Chemical Thermodynamics Experiment 1: Heat of Solution of Oxalic Acid

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Questions and Answers

What property of a substance does solubility depend on?

Temperature and pressure

How is the extent of solubility measured?

By the saturation concentration

Which equation relates the change in temperature to the enthalpy change for the process?

Vant Hoff's equation

What is the significance of the equivalent weight of oxalic acid in determining its solubility?

<p>It helps in calculating the solubility accurately</p> Signup and view all the answers

Which equipment is NOT mentioned in the experimental procedure for determining the heat of solution?

<p>Bunsen burner</p> Signup and view all the answers

What does ln 𝑆 represent in Vant Hoff's equation?

<p>Logarithm of solubility</p> Signup and view all the answers

'S' in the Vant Hoff's equation stands for:

<p>Saturation concentration</p> Signup and view all the answers

What role does temperature play in determining solubility?

<p>It increases solubility.</p> Signup and view all the answers

Why is it important to label beakers in the experimental procedure?

<p>To avoid cross-contamination.</p> Signup and view all the answers

Study Notes

Solubility and Temperature

  • Solubility of a substance depends on its intrinsic properties and the solvent used.
  • The extent of solubility is measured by the maximum amount of solute that can dissolve in a given amount of solvent at a specific temperature.

Enthalpy Change and Temperature

  • The van 't Hoff equation relates the change in temperature to the enthalpy change (ΔH) for the process: ΔH = R * lnKeq / (1/T1 - 1/T2).
  • The equation indicates that a change in temperature affects the equilibrium constant (Keq) and subsequently the solubility of a substance.

Vant Hoff's Equation

  • ln 𝑆 represents the natural logarithm of the solubility (𝑆) in Vant Hoff's equation.
  • 'S' in Vant Hoff's equation stands for solubility.

Temperature and Solubility

  • Temperature plays a significant role in determining solubility, as a change in temperature can alter the solubility of a substance.

Experimental Procedure

  • Labeling beakers is important to avoid contamination and ensure accurate results in the experimental procedure for determining the heat of solution.
  • The equipment used in the experimental procedure includes a polystyrene calorimeter, a thermometer, and a stirrer, among others. The equipment NOT mentioned is a burette.

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