • Na2S (correct)
  • Na3P

What is the formula for iron(III) oxide?

  • HgO
  • Hg2O
  • Fe2O3 (correct)
  • FeO

Which element is a transition metal that can form more than one kind of ion?

  • Al
  • Na
  • Cu (correct)
  • Cs

What is the charge on the cation in the compound Fe2O3?

<p>+3 (B)</p> Signup and view all the answers

Which of the following polyatomic ions is a cation?

<p>NH4+ (A)</p> Signup and view all the answers

What is the purpose of coefficients in a balanced chemical equation?

<p>To indicate the number of molecules of each reactant and product (C)</p> Signup and view all the answers

In the reaction C2H6 + 7O2 → 4CO2 + 6H2O, how many total oxygen atoms are present on the product side?

<p>14 (A)</p> Signup and view all the answers

What is a correct balanced equation for the reaction of ethane (C2H6) with oxygen (O2)?

<p>2C2H6 + 7O2 → 4CO2 + 6H2O (C)</p> Signup and view all the answers

When balancing the equation C2H6 + O2 → CO2 + H2O, which element must be balanced last?

<p>Oxygen (C)</p> Signup and view all the answers

Which one of the following statements best describes the application of stoichiometry in everyday life?

<p>It can help determine quantities needed for assembling items like bicycles. (D)</p> Signup and view all the answers

What type of mixture is represented by Image I?

<p>Homogeneous mixture (C)</p> Signup and view all the answers

How is Image II best categorized?

<p>Compound (D)</p> Signup and view all the answers

What does the composition of molecules in Image III indicate?

<p>Compound (A)</p> Signup and view all the answers

Which of the following best describes a physical property of matter?

<p>Melting point (B)</p> Signup and view all the answers

Which option represents a chemical property of matter?

<p>Oxidizing ability (C)</p> Signup and view all the answers

Image I is comprised of similar blue spheres. What can be inferred about its classification?

<p>It contains a single type of element. (B)</p> Signup and view all the answers

The organization of spheres in Image II suggests what about its purity?

<p>It represents a pure compound. (A)</p> Signup and view all the answers

Which of the following statements about the properties of matter is true?

<p>Physical properties can be determined without changing composition. (D)</p> Signup and view all the answers

Which type of radiation was discovered by Ernest Rutherford?

<p>β (beta) particles (A), α (alpha) particles (C), γ (gamma) rays (D)</p> Signup and view all the answers

What does the atomic number (Z) represent?

<p>The number of protons in an atom (A)</p> Signup and view all the answers

How are isotopes defined?

<p>Atoms of the same element with different numbers of neutrons (B)</p> Signup and view all the answers

What is the atomic mass number based on?

<p>The total number of protons and neutrons (C)</p> Signup and view all the answers

Which of the following is true about the mass of subatomic particles?

<p>Protons and neutrons have essentially the same mass (D)</p> Signup and view all the answers

What percentage of carbon isotopes in a natural sample is typically C-12?

<p>98.93% (A)</p> Signup and view all the answers

Which scientist coined the term 'proton'?

<p>Ernest Rutherford (A)</p> Signup and view all the answers

What is the balanced reaction for the formation of ammonia from nitrogen and hydrogen?

<p>N2(g) + 3H2(g) → 2NH3(g) (D)</p> Signup and view all the answers

Which element does not have a stable isotope with mass number 14?

<p>Hydrogen (C)</p> Signup and view all the answers

What is considered the theoretical yield in a chemical reaction?

<p>The maximum product expected under ideal conditions (B)</p> Signup and view all the answers

In the reaction of 2 Al(s) + 3 Cl2(g) → 2 AlCl3(s), if 1.50 mol of Al and 3.00 mol of Cl2 react, what is the limiting reactant?

<p>Al (D)</p> Signup and view all the answers

If 1.50 mol of Al yield 2.00 mol of AlCl3, how many moles of Cl2 remain at the end of the reaction that started with 3.00 mol?

<p>1.00 mole (C)</p> Signup and view all the answers

What is the oxidation state of sulfur in H2S?

<p>-1 (B)</p> Signup and view all the answers

In potassium dichromate (K2Cr2O7), what is the oxidation state of one chromium atom?

<p>6 (A)</p> Signup and view all the answers

What characterizes a strong electrolyte?

<p>dissociates completely in solution (D)</p> Signup and view all the answers

In the reaction FeO (s) + C (s) -> Fe (s) + CO (g), which substance is the reducing agent?

<p>C (B)</p> Signup and view all the answers

What is the oxidation state of sulfur in the polyatomic ion SO42-?

<p>6 (A)</p> Signup and view all the answers

In a single-displacement reaction represented as A + MX -> M + AX, what happens to element A?

<p>It replaces M in the compound (B)</p> Signup and view all the answers

What is the oxidation number of sulfur in sodium sulfite (Na2SO3)?

<p>4 (B)</p> Signup and view all the answers

Flashcards

Element

A substance made up of only one type of atom. An element cannot be broken down into simpler substances by chemical means.

Compound

A substance made up of two or more different elements chemically combined in a fixed ratio. Compounds can be broken down into simpler substances (elements) by chemical means.

Homogeneous Mixture

A mixture that has a uniform composition throughout. The different components are evenly distributed and not easily distinguishable.

Heterogeneous Mixture

A mixture that does not have a uniform composition. The different components are not evenly distributed and can be easily distinguished.

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Physical Property

A characteristic of a substance that can be observed or measured without changing the substance's chemical composition.

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Chemical Property

A characteristic of a substance that describes its ability to undergo a change in chemical composition.

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Physical Change

A change in the form or appearance of a substance, but not in its chemical composition. Physical changes are usually reversible.

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Chemical Change

A change in the chemical composition of a substance. Chemical changes often involve the formation of new substances and are usually irreversible.

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Dalton's atomic theory

Proposed that atoms are indivisible particles and the fundamental building blocks of matter.

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J.J. Thomson's contribution to atomic structure

Discovered electrons and determined their charge-to-mass ratio, contributing to our understanding of atomic structure.

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Millikan's oil drop experiment

Determined the charge of an electron, providing a fundamental constant in physics.

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Radioactivity

The spontaneous emission of radiation from the nucleus of an atom, leading to the transformation of one element into another.

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Rutherford's discovery of radioactive emissions

Identified three types of radioactive emissions: alpha particles (α), beta particles (β), and gamma rays (γ).

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Atomic nucleus

The central part of an atom containing protons and neutrons.

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Neutrons

Neutral particles found in the nucleus of an atom. They contribute to an atom's mass but not its charge.

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Isotopes

Atoms of the same element that have a different number of neutrons, leading to different atomic masses.

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Transition Metal Ions

Transition metals are elements that can have more than one positive charge. The charge of a transition metal ion is indicated using Roman numerals in parentheses following the element's name.

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Writing Ionic Compound Formulas

To determine the formula of an ionic compound, the charge on the cation becomes the subscript on the anion, and vice versa. The subscripts should be in the simplest whole-number ratio.

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Polyatomic Ions

A polyatomic ion is a group of atoms that act as a single charged unit. They often behave as a whole during chemical reactions.

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Common Cations

Commonly encountered cations are those with a positive charge. Ammonium (NH4+) and hydronium (H3O+) are two common examples.

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Which is the transition metal?

Copper (Cu) is a transition metal and can have more than one kind of ion (Cu+ or Cu2+). It has a variable charge.

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Balancing Chemical Equations

The process of balancing a chemical equation to ensure that the number of atoms of each element on the reactant side matches the number of atoms on the product side.

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Stoichiometric Coefficients

The coefficients in a balanced chemical equation represent the relative number of moles of each reactant and product involved in the reaction.

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Stoichiometry

The study of the quantitative relationships between reactants and products in chemical reactions.

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Balanced Chemical Equation

A balanced chemical equation where the number of atoms of each element on the reactant side is equal to the number of atoms on the product side.

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Subscript in Chemical Formula

The number of atoms of a particular element in a molecule is represented by a subscript after the element's symbol.

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Limiting reactant

The reactant that is completely consumed first in a chemical reaction, limiting the amount of product that can be formed.

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Excess reactant

The reactant that is not completely consumed in a chemical reaction, meaning some amount is left over.

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Theoretical yield

The maximum amount of product that can be formed in a reaction based on the stoichiometric coefficients.

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Actual yield

The actual amount of product obtained in a chemical reaction, often less than the theoretical yield due to side reactions or incomplete reactions.

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Percent yield

The ratio of the actual yield to the theoretical yield, expressed as a percentage, indicating the efficiency of a reaction.

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Oxidation Number Rule for Polyatomic Ions

The sum of the oxidation states of all atoms in a polyatomic ion equals the charge of the ion.

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Oxidation State of Elements

The oxidation state of an element in its elemental form is always 0.

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Strong Electrolyte

A strong electrolyte dissociates completely into ions when dissolved in water, producing a solution that conducts electricity strongly.

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Single-Displacement Reaction

A chemical reaction where one element replaces another in a compound. The element with a higher activity replaces the element with a lower activity.

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Oxidizing Agent

A chemical species that gains electrons in a redox reaction, causing the other reactant to be oxidized.

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Reducing Agent

A chemical species that loses electrons in a redox reaction, causing the other reactant to be reduced.

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Oxidized Species

The reactant that gains electrons in a redox reaction, undergoing a decrease in oxidation number.

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Reduced Species

The reactant that loses electrons in a redox reaction, undergoing an increase in oxidation number.

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Study Notes

Chapter 1: The Basics of Chemistry

  • Chemistry is the study of matter, its properties, and the mechanisms involved in its changes.
  • Matter is any substance that has mass and occupies space.
  • The fundamental building blocks of matter are atoms, which cannot be chemically broken down into smaller components.
  • Atoms combine to form larger molecules and compounds.
  • Matter comes in three states: gas, solid, and liquid.

States of Matter

  • Solids: Atoms are closely packed together, relatively stationary, slightly compressible, have a definite shape and volume.
  • Liquids: Atoms are more spread out, have intermediate mobility, slightly compressible, no definite shape, but definite volume.
  • Gases: Atoms are very far apart, high velocities, highly compressible, no definite shape or volume.

Classification of Matter

  • Matter:
    • Pure substance: Cannot be physically separated.
      • Element: Cannot be decomposed chemically.
      • Compound: Can be decomposed chemically.
    • Mixture: Can be physically separated.
      • Homogeneous mixture: Uniform composition (solution).
      • Heterogeneous mixture: Non-uniform composition.

The Scientific Method

  • Develop theories that are consistent with available data.
  • Make observations about nature using experiences, thoughts, and readings.
  • Ask interesting questions.
  • Formulate hypotheses based on observations and questions.
  • Develop testable predictions from hypotheses.
  • Gather data to test predictions and verify results.

Units of Measurement

  • Property | English units | SI units
  • --|---|---
  • Mass* | pounds (lbs) | kilogram (kg)
  • Length* | yard (yd) | Meter (m)
  • Volume* | gallon (gal) | Cubic Meter (m^3)
  • Temperature* | Fahrenheit (°F) | Kelvins (K)

Temperature Scales

  • Conversion formulas for temperature scales: °F = (°C) + 32 °C = (°F - 32)/9 9 * K =°C + 273.15

Significant Figures

  • Report all measurements to one digit past the last digit of certainty.
  • The number of digits in a measurement indicates the precision of the measurement.
  • Zeros between non-zero digits are significant
  • Leading zeros are not significant
  • Trailing zeros after a decimal point are significant

Exact Quantities

  • Quantities whose precision is considered infinite are known as exact numbers
  • Equality statements or conversion factors

Dimensional Analysis

  • Use conversion factors to express a given unit in a different unit
  • The magnitude of the units in the conversion factor has to be the same as the given unit; therefore, the given unit has to be on the bottom and the new unit on the top
  • The magnitude of the units on the top and bottom has to be the same

Density

  • Density is the ratio of mass to volume.
  • Density = mass/volume
  • Density, is a physical property, unique to each substance, and is temperature dependent.
  • Water Density at 20°C = 0.99823 g/mL

Chapter 2: Matter at the Atomic Level

  • Atoms are extremely small, fundamental particles of matter.
  • Atoms of the same element are identical to each other
  • Atoms in chemical reactions are not changed into other elements; atoms are neither created or destroyed.
  • Compounds are formed when atoms of more than one element combine in a fixed, whole-number ratio.
  • Atomic theory
  • J.J. Thomson and the electron
  • Rutherford's gold-foil experiment and the nuclear model of the atom
  • Atomic numbers
  • lons
  • Atomic mass and isotopes
  • The periodic table
  • The mole and Avogadro's number
  • Radioactivity
  • Subatomic particles
  • Symbols of elements, and their relations to atomic numbers and mass numbers
  • Isotopes and their percent natural abundance
  • Average mass calculation
  • Properties of metals, nonmetals and metalloids
  • Using the Periodic Table to predict properties of elements and formations of ions

Important Concepts

  • Atomic number (Z): The number of protons in an atom.
  • Mass number (A): The sum of protons and neutrons in an atom.
  • Isotopes: Atoms of the same element with different mass numbers (different numbers of neutrons).
  • Isotopic abundance: The percentage of each isotope in a naturally occurring sample of an element.
  • Atomic mass: The weighted average of the masses of all the naturally occurring isotopes of an element.
  • Atom: The smallest unit of an element that retains the properties of that element.
  • Mole: A unit that represents 6.022 x 10^23 particles (atoms or molecules).
  • Molar mass: The mass of one mole of a substance in grams/mole

Chapter 3: Molecules, Compounds, and Their Composition

  • Introduction: Importance of compound formulas and naming.
  • Chemical formulas representing compounds.
  • Differentiating ionic and covalent compounds
  • Naming ionic and molecular compounds
  • Molar mass calculation
  • Mass percent calculation
  • Calculating empirical formula
  • Calculating molecular formulas

Chapter 4: Chemical Reactions and Stoichiometry

  • Introduction: Defining chemical reactions and their relevance to understanding chemical systems.
  • Chemical Equations provide a representation of reactants and products.
  • Coefficents are used when balancing chemical equations for conservation of mass, showing the number of moles of each reactant and product in a chemical reaction.
  • Stoichiometry: relates the amounts of compounds or elements involved in a reaction.
  • Using chemical equations/coefficients to calculate the number of moles of reactants/products needed or formed in a reaction.
  • Limiting reactants: The reactant that determines the amount of product that can be formed.
  • Excess reactants: The reactant that is not completely consumed in the reaction.
  • Calculating the percent yield of a chemical reaction and the relationship between theoretical and actual yields.
  • Types of chemical reactions to be aware of: - double replacement (exchange/metathesis - precipitation - acid-base neutralization - gas -forming
  • Reactions in aqueous solutions:
    • solutions/solvents/solutes
    • molarity calculations including using molarity in stoichiometric calculations

Chapter 5: Thermochemistry

  • Introduction to Thermochemistry
  • Energy Types (Kinetic and Potential)
  • Law of Conservation of Energy
  • System and Surrounding
  • Heat and Work relationships
  • Enthalpy of reaction
  • Specific Heat measurement
  • Calorimetry (Coffee cup and Bomb)
  • Hess's Law

Chapter 6: Early Quantum Theory - The Nature of Light and Matter

  • Introduction (Classical Mechanics vs Quantum theory)
  • Electromagnetic Radiation
  • Wavelength and Frequency
  • The Electromagnetic Spectrum
  • Atomic Spectroscopy
  • Planck's constant
  • Bohr Model
  • De Broglie Wavelength
  • The Uncertainty Principle
  • Quantum Mechanics
  • Quantum Numbers
  • Using Quantum Mechanics to describe electron behavior in atoms

Chapter 8: Representing Valence Electrons: Lewis Structures of Atoms, Ions, and Molecules

  • Introduction to Electron Configurations, Lewis Structures
  • Lewis Structures of selected atoms
  • Writing Lewis Structures
  • Formal Charges
  • Resonance
  • Exceptions to the Octet Rule

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