Chemical Bonding Overview

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Questions and Answers

What is the ionic formula for the combination of magnesium and chlorine?

  • Mg2Cl
  • MgCl2 (correct)
  • MgCl
  • Mg3Cl2

How many electrons are transferred from sodium to sulfur when forming Na2S?

  • 2 (correct)
  • 4
  • 1
  • 6

What type of ion is formed when aluminum loses electrons?

  • Metallic Cation (correct)
  • Nonmetallic Anion
  • Anion
  • Neutral Atom

What is the empirical formula for aluminum oxide?

<p>Al2O3 (D)</p> Signup and view all the answers

What characterizes the bond formation in ionic compounds?

<p>By the transfer of valence electrons (C)</p> Signup and view all the answers

What relationship exists between the radii of atoms and their cations?

<p>Cations are smaller than their neutral atoms (C)</p> Signup and view all the answers

Which noble gas configuration is most similar to that of Mg2+ after ionization?

<p>[Ne] (D)</p> Signup and view all the answers

What is the nature of most compounds formed between metals and nonmetals?

<p>Ionic Compounds (A)</p> Signup and view all the answers

Which group of the periodic table tends to have nonmetals with high electron affinity?

<p>Group VIIA (C)</p> Signup and view all the answers

Which of the following elements forms a cation with a charge of +2?

<p>Calcium (D)</p> Signup and view all the answers

Which of the following ions is formed by a nonmetal from Group V?

<p>P3– (B)</p> Signup and view all the answers

What happens to the valence electrons when an element from Group IIA forms a cation?

<p>All s and p electrons are lost (A)</p> Signup and view all the answers

Which of these elements has the potential to form a covalent bond instead of an ionic compound?

<p>Carbon (C)</p> Signup and view all the answers

Which type of bond is characterized by the transfer of electrons?

<p>Ionic bonding (A)</p> Signup and view all the answers

In which of the following compounds would you expect to find covalent bonding?

<p>H2O (C)</p> Signup and view all the answers

What describes metallic bonds best?

<p>Sea of electrons (C)</p> Signup and view all the answers

Which elements are most likely to form ionic bonds?

<p>Metals and nonmetals (A)</p> Signup and view all the answers

What is the role of valence electrons in chemical bonding?

<p>They are involved in the formation of bonds. (D)</p> Signup and view all the answers

Which of the following statements about ionic bonds is correct?

<p>They are electrostatic attractions between oppositely charged ions. (B)</p> Signup and view all the answers

What do the dots represent in Lewis Electron-Dot Symbols?

<p>Valence electrons (D)</p> Signup and view all the answers

What type of bond occurs in the compound $HCl$?

<p>Covalent bond (A)</p> Signup and view all the answers

Which of these properties is typically associated with ionic compounds?

<p>Crystalline solids at room temperature (C)</p> Signup and view all the answers

Identify the incorrect statement about covalent bonds.

<p>They form between metals and nonmetals. (B)</p> Signup and view all the answers

Which of the following statements about Lewis Electron-Dot Symbols is true?

<p>The symbols represent noble gas cores. (C)</p> Signup and view all the answers

Which of the following compounds are classified as salts?

<p>NaCl and KNO3 (C)</p> Signup and view all the answers

Which statement is correct regarding the size of cations?

<p>A higher positive charge leads to a smaller cation. (D)</p> Signup and view all the answers

Which of the following cations would be isoelectronic with Argon?

<p>Ca2+ (C)</p> Signup and view all the answers

What is the relationship between ionic charge and size for anions?

<p>Larger negative charges lead to larger anions. (D)</p> Signup and view all the answers

Flashcards

First Ionization Energy of Sodium

The energy change that occurs when one mole of sodium atoms in the gaseous state loses one electron to form one mole of sodium ions in the gaseous state.

Electron Affinity of Cl

The energy change that occurs when one mole of chlorine atoms gains one electron to form one mole of chloride ions in the gaseous state.

Lattice Energy of NaCl

The energy released when one mole of sodium ions and one mole of chloride ions combine to form one mole of solid sodium chloride.

Enthalpy Change of Reaction

The overall energy change in a chemical reaction.

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Exothermic Reaction

A chemical reaction that releases energy into its surroundings.

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Ionic Compound

A chemical compound formed by the electrostatic attraction between positively and negatively charged ions.

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Anion

An atom or group of atoms that has gained one or more electrons and carries a negative charge.

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Cation

An atom or group of atoms that has lost one or more electrons and carries a positive charge.

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Ionic Bond

The force of attraction that holds ions together in an ionic compound. It involves the transfer of electrons between atoms with different electronegativities.

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Empirical Formula

The smallest whole number ratio of atoms in a compound.

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Molecular Formula

The chemical formula that shows the actual number of atoms of each element in a molecule or compound.

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Ionic Bonding

The process of forming an ionic bond by the transfer of electrons from a metal atom to a nonmetal atom.

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Lattice Energy

The energy released when an ionic compound is formed from its constituent elements in their standard states.

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X-ray diffraction crystallography

A method that uses X-rays to determine the positions of atoms in a crystal, giving us insights into the distances between nuclei.

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Interatomic distance

The distance between the centers of two adjacent atoms in a crystal lattice.

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Ionic radius

The average distance between the nucleus and the outermost electron shell of an atom or ion.

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Isoelectronic species

Atoms or ions that have the same number of electrons and the same electron configuration.

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Determining ionic radius using interatomic distances

The process of determining the radius of an ion by subtracting half the distance between two identical ions from the distance between a cation and an anion.

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Metals and Cations

Metals, located on the lower left of the periodic table, tend to lose electrons (low ionization energy), forming positively charged ions called cations.

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Nonmetals and Anions

Nonmetals, located on the upper right of the periodic table, tend to gain electrons (high electron affinity), forming negatively charged ions called anions.

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Group IA and IIA Cation Formation

Group IA and IIA metals form cations with a charge equal to their group number by losing all their valence electrons ('s' and 'p' electrons). Their electronic configuration becomes like the preceding noble gas.

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Group IIIA to VA Cation Formation

Group IIIA to VA metals form cations with a charge equal to their group number minus two, by losing only their 'p' valence electrons. They retain their 's' electrons.

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Electronic Configuration of Group IIIA to VA Cations

The electronic configuration of these cations (Group IIIA to VA) resembles the preceding 'pseudo-noble gas' configuration + ns2 (where 'n' is the principal quantum number).

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Ionic Charge

The charge of an ion is determined by the difference between the number of protons (positive charge) and electrons (negative charge).

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Ionic Bond Formation

The formation of ionic compounds involves the transfer of electrons from a metal atom to a nonmetal atom, resulting in a stable ionic bond.

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Chemical Bond

A strong attractive force that exists between atoms in a substance.

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Covalent Bond

A chemical bond formed by the sharing of electrons between two nonmetal atoms.

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Metallic Bond

A chemical bond formed by the delocalized sharing of electrons between metal atoms.

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Valence Electrons

Electrons in the outermost energy level of an atom.

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Lewis Electron Dot Symbol

A shorthand representation of an atom that shows the element symbol surrounded by dots representing valence electrons.

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Noble Gas Core

The core of a Lewis Dot Symbol that represents the noble gas configuration of the atom's inner electrons.

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Pseudo Noble Gas Core

The core of a Lewis Dot Symbol that represents the pseudo noble gas configuration of the atom's inner electrons.

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Salt

A compound formed by the electrostatic attraction between oppositely charged ions.

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Electron Transfer

The process of forming an ionic bond by transferring electrons between atoms.

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Electrostatic Attraction

The electrostatic attraction between oppositely charged ions, causing them to bond together.

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Crystalline Solid

The state of matter where a salt is a solid and has a high melting point.

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Strong Electrolyte

Any substance that conducts electricity when dissolved in water or melted

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Cation Size Trend

For cations of the same element, the larger the positive charge, the smaller the ion.

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Cation Size Explanation

Cations have fewer electrons than their neutral atom counterpart. This results in a stronger pull from the nucleus, causing the ion to shrink.

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Anion Size Trend

For anions of the same element, the larger the negative charge, the larger the ion.

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Anion Size Explanation

Anions have more electrons than their neutral atom counterpart. This leads to increased electron-electron repulsion, causing the ion to expand.

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Atomic/Ionic Size

The size of an atom or ion is determined by the average distance of its outermost electrons from the nucleus.

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Nuclear Charge

The nucleus of an atom has a positive charge, while the electrons surrounding it have a negative charge.

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Nuclear Attraction

The attraction between the nucleus and the electrons is what keeps the atom or ion intact.

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Inter-Electron Repulsions

The repulsion between electrons in the same energy level can cause an increase in ionic size.

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Ion Size Summary

The size of an ion is related to the strength of the nuclear attraction and inter-electron repulsion forces.

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Study Notes

Chemical Bonding

  • Chemical bonds are strong attractive forces between atoms in a substance.
  • Bonds are classified into three types: ionic, covalent, and metallic.

Ionic Bonding

  • Ionic bonds typically form between metals and nonmetals.
  • Electrons are transferred from metal to nonmetal atoms.
  • Examples include NaCl, MgBr2, and AlF3.

Covalent Bonding

  • Covalent bonds usually form between nonmetals.
  • Atoms share electrons.
  • Examples include H2, Cl2, N2, HCl, H2O, NH3, CO2, and CCl4.

Metallic Bonding

  • Metallic bonds occur between metallic ions.
  • Electrons are shared in a "sea of electrons" within the metallic structure.
  • Examples include Cu, Al, and Na.

Lewis Electron-Dot Symbols

  • Valence electrons are represented by dots around the symbol of an element.
  • Dots represent the outermost electrons.
  • Examples include Na and Ga

Ionic Bonds (Properties)

  • Salts are typically crystalline solids at room temperature.
  • Salts have high melting points.
  • Salts are strong electrolytes in molten or aqueous solutions.
  • Ionic bonds are electrostatic attractions between oppositely charged ions.

Other Examples of Ionic Compounds

  • Example reactions illustrating the formation and transfer of electrons in ionic compounds.

Energy Involved in Ionic Bonding

  • This is an endothermic (absorbs energy) or exothermic (releases energy) process depending on the sequence of steps.
  • Steps include sublimation of sodium, dissociation of chlorine, ionization of sodium, formation of chloride ions, and formation of the ionic solid.

Ionic Radii

  • The radius of an ion is the distance from the nucleus to the outermost electron shell.
  • Determined experimentally using X-ray diffraction crystallography.
  • Provides insights into the size and structure of ions in crystals.

Radii of Cations

  • The size of a cation (positive ion) depends on the number of protons and electrons.
  • More positive ionic charges result in smaller cations.
  • This can be attributed to the electron-proton interactions within the ion.

Radii of Anions

  • The size of an anion (negative ion) depends on the number of protons and electrons.
  • More negative ionic charges result in larger anions.
  • More electrons mean less attraction between the nucleus and electrons within the ion.

Size of Cations in the Periodic Table

  • Cations decrease in size moving across a period (left to right) on the periodic table.
  • Cations increase in size moving down a group (top to bottom) on the periodic table.
  • The increasing number of filled electron shells and corresponding electron-electron repulsions influence ionic size.

Size of Anions in the Periodic Table

  • Anions decrease in size moving across a period (left to right) on the periodic table.
  • Anions increase in size moving down a group (top to bottom) on the periodic table.
  • The increasing number of filled electron shells and corresponding electron-electron repulsions influence ionic size.

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