Chemical Reactions and Stoichiometry

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Questions and Answers

Which statement best describes the relationship between pH, $[H^+]$ concentration, and acidity?

  • Lower pH indicates higher $[H^+]$ concentration and increased acidity. (correct)
  • Higher pH indicates lower $[H^+]$ concentration and increased acidity.
  • Higher pH indicates higher $[H^+]$ concentration and increased acidity.
  • Lower pH indicates lower $[H^+]$ concentration and increased acidity.

A solution has a pH of 3.0. If water is added to dilute the solution, which of the following is most likely to occur?

  • The pH will approach 7.0. (correct)
  • The pH will become more acidic.
  • The pH will remain constant.
  • The pH will decrease.

Which of the following is the best example of an amphoteric substance?

  • Sodium hydroxide (NaOH)
  • Water ($H_2O$) (correct)
  • Ammonia ($NH_3$)
  • Hydrochloric acid (HCl)

In a titration experiment, 20.0 mL of 0.1 M HCl is required to neutralize 10.0 mL of a NaOH solution. What is the molarity of the NaOH solution?

<p>0.2 M (C)</p> Signup and view all the answers

A buffer solution is prepared using a weak acid HA and its conjugate base $A^-$. If the $pK_a$ of HA is 4.5, at what pH will the concentrations of HA and $A^-$ be equal?

<p>pH = 4.5 (C)</p> Signup and view all the answers

Which of the following statements accurately describes the role of buffers in biological systems?

<p>Buffers maintain a stable pH by neutralizing small amounts of added acid or base. (A)</p> Signup and view all the answers

What is the pH of a neutral solution at standard conditions?

<p>7 (A)</p> Signup and view all the answers

Which of the following statements correctly distinguishes between strong and weak acids?

<p>Strong acids completely dissociate in water, while weak acids only partially dissociate. (B)</p> Signup and view all the answers

Which of the following is a correct application of the Bronsted-Lowry acid-base theory?

<p>A Bronsted-Lowry base is a proton acceptor. (A)</p> Signup and view all the answers

A solution with a pH of 9 is considered:

<p>Basic (D)</p> Signup and view all the answers

Flashcards

Acids

Substances that donate protons (H+) or accept electrons.

Bases

Substances that accept protons (H+) or donate electrons.

Acid-base reactions

Reactions involving the transfer of protons from an acid to a base.

Arrhenius acids

Produce H+ ions in aqueous solutions (Arrhenius).

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Arrhenius bases

Produce OH- ions in aqueous solutions (Arrhenius).

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Bronsted-Lowry acids

Proton donors (Bronsted-Lowry).

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Bronsted-Lowry bases

Proton acceptors (Bronsted-Lowry).

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pH

Measure of the acidity or basicity of a solution.

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Buffers

Solutions that resist changes in pH upon addition of small amounts of acid or base.

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Amphoteric substances

Substances that can act as both acids and bases.

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Study Notes

  • Chemical reactions involve the rearrangement of atoms and molecules to form new substances
  • Reactants are the initial substances that participate in a chemical reaction
  • Products are the substances formed as a result of a chemical reaction
  • Chemical equations represent chemical reactions using symbols and formulas
  • Balancing chemical equations ensures that the number of atoms of each element is the same on both sides of the equation, obeying the law of conservation of mass.
  • Stoichiometry is the quantitative study of reactants and products in chemical reactions
  • The mole is the SI unit for the amount of a substance
  • Molar mass is the mass of one mole of a substance, expressed in grams per mole (g/mol)
  • Limiting reactant is the reactant that is completely consumed in a reaction and determines the amount of product formed
  • Excess reactant is the reactant present in a greater amount than necessary to react with the limiting reactant
  • Theoretical yield is the maximum amount of product that can be formed from a given amount of reactants, assuming complete conversion
  • Actual yield is the amount of product actually obtained from a reaction
  • Percent yield is the ratio of actual yield to theoretical yield, expressed as a percentage
  • Acids are substances that donate protons (H+) or accept electrons.
  • Bases are substances that accept protons (H+) or donate electrons.
  • Acid-base reactions involve the transfer of protons from an acid to a base.
  • Arrhenius acids produce H+ ions in aqueous solutions.
  • Arrhenius bases produce OH- ions in aqueous solutions.
  • Bronsted-Lowry acids are proton donors.
  • Bronsted-Lowry bases are proton acceptors.
  • Lewis acids accept electron pairs.
  • Lewis bases donate electron pairs.
  • Conjugate acid-base pairs consist of two substances that differ by the presence of a proton.
  • Amphoteric substances can act as both acids and bases.
  • Water is a common amphoteric substance.
  • Strong acids completely dissociate into ions in aqueous solutions.
  • Weak acids only partially dissociate into ions in aqueous solutions.
  • Strong bases completely dissociate into ions in aqueous solutions.
  • Weak bases only partially dissociate into ions in aqueous solutions.
  • pH is a measure of the acidity or basicity of a solution.
  • pH is defined as the negative logarithm (base 10) of the hydrogen ion concentration ([H+]).
  • pH = -log[H+]
  • A pH of 7 is neutral.
  • A pH less than 7 is acidic.
  • A pH greater than 7 is basic or alkaline.
  • The pH scale typically ranges from 0 to 14.
  • Acidic solutions have a higher concentration of H+ ions than OH- ions.
  • Basic solutions have a higher concentration of OH- ions than H+ ions.
  • Neutral solutions have equal concentrations of H+ and OH- ions.
  • Indicators are substances that change color depending on the pH of the solution.
  • Litmus paper is a common pH indicator.
  • pH meters are electronic devices used to measure pH accurately.
  • Acid-base titrations are used to determine the concentration of an acid or a base by neutralizing it with a solution of known concentration.
  • The equivalence point in a titration is the point at which the acid and base have completely reacted with each other.
  • Buffers are solutions that resist changes in pH upon the addition of small amounts of acid or base.
  • Buffers typically consist of a weak acid and its conjugate base, or a weak base and its conjugate acid.
  • The Henderson-Hasselbalch equation relates the pH of a buffer solution to the pKa of the weak acid and the ratio of the concentrations of the acid and its conjugate base.
  • pKa is the negative logarithm (base 10) of the acid dissociation constant (Ka).
  • The Henderson-Hasselbalch equation: pH = pKa + log([A-]/[HA]), where [A-] is the concentration of the conjugate base and [HA] is the concentration of the weak acid.
  • Buffers are important in biological systems to maintain a stable pH for biochemical reactions.
  • The pH of blood is tightly regulated by buffer systems.

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