Chemical Thermodynamics Experiment 1: Heat of Solution of Oxalic Acid
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Questions and Answers

What property of a substance does solubility depend on?

  • Atomic number and mass
  • Density and volume
  • Color and odor
  • Temperature and pressure (correct)
  • How is the extent of solubility measured?

  • By the volume of the solution
  • By the saturation concentration (correct)
  • By the mass of the solute
  • By the color change in the solvent
  • Which equation relates the change in temperature to the enthalpy change for the process?

  • Einstein's equation
  • Vant Hoff's equation (correct)
  • Avogadro's equation
  • Boyle's Law equation
  • What is the significance of the equivalent weight of oxalic acid in determining its solubility?

    <p>It helps in calculating the solubility accurately</p> Signup and view all the answers

    Which equipment is NOT mentioned in the experimental procedure for determining the heat of solution?

    <p>Bunsen burner</p> Signup and view all the answers

    What does ln 𝑆 represent in Vant Hoff's equation?

    <p>Logarithm of solubility</p> Signup and view all the answers

    'S' in the Vant Hoff's equation stands for:

    <p>Saturation concentration</p> Signup and view all the answers

    What role does temperature play in determining solubility?

    <p>It increases solubility.</p> Signup and view all the answers

    Why is it important to label beakers in the experimental procedure?

    <p>To avoid cross-contamination.</p> Signup and view all the answers

    Study Notes

    Solubility and Temperature

    • Solubility of a substance depends on its intrinsic properties and the solvent used.
    • The extent of solubility is measured by the maximum amount of solute that can dissolve in a given amount of solvent at a specific temperature.

    Enthalpy Change and Temperature

    • The van 't Hoff equation relates the change in temperature to the enthalpy change (ΔH) for the process: ΔH = R * lnKeq / (1/T1 - 1/T2).
    • The equation indicates that a change in temperature affects the equilibrium constant (Keq) and subsequently the solubility of a substance.

    Vant Hoff's Equation

    • ln 𝑆 represents the natural logarithm of the solubility (𝑆) in Vant Hoff's equation.
    • 'S' in Vant Hoff's equation stands for solubility.

    Temperature and Solubility

    • Temperature plays a significant role in determining solubility, as a change in temperature can alter the solubility of a substance.

    Experimental Procedure

    • Labeling beakers is important to avoid contamination and ensure accurate results in the experimental procedure for determining the heat of solution.
    • The equipment used in the experimental procedure includes a polystyrene calorimeter, a thermometer, and a stirrer, among others. The equipment NOT mentioned is a burette.

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    Description

    This quiz focuses on determining the heat of solution of oxalic acid by measuring its solubility in water at different temperatures. The Vant Hoff's equation is utilized to relate the change in temperature to the enthalpy change. Apparatus, chemicals, and theory related to solubility are covered in this experiment.

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