Podcast
Questions and Answers
The Bronsted theory states that an acid is a ______ donor and a base is a ______ acceptor.
The Bronsted theory states that an acid is a ______ donor and a base is a ______ acceptor.
What is the Bronsted-Lowry definition of an acid?
What is the Bronsted-Lowry definition of an acid?
A Bronsted-Lowry acid is a proton donor.
What is the relationship between the strength of an acid and its Ka value?
What is the relationship between the strength of an acid and its Ka value?
Lower Ka values correspond to weaker acids.
What is the relationship between the strength of a base and its Kb value?
What is the relationship between the strength of a base and its Kb value?
What is the relationship between pKa and pKb?
What is the relationship between pKa and pKb?
What is the definition of autoprotolysis of water?
What is the definition of autoprotolysis of water?
What is the pH of pure water at 25°C?
What is the pH of pure water at 25°C?
What is the definition of solvent leveling?
What is the definition of solvent leveling?
According to the Lewis definition, what is an acid?
According to the Lewis definition, what is an acid?
What is the HSAB (Hard and Soft Acid Base) principle?
What is the HSAB (Hard and Soft Acid Base) principle?
What is the difference between hard acids and soft acids?
What is the difference between hard acids and soft acids?
What is the difference between hard bases and soft bases?
What is the difference between hard bases and soft bases?
The strength of acids and bases can be distinguished in solvents like acetic acid or ammonia.
The strength of acids and bases can be distinguished in solvents like acetic acid or ammonia.
What is the main reason for the high density of the nucleus?
What is the main reason for the high density of the nucleus?
Why are isotopes with even numbers of protons and neutrons generally more stable?
Why are isotopes with even numbers of protons and neutrons generally more stable?
What is the main reason for the radioactive decay of an unstable nucleus?
What is the main reason for the radioactive decay of an unstable nucleus?
What are the four main types of radioactive decay?
What are the four main types of radioactive decay?
What is the unit of measurement for radioactivity?
What is the unit of measurement for radioactivity?
What is the definition of half-life in terms of radioactive decay?
What is the definition of half-life in terms of radioactive decay?
What is the principle of binding energy as it relates to nuclear stability?
What is the principle of binding energy as it relates to nuclear stability?
What is the significance of the mass defect in relation to binding energy?
What is the significance of the mass defect in relation to binding energy?
What is the difference between nuclear fission and nuclear fusion?
What is the difference between nuclear fission and nuclear fusion?
What are the key factors that influence the rate of a nuclear reaction?
What are the key factors that influence the rate of a nuclear reaction?
What is the meaning of a chain reaction in the context of nuclear fission?
What is the meaning of a chain reaction in the context of nuclear fission?
What is meant by critical mass in nuclear fission?
What is meant by critical mass in nuclear fission?
What are some of the major applications of radioactivity in various fields?
What are some of the major applications of radioactivity in various fields?
Flashcards
Acid
Acid
A substance that donates a proton (H+) in a chemical reaction.
Base
Base
A substance that accepts a proton (H+) in a chemical reaction.
Conjugate acid
Conjugate acid
The species formed when a base accepts a proton.
Conjugate base
Conjugate base
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pH
pH
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Strong acid/base
Strong acid/base
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Weak acid/base
Weak acid/base
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Acid Dissociation Constant (Ka)
Acid Dissociation Constant (Ka)
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Base Dissociation Constant (Kb)
Base Dissociation Constant (Kb)
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Autoionization of water
Autoionization of water
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pKa
pKa
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pKb
pKb
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Kw
Kw
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Superacids
Superacids
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Half-life
Half-life
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Radioactive decay
Radioactive decay
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pH scale
pH scale
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Neutralization reaction
Neutralization reaction
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Buffer
Buffer
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Study Notes
Acids and Bases
- Arrhenius (1884): Acids produce hydrogen ions (H+) in water; bases produce hydroxide ions (OH-) in water.
- Brønsted-Lowry (1923): An acid is a proton donor; a base is a proton acceptor.
- Conjugate acid-base pairs: Formed when an acid donates a proton and a base accepts it.
- Proton transfer reaction: An acid transfers a proton to a base, forming a conjugate acid-base pair.
Acid & Base Strength
- Ka (acid dissociation constant): A measure of an acid's strength. A larger Ka indicates a stronger acid.
- Kb (base dissociation constant): A measure of a base's strength. A larger Kb indicates a stronger base.
- pKa and pKb: Negative logarithm of Ka and Kb, respectively. Lower pKa/pKb values indicate stronger acids/bases.
Strength of acids and bases
- Strength of an acid or base can vary depending on the solvent.
- Solvent leveling effect: Very strong acids and bases may exhibit the same strength in a given solvent because the solvent itself participates in the reaction; stronger acids are "leveled" to the strength of the solvent.
- Autoprotolysis of water (self-ionization of water):
Water can act as both an acid and a base.
Lewis Acids and Bases
- Lewis acid: Accepts a pair of electrons.
- Lewis base: Donates a pair of electrons.
Gas Phase Acid-Base and Proton Affinity
- Gas-phase proton affinity (PA): The enthalpy change when a proton is added to a molecule in the gas phase.
- Gas-phase acidity: The tendency of a molecule to lose a proton in the gas phase.
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