Chemical Reactions of Acids and Bases

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Questions and Answers

What products are formed when metallic oxides react with acids?

  • Hydrogen gas and a base
  • Salt and water (correct)
  • Only Salt
  • Salt and carbon dioxide

What is the general nature of non-metallic oxides?

  • Neutral
  • Basic
  • Acidic (correct)
  • Amphoteric

What products are formed when carbon dioxide reacts with calcium hydroxide (lime water)?

  • Only water
  • Acid and base
  • Salt and water (correct)
  • Only salt

Why should curd and sour substances not be kept in brass and copper vessels?

<p>To prevent a reaction between the acids in the food and the metal (A)</p> Signup and view all the answers

What gas is typically released when an acid reacts with a metal?

<p>Hydrogen (B)</p> Signup and view all the answers

What is a common product when both acids and bases react?

<p>Salt (D)</p> Signup and view all the answers

What is the general term for oxides that react with acids to form salts and water?

<p>Basic oxides (C)</p> Signup and view all the answers

Which gas extinguishes a burning candle?

<p>Carbon dioxide (B)</p> Signup and view all the answers

What is common to all acids?

<p>Hydrogen (A)</p> Signup and view all the answers

What is produced when metal compound A reacts with dilute hydrochloric acid?

<p>Effervescence (C)</p> Signup and view all the answers

If a metal oxide reacts with an acid and forms salt and water, what is the nature of the metal oxide?

<p>Basic (B)</p> Signup and view all the answers

A non-metallic oxide reacts with a base to produce salt and water. What can you infer about the nature of this non-metallic oxide?

<p>It is acidic (D)</p> Signup and view all the answers

Which of the following best describes the expected outcome when sulfur trioxide ($\text{SO}_3$) is bubbled through a solution of potassium hydroxide ($\text{KOH}$)?

<p>A neutral salt and water will form. (C)</p> Signup and view all the answers

Why is it chemically unsound to store lemon juice in a container made of aluminum?

<p>The citric acid in lemon juice could react with the aluminum. (C)</p> Signup and view all the answers

When dilute hydrochloric acid reacts with magnesium metal, a gas is produced. What experimental method would confirm the identity of this gas?

<p>Observing if it extinguishes a flame with a 'pop' sound (A)</p> Signup and view all the answers

A metal carbonate, $XCO_3$, reacts with hydrochloric acid to produce a gas that turns limewater milky. Besides the gas, what other products would you expect to find in the resulting solution?

<p>Only metal chloride and water (A)</p> Signup and view all the answers

Which statement explains why acids have similar chemical properties?

<p>They all produce hydrogen ions in solution. (B)</p> Signup and view all the answers

Based on Activity 2.8, what is the most accurate conclusion regarding compounds containing hydrogen?

<p>Not all hydrogen-containing compounds are acidic. (A)</p> Signup and view all the answers

A student mixes a solution of acetic acid ($CH_3COOH$) with a solution of sodium hydroxide ($NaOH$). Which of the following correctly describes the resulting solution?

<p>It will be acidic, basic, or neutral depending on the amounts of each solution used. (A)</p> Signup and view all the answers

Which observation would lead you least likely to classify an unknown substance as an acid?

<p>It tastes bitter. (D)</p> Signup and view all the answers

If element X forms an oxide that reacts with both acids and bases, what term best describes this oxide?

<p>Amphoteric oxide (C)</p> Signup and view all the answers

When a non-metallic oxide reacts with water, what is the likely result?

<p>Formation of an acid (D)</p> Signup and view all the answers

Consider a solution where a metal oxide reacts with an acid. If the resulting solution is tested with a universal indicator and turns green, what does this indicate about the solution?

<p>The solution is neutral (C)</p> Signup and view all the answers

If you have two solutions, one of hydrochloric acid ($HCl$) and the other of sodium hydroxide ($NaOH$), how would you determine which one is acidic and which one is basic without tasting them?

<p>Test them with litmus paper; acids turn blue litmus red, and bases turn red litmus blue. (B)</p> Signup and view all the answers

Vinegar, which contains acetic acid, can react with baking soda (sodium bicarbonate). What products would you expect from this reaction?

<p>A salt, water, and carbon dioxide (D)</p> Signup and view all the answers

A student tests a solution with both red and blue litmus paper. The red litmus paper turns blue, while the blue litmus paper remains blue. What can the student conclude?

<p>The solution is basic (C)</p> Signup and view all the answers

Magnesium oxide ($MgO$) is added to water, and the mixture is stirred. What would you expect the resulting solution to be?

<p>A basic solution (B)</p> Signup and view all the answers

If a solution of hydrochloric acid is electrolyzed, which gas would you expect to be liberated at the anode (positive electrode)?

<p>Chlorine (B)</p> Signup and view all the answers

Which of the following describes what happens when dilute hydrochloric acid ($HCl$) is added to copper oxide ($CuO$)?

<p>A reaction occurs, forming copper chloride and water. (D)</p> Signup and view all the answers

Suppose you accidentally spill some strong acid on the floor. Which of the following actions is the MOST appropriate first step to neutralize the spill?

<p>Sprinkle baking soda (sodium bicarbonate) over the spill. (D)</p> Signup and view all the answers

Consider a scenario where a metal oxide reacts with a strong acid, forming a salt and water. If the resulting solution is then evaporated, leaving behind a solid residue, what would you expect the composition of this residue to be?

<p>Only the salt formed from the reaction. (A)</p> Signup and view all the answers

A student investigates the reaction between various oxides and solutions. Which of the following observations would provide the STRONGEST evidence that a particular oxide is amphoteric?

<p>It reacts with both strong acids and strong bases. (C)</p> Signup and view all the answers

When non-metallic oxide $X$ reacts with a base, it forms salt $Y$ and water. If salt $Y$ is then treated with a strong acid, which of the following outcomes would provide the best evidence that the original reaction was indeed an acid-base neutralization?

<p>The original non-metallic oxide X is regenerated. (C)</p> Signup and view all the answers

Consider the reaction between a metal and an acid in an open container. Which of the following factors would MOST significantly affect the rate of hydrogen gas production?

<p>The temperature of the acid. (D)</p> Signup and view all the answers

A student notices effervescence when a metal is added to hydrochloric acid and wants to ensure the evolved gas is hydrogen. Which of the following control experiments would BEST validate the student's conclusion?

<p>Collecting the gas and testing it with a glowing splint and comparing to a known sample of $CO_2$. (D)</p> Signup and view all the answers

Aqueous solutions of equimolar concentrations of hydrochloric acid ($HCl$) and acetic acid ($CH_3COOH$) are prepared. Which of the following statements accurately compares their properties?

<p>The hydrochloric acid solution will have a lower pH and higher electrical conductivity. (B)</p> Signup and view all the answers

A student is given a solid and told it is either a metal, metal oxide or non-metal oxide. When added to water, it forms an acidic solution. What can be definitively concluded about the solid?

<p>The solid is a non-metal oxide. (A)</p> Signup and view all the answers

Consider a scenario where metal X reacts with dilute sulfuric acid to produce hydrogen gas. If the rate of gas production decreases significantly over time, despite the continued presence of both metal and acid, which of the following is the MOST likely explanation?

<p>A coating of the metal sulfate is forming on the metal surface, hindering further reaction. (D)</p> Signup and view all the answers

A student performs an experiment where they react zinc metal with hydrochloric acid in a closed container. The gas produced is collected and analyzed. How would increasing the concentration of hydrochloric acid affect the pressure inside the container, assuming a constant temperature?

<p>It would increase the pressure due to increased hydrogen gas production. (B)</p> Signup and view all the answers

If both hydrochloric acid ($HCl$) and nitric acid ($HNO_3$) solutions of equal molarity are tested for electrical conductivity, which of the following observations would be expected, and what accounts for this difference?

<p>Both exhibit similar conductivity because they are both strong acids and completely dissociate in the solution. (A)</p> Signup and view all the answers

Consider a scenario where a novel metallic oxide, $M_2O_3$, is reacted with a Brnsted-Lowry superacid, $H_3O^+ SbF_5^-$, in anhydrous conditions. Given the propensity of superacids to fully protonate even weakly basic species, which of the following represents the most probable outcome, assuming complete reaction and formation of stable products?

<p>Protonation of the oxide lattice leading to the formation of $(MOH_2)_2(SbF_6)_6$ with retention of the oxide structure. (B)</p> Signup and view all the answers

A researcher discovers a new allotrope of carbon that forms a stable oxide, $C_5O_2$. When this oxide is bubbled through a concentrated solution of tetraethylammonium hydroxide ($(C_2H_5)_4NOH$), what is the most likely outcome, assuming standard conditions and complete reaction?

<p>Formation of a complex tetraethylammonium salt with a polymeric oxycarbon backbone, represented as $[(C_2H_5)_4N]_2[C_5O_3]_n$. (B)</p> Signup and view all the answers

Imagine a scenario where zirconium metal reacts with concentrated perchloric acid ($HClO_4$). Considering the known passivity of zirconium due to surface oxide layer formation and the strong oxidizing nature of perchloric acid, what is the most probable initial product formed during this reaction under standard conditions?

<p>$ZrO(ClO_4)_2 \cdot xH_2O$ involving the initial dissolution of the passive oxide layer followed by perchlorate coordination. (A)</p> Signup and view all the answers

Aqueous solutions of hydrofluoric acid ($HF$) are uniquely corrosive to silicate glasses ($SiO_2$). If a glass apparatus is used to contain a solution of $HF$, what are the most probable primary reaction products formed during this interaction?

<p>$H_2SiF_6(aq)$ and $H_2O(l)$, resulting in the gradual dissolution of the glass. (A)</p> Signup and view all the answers

Consider a novel electrochemical cell employing a metal oxide ($MO_2$) as a catalytic electrode for oxygen evolution in a highly alkaline electrolyte (10M $KOH$). If the overpotential for oxygen evolution is observed to decrease significantly upon surface treatment of the $MO_2$ electrode with a thin layer of a redox-active polymer, such as poly(vinylferrocene), which of the following mechanisms BEST explains this enhancement?

<p>The polymer undergoes redox cycling, providing a lower energy pathway for the multi-electron transfer process of oxygen evolution. (D)</p> Signup and view all the answers

A graduate student attempts to synthesize a new metal-organic framework (MOF) using zinc oxide ($ZnO$) and a novel tetratopic organic linker containing carboxylic acid functional groups in a solvothermal reaction. Upon characterization, the resulting material is amorphous instead of crystalline. Which modification to the reaction conditions is MOST likely to promote the formation of a crystalline MOF?

<p>Adding a modulating agent (e.g., acetic acid) to control the deprotonation rate of the carboxylic acid groups. (A)</p> Signup and view all the answers

A materials scientist is investigating the catalytic activity of a series of transition metal oxides for CO oxidation. They observe that the activity correlates strongly with the concentration of oxygen vacancies on the oxide surface. Which of the following statements BEST explains the role of oxygen vacancies in promoting CO oxidation?

<p>Oxygen vacancies weaken the metal-oxygen bond, promoting oxygen dissociation and subsequent reaction with CO. (C)</p> Signup and view all the answers

In a newly developed solid-state battery, a lithium lanthanum titanate (LLTO) perovskite ($Li_{0.34}La_{0.51}TiO_3$) is used as the solid electrolyte. However, during operation at elevated temperatures, the battery exhibits a rapid capacity fade due to the formation of an interfacial layer between the LLTO electrolyte and the lithium metal anode. Which of the following strategies is MOST likely to mitigate this issue?

<p>Introducing a thin buffer layer of lithium fluoride (LiF) between the LLTO and the lithium metal. (B)</p> Signup and view all the answers

Consider a scenario where a novel semiconductor quantum dot (QD) composed of cadmium sulfide ($CdS$) is synthesized and used for photocatalytic hydrogen production. After extensive characterization, it is discovered that the QDs exhibit extremely low quantum yield for hydrogen evolution due to rapid electron-hole recombination. Which of the following modifications is MOST likely to enhance the photocatalytic activity of these $CdS$ QDs?

<p>Surface passivation of the $CdS$ QDs with zinc sulfide ($ZnS$) to reduce surface defects acting as recombination centers. (D)</p> Signup and view all the answers

A chemist is investigating the reaction between a complex cobalt oxide, $La_{1-x}Sr_xCoO_{3-\delta}$ (LSC), and sulfur dioxide ($SO_2$) at high temperatures. This reaction is crucial in the development of sulfur-resistant catalysts for various industrial processes. Given that LSC can exhibit non-stoichiometry with oxygen vacancies ($\delta$) and that $SO_2$ is an acidic oxide, which of the following reaction pathways is MOST thermodynamically favorable?

<p>$SO_2$ reacts with lattice oxygen in LSC to form $SO_3$, while increasing the concentration of oxygen vacancies. (B)</p> Signup and view all the answers

Based on the general reaction between metallic oxides and acids, what type of compound is typically formed in addition to water?

<p>A salt (B)</p> Signup and view all the answers

If a non-metallic oxide reacts with a base, which products are most likely to be formed?

<p>A salt and water (B)</p> Signup and view all the answers

Why are metallic oxides generally considered to be basic oxides?

<p>They react with acids to form salts and water. (A)</p> Signup and view all the answers

Metal compound A reacts with dilute hydrochloric acid to produce effervescence, and the gas released extinguishes a burning candle. If one product of the reaction is calcium chloride, what is the identity of metal compound A?

<p>Calcium carbonate (A)</p> Signup and view all the answers

When a non-metallic oxide, such as sulfur dioxide ($SO_2$), reacts with water, what is the likely result?

<p>Formation of an acid (B)</p> Signup and view all the answers

Consider a scenario where a student mixes hydrochloric acid ($HCl$) with an unknown substance and observes effervescence. The gas produced turns limewater milky. What can be concluded about the unknown substance?

<p>The substance is likely a carbonate. (B)</p> Signup and view all the answers

A student tests a gas produced from a chemical reaction and finds that it extinguishes a burning splint and turns limewater milky. Which gas is MOST likely present?

<p>Carbon Dioxide (A)</p> Signup and view all the answers

When a non-metallic oxide reacts with a strong base, such as sodium hydroxide ($NaOH$), in aqueous solution, what primary interaction governs the chemical outcome at a molecular level?

<p>Nucleophilic addition of hydroxide ions to the non-metallic oxide, followed by the formation of a salt and water. (D)</p> Signup and view all the answers

A research team is investigating the reaction mechanism between a novel superacid, $H(CB_{11}H_6Cl_6)$, and a weakly basic metal oxide nanoparticle, $TiO_2$, in a non-aqueous solvent. Given the extreme proton donating ability of the superacid, which of the following initial steps is MOST likely to occur?

<p>Protonation of the surface oxygen atoms of $TiO_2$ by the superacid, forming $Ti-OH^+$ groups and generating a positively charged nanoparticle surface. (A)</p> Signup and view all the answers

Metallic oxides are considered basic oxides because they react with acids in a manner similar to:

<p>A base with an acid. (C)</p> Signup and view all the answers

Non-metallic oxides are generally considered acidic because they:

<p>React with bases to form salts and water. (D)</p> Signup and view all the answers

If a solution containing calcium hydroxide is exposed to carbon dioxide, what will likely happen?

<p>A white precipitate of calcium carbonate will form. (A)</p> Signup and view all the answers

What is a key characteristic shared by all acids, according to the text?

<p>They all produce hydrogen gas when reacting with metals. (D)</p> Signup and view all the answers

Assuming the general properties discussed, what type of oxide is $SO_2$?

<p>Acidic Oxide (B)</p> Signup and view all the answers

Based on the activity described with glucose, alcohol, hydrochloric acid, and sulfuric acid, what is being investigated?

<p>Whether all hydrogen-containing compounds are acidic. (B)</p> Signup and view all the answers

A student finds that a gas produced during a reaction extinguishes a burning candle and forms a white precipitate when bubbled through limewater. If the reaction also produces calcium chloride, what was likely one of the reactants?

<p>Calcium carbonate (A)</p> Signup and view all the answers

Why are certain food items not recommended in brass and copper vessels?

<p>Acids in the food can react with the metal, forming toxic compounds. (A)</p> Signup and view all the answers

A newly discovered oxide, $X_2O_3$, reacts vigorously with both hydrochloric acid ($HCl$) and sodium hydroxide ($NaOH$), forming salts and water in each case. What can be definitively concluded about the nature of $X_2O_3$?

<p>It is amphoteric. (A)</p> Signup and view all the answers

A researcher prepares several solutions: hydrochloric acid ($HCl$), acetic acid ($CH_3COOH$), ethanol ($C_2H_5OH$), and sucrose ($C_{12}H_{22}O_{11}$). Each solution has the same concentration of hydrogen atoms. Which solution will exhibit the LOWEST electrical conductivity?

<p>Sucrose ($C_{12}H_{22}O_{11}$) (A)</p> Signup and view all the answers

Flashcards

Basic Oxides

Metallic oxides that react with acids to form salts and water.

Reaction of Non-metallic Oxides

Reaction between non-metallic oxides and bases to form salts and water.

Example of Non-metallic Oxide Reaction

Carbon dioxide reacts with calcium hydroxide to produce calcium carbonate and water.

Acids and Metals

Acids typically liberate hydrogen gas when reacting with metals.

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Effervescence

Bubbling or fizzing due to gas release in a reaction.

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Calcium Chloride Formation

Produced when calcium reacts with hydrochloric acid in the form of a balanced equation.

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Common Property of Acids

All acids generate hydrogen ions or gas during reactions.

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Testing for Hydrogen Gas

A lit candle extinguishes in the presence of hydrogen gas.

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Acidity of Certain Compounds

Hydrogen-containing compounds like glucose and alcohol can be tested for acidity.

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Hydrochloric Acid

A strong acid that reacts with metals to produce hydrogen and salts.

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Metallic Oxides

Metal oxides that react with acids to produce salts and water.

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Basic Nature of Metallic Oxides

Metallic oxides are classified as basic oxides due to their reaction with acids.

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Reaction with Carbon Dioxide

Calcium hydroxide reacts with carbon dioxide to form calcium carbonate and water.

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Acidic Nature of Non-metallic Oxides

Non-metallic oxides react with bases to produce salts and water, indicating acidity.

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Curd and Brass/Copper Interaction

Keeping curd in brass/copper can lead to unwanted reactions, affecting taste.

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Gas Liberated from Acids

When acids react with metals, hydrogen gas is typically released.

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Testing for Gas Liberation

To test for hydrogen, use a lit candle; it extinguishes if hydrogen is present.

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Reaction of Metal with Hydrochloric Acid

Metal compound A reacts with hydrochloric acid, producing calcium chloride and hydrogen.

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Hydrogen's Role in Acidity

Hydrogen is common in all acids and contributes to their properties.

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Acidity Investigation Activity

Test various compounds to see if they produce hydrogen ions, indicating acidity.

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Metallic Oxides and Acids

Metallic oxides react with acids to form salts and water, indicating they are basic oxides.

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Non-metallic Oxides and Bases

Non-metallic oxides react with bases to produce salts and water, indicating their acidic nature.

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Calcium Hydroxide Reaction

Calcium hydroxide reacts with carbon dioxide to form calcium carbonate and water.

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Hydrogen in Acids

All acids generate hydrogen gas when reacting with metals, a key characteristic.

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Effervescence from Acids

Effervescence is the bubbling caused by gas release, often seen in acid reactions.

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Testing for Acidity

An activity where compounds like glucose are tested for their acidic properties.

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Curd and Metal Interaction

Curd and sour substances shouldn't be kept in brass/copper due to reactions that may occur.

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Gas from Metal-Acid Reaction

When a metal reacts with an acid, hydrogen gas is often liberated, producing effervescence.

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Balanced Chemical Equation

The balanced equation shows the precise amounts of reactants and products in a chemical reaction.

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Commonality of Acids

All acids possess hydrogen, which contributes to their similar properties and reactions.

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Basic Oxides Reaction

Metallic oxides react with acids to produce salts and water.

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Carbon Dioxide and Calcium Hydroxide

Carbon dioxide reacts with calcium hydroxide to form calcium carbonate and water.

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Hydrogen Gas Production

Acids liberate hydrogen gas when reacting with metals.

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Effervescence Due to Gas

Effervescence is the bubbling or fizzing that occurs when gas is released in a reaction.

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Curd and Copper Interaction

Curd and sour substances can react with brass/copper containers, affecting flavor.

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Basic Nature of Non-metallic Oxides

Non-metallic oxides react with bases to produce salts and water, indicating acidity.

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Common Reaction of Acids

When acids react with metals, they generate hydrogen gas, a key characteristic of acids.

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Effervescence from Acid-Base Reactions

Effervescence refers to the bubbling that occurs due to gas release during reactions with acids or bases.

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Acids Generating Hydrogen

All acids release hydrogen ions in reactions, making hydrogen essential to acid properties.

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Acidic Characteristics of Compounds

Not all compounds with hydrogen are acidic; true acidity is determined by behavior in reactions.

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Metal Compounds with Hydrochloric Acid

Metal compound A when reacting with hydrochloric acid produces calcium chloride and hydrogen gas.

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Balancing Chemical Equation

The process of equalizing reactants and products in a chemical reaction.

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Basic Oxide Definition

Metallic oxides known to react with acids to form salts and water.

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Acidic Non-metallic Oxides

Non-metallic oxides that typically react with bases to yield salts and water.

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Hydrogen Generation in Acids

Acids produce hydrogen gas when they react with metals.

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Reaction Products: Salt and Water

When acids and bases react, they typically produce salt and water.

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Reactivity of Curd and Metals

Curd shouldn’t be stored in brass/copper due to potential reactions.

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Gas Testing Method

A lit candle extinguishes when hydrogen gas is present.

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Effervescence Indicator

Bubbling due to gas release during chemical reactions.

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Activity for Acidity Investigation

An experiment testing compounds for acidic nature through reactions.

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Metallic Oxide Reaction

Metallic oxides react with acids to produce salts and water.

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Calcium Hydroxide and CO2

Calcium hydroxide reacts with carbon dioxide to form calcium carbonate and water.

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Hydrogen Gas in Acid Reactions

Hydrogen gas is released when an acid reacts with a metal.

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Effervescent Reactions

Effervescence is the bubbling due to gas release in a reaction.

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Curd in Metal Containers

Curd should not be kept in brass or copper due to reactions affecting flavor.

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Balanced Chemical Equation Importance

Balanced chemical equations represent equal quantities of reactants and products.

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Acidity of Hydrogen Compounds

Not all compounds containing hydrogen are acidic; acidity depends on behavior in reactions.

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Effect of Bases on Acids

Bases react with acids to form salts and water, showcasing their neutralization.

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Study Notes

Non-Metallic Oxide Reaction with Base

  • Non-metallic oxides react with bases, similar to acids reacting with bases.
  • Carbon dioxide reacts with calcium hydroxide (limewater) to form calcium carbonate and water. This is similar to the reactions between bases and acids.
  • Metallic oxides also react with acids to produce salts and water.

Acid and Base Properties

  • Acids and bases share similar chemical properties.
  • Acids produce hydrogen gas when reacting with metals.
  • Investigating if all hydrogen-containing compounds are acidic is a key area to explore.
  • It has been observed that acids have similar properties, which can be seen when reacting with metals to produce hydrogen gas. This points to a common property in all acids.

Metal and Acid Reaction

  • Acids react with some metals, producing effervescence (bubbles).
  • The gas produced can extinguish a lit candle (an indication of carbon dioxide or similar gas).
  • Example: A reaction with dilute hydrochloric acid produces effervescence and a gas that extinguishes a burning candle. This gas may be related to calcium chloride formation.
  • The reaction produces a gas that extinguishes a candle, potentially involving a compound like calcium chloride.
  • A balanced chemical equation for the reaction should be written if one of the products is calcium chloride.
  • Curd and sour substances should not be kept in brass or copper vessels.

Acid Solution Electrical Conductivity

  • Acid solutions in water conduct electricity.
  • Solutions like glucose or alcohol do not conduct electricity.
  • This can be shown experimentally by connecting nails to a cork and placing them in a beaker of acid or in solutions like glucose, alcohol, hydrochloric acid, and sulfuric acid to see whether the bulb glows.
  • The experiment should be repeated with different solutions (e.g., glucose, alcohol, sulfuric acid) to compare their conductivity.
  • Solutions of glucose, alcohol, hydrochloric acid, and sulphuric acid can be tested to see if they conduct electricity.

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