Chemistry 108: Electronic Configurations and Atomic/Ionic Radii of Lanthanum and Lanthanoids
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Questions and Answers

What causes the almost identical radii of Zr and Hf?

  • Lanthanoid expansion
  • Atomic number increase
  • Lanthanoid contraction (correct)
  • Transition series expansion

What is the predominant oxidation state for lanthanoids according to the text?

  • +3 (correct)
  • +4
  • +5
  • +2

Which lanthanoid exhibits both +2 and +3 oxidation states?

  • Dysprosium
  • Samarium
  • Promethium
  • Europium (correct)

Why does Ce(IV) form favorably in compounds according to the text?

<p>Extra stability of empty f subshell (B)</p> Signup and view all the answers

Which lanthanoid exhibits the +4 oxidation state only in oxides?

<p>Terbium (A)</p> Signup and view all the answers

Which electronic configuration is common among lanthanoids?

<p>6s2 and variable occupancy of 4f level (A)</p> Signup and view all the answers

What is the general formula for the electronic configurations of tripositive ions of lanthanoids?

<p>4f n (n = 1 to 14) (A)</p> Signup and view all the answers

What is the cause attributed to the overall decrease in atomic and ionic radii from lanthanum to lutetium?

<p>Imperfect shielding of one electron by another in the same sub-shell (B)</p> Signup and view all the answers

What is unique about the lanthanoid contraction compared to an ordinary transition series?

<p>Fairly regular decrease in atomic and ionic sizes with increasing atomic number (B)</p> Signup and view all the answers

What effect does an increase in nuclear charge have along the lanthanoid series?

<p>Shielding of one f electron by another is less than one d electron by another (C)</p> Signup and view all the answers

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