Chemical Equilibrium Criteria and Expression Quiz
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Questions and Answers

What is the condition for chemical equilibrium?

  • Concentrations of reactants are constant
  • Rates of forward reaction equal rates of reverse reaction (correct)
  • Concentrations of products are higher than reactants
  • Rates of forward reaction are faster than reverse reaction

What does the equilibrium expression represent?

  • Volume change during a reaction
  • Rate of the forward reaction
  • Temperature dependence of a reaction
  • Concentrations of product and reactant in a reaction (correct)

What does the equilibrium constant, K, predict?

  • Temperature at which equilibrium is achieved
  • Initial concentrations of reactants
  • Rate of the chemical reaction
  • Extent of established chemical reaction (correct)

What is a characteristic of the equilibrium constant, K?

<p>Dimensionless quantity (B)</p> Signup and view all the answers

Which factor determines the direction of the net reaction in a given set of initial concentrations?

<p>Equilibrium constant, K (C)</p> Signup and view all the answers

What does Le Châtelier's Principle help predict in a system at equilibrium?

<p>The effect of disturbances on an equilibrium system (C)</p> Signup and view all the answers

According to the Debye-Hückel equation, how does the activity coefficient of an ion change with increasing ionic strength?

<p>The activity coefficient decreases (B)</p> Signup and view all the answers

How does the charge of an ion affect the departure of its activity coefficient from unity?

<p>The departure from unity increases with increasing charge (B)</p> Signup and view all the answers

What is the relationship between ion size and activity effects?

<p>Activity effects increase with decreasing ion size (C)</p> Signup and view all the answers

Which of the following equilibria is NOT affected by the ionic strength of the solution?

<p>Redox equilibria (C)</p> Signup and view all the answers

If the activity coefficient of Ca2+ is found using the Debye-Hückel equation, what parameter is NOT needed for the calculation?

<p>The concentration of Ca2+ (B)</p> Signup and view all the answers

How does Le Châtelier's principle apply to the effect of ionic strength on chemical reactions?

<p>Increasing ionic strength shifts the equilibrium towards the products (B)</p> Signup and view all the answers

What is the effect of adding a reactant to a homogeneous equilibrium system?

<p>The equilibrium shifts to the right (D)</p> Signup and view all the answers

What type of equilibrium is represented by the reaction CaCO3(s) + H2O(l) + CO2(aq) ⇄ Ca2+(aq) + 2HCO3-(aq)?

<p>Heterogeneous equilibrium (D)</p> Signup and view all the answers

Which of the following statements about Le Châtelier's principle is correct?

<p>The system adjusts to partially offset the stress applied to the system (A)</p> Signup and view all the answers

Which of the following is not a form of equilibrium?

<p>Temperature equilibrium (B)</p> Signup and view all the answers

What happens to a heterogeneous equilibrium system when the temperature is decreased?

<p>The equilibrium shifts to the left (C)</p> Signup and view all the answers

What is the effect of increasing pressure on a system where the number of gas molecules on the reactant side is greater than the number of gas molecules on the product side?

<p>The equilibrium shifts to the right (B)</p> Signup and view all the answers

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