Chemical Equilibrium Reactions
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Questions and Answers

What is the chemical equation for the decomposition of silver carbonate upon heating?

  • Ag2CO3(s) → Ag2O(s) + CO2(g) (correct)
  • Ag2CO3(s) → Ag2(s) + CO2(g)
  • Ag2CO3(s) → Ag(s) + CO2(g)
  • Ag2CO3(s) → AgO(s) + CO2(g)

What is the value of Kp for the decomposition reaction of silver carbonate at 503 K?

  • 2.5 atm
  • 0.5 atm
  • 3.5 atm
  • 1.5 atm (correct)

Write the Kp expression for the reaction: Ag2CO3(s) → Ag2O(s) + CO2(g).

  • *Kp* = P_CO2 / [Ag2CO3]
  • *Kp* = [CO2]
  • *Kp* = P_CO2 (correct)
  • *Kp* = [Ag2O][CO2]

What percentage of nitrosyl chloride is present at equilibrium if 1.0 mol of nitrosyl chloride is placed in a closed container at 823 K?

<p>78% (D)</p> Signup and view all the answers

What is the equilibrium expression for the reaction: 2NOCI(g) ↔ 2NO(g) + Cl2(g)?

<p><em>Kp</em> = (P_NO)^2 * P_Cl2 / (P_NOCI)^2 (A)</p> Signup and view all the answers

Study Notes

Chemical Equilibrium

Silver Carbonate Decomposition

  • When silver carbonate is heated, it decomposes into silver oxide and carbon dioxide according to the reaction: Ag2CO3(s) → Ag2O(s) + CO2(g)
  • At 503 K, the value of Kp for this reaction is 1.5 atm
  • The Kp expression for this reaction is: Kp = P(CO2)
  • The equilibrium pressure of carbon dioxide at 503 K can be calculated using the given Kp value

Nitrosyl Chloride Dissociation

  • When nitrosyl chloride gas is heated, it dissociates reversibly into nitric oxide and chlorine according to the reaction: 2NOCI(g) ↔ 2NO(g) + Cl2(g)
  • The Kp expression for this reaction is: Kp = (P(NO)^2 * P(Cl2)) / (P(NOCI))^2
  • If 1.0 mol of nitrosyl chloride gas is heated to 823 K, the equilibrium reached contains 78% of nitrosyl chloride and the pressure in the vessel is 5.0 atm
  • The value of Kp at 823 K can be computed using the given equilibrium composition and pressure

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Solve two problems involving chemical equilibrium reactions, including writing a Kp expression and calculating equilibrium pressure of carbon dioxide.

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