Chemical Bonding - The Metallic Bond

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Questions and Answers

Which property is characteristic of metals but not salts?

  • Brittleness
  • Electrical conductivity
  • Malleability (correct)
  • Solubility in water

Alloys are made by mixing a metal with another metal or non-metal.

True (A)

What type of bond is characterized by a sea of delocalized electrons surrounding positively charged metallic ions?

  • Covalent bond
  • Metallic bond (correct)
  • Hydrogen bond
  • Ionic bond

What is an example of an alloy made from copper?

<p>brass</p> Signup and view all the answers

Mercury is a solid metal at room temperature and pressure.

<p>False (B)</p> Signup and view all the answers

A mixture of copper and tin creates ______.

<p>bronze</p> Signup and view all the answers

What is one unique property of metals that makes them useful for conducting electricity?

<p>Good conductivity of electricity</p> Signup and view all the answers

Tungsten has the highest melting point among metals at _____°C.

<p>3410</p> Signup and view all the answers

Match the following alloys with their components:

<p>Brass = Copper with zinc Bronze = Copper with tin Stainless steel = Carbon, chromium, and nickel Hard steel = Steel with carbon</p> Signup and view all the answers

Match the following metals with their respective properties:

<p>Gold = Metallic shine Copper = Good conductor of electricity Tungsten = Highest melting point Osmium = High density</p> Signup and view all the answers

Flashcards

Malleability

The ability of a material to be hammered or pressed into different shapes without breaking.

Brittleness

A material that readily shatters when subjected to force.

Alloy

A mixture of two or more metals, or a metal and a non-metal, designed to create new properties.

Solid solution

An alloy created by replacing some atoms in the metal lattice with atoms of a similar size, resulting in a new material with unique properties.

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Strengthening alloy

A type of alloy where atoms of much smaller size are introduced into the metal structure, preventing the lattice from being disrupted easily.

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Sea of electrons

In metals, valence electrons are not bound to individual atoms, but are free to move throughout the metal lattice, forming a "sea of electrons".

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Metallic bond

The strong attraction between the positively charged metal ions and the negatively charged sea of electrons.

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Why are metals good conductors?

Metals are generally good conductors of both heat and electricity because the delocalized electrons can easily carry energy through the material.

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Why are metals shiny?

Metals have a shiny appearance because light can easily travel through their free electrons, reflecting back to your eyes.

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Study Notes

Chemical Bonding - The Metallic Bond

  • Metallic bonding occurs between metal atoms.
  • Unlike ionic or covalent bonds, a positive and negative charge for identical atoms in a substance is difficult to explain.
  • Metal atoms have few valence electrons, making them unable to achieve a noble gas configuration through typical sharing or transferring of electrons.

Metals at an Atomic Level

  • Metal atoms give up their valence electrons, which then become delocalized.
  • These delocalized electrons form a "sea" around positively charged metal ions.
  • The positively charged metal ions are held together by the strong electrostatic attraction to this sea of delocalized electrons.

Properties of Metals

  • Metallic Shine: Metals typically have a grey color, although exceptions exist (gold, copper).
  • Physical State at Room Temperature (rtp): Most metals are solid at rtp, with mercury being an exception, which is liquid.
  • Good Conductivity of Heat and Electricity: The delocalized electrons can easily move and carry electrical charges. They also readily transfer kinetic energy, resulting in good heat conductivity.
  • High Melting Point, Great Hardness, and High Density: These properties result from the strong electrostatic forces between metal ions and delocalized electrons. Tungsten has the highest melting point among metals (3410°C), while osmium is exceptionally dense.
  • Malleability (Stretchable, Cuttable, Foldable): This property results from the ability of the metal atoms to slide past one another without disrupting the metallic bonds. In contrast, ionic compounds are brittle, as the disruption of the ionic lattice structure causes repulsion between like charges, leading to breakage.

Alloys

  • An alloy is a mixture of one metal with another metal or a non-metal.
  • Alloys are created by replacing atoms with similar atomic radii, leading to a "solid solution" with new properties.
  • Examples of alloys include brass (copper and zinc), bronze (copper and tin), and stainless steel (iron, carbon, chromium, and nickel).
  • Introducing atoms with smaller atomic radii into a metal lattice prevents disruption of the metal lattice structure, hence strengthening the alloy. An example is steel (iron with carbon).

Practice Questions and Answers (from provided content)

  • Question 31: Which is the best definition of metallic bonding?
  • Answer: The attraction between cations and delocalized electrons.
  • Question 32: What properties make aluminum suitable for baking foil, aircraft bodywork, cooking pans, and tent frames?
  • Answer: Malleability, thermal conductivity, and thermal stability (for various applications).

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