CHEM311 Chapter 2: Water and Polarity
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Questions and Answers

What is the purpose of using buffers in a solution?

  • To maintain a stable pH by neutralizing small quantities of additional acid or base (correct)
  • To make the solution more acidic
  • To decrease the pH of the solution
  • To neutralize large quantities of acids or bases

In a buffer solution, which component neutralizes a strong base?

  • The spectator ion
  • The strong acid
  • The acid (correct)
  • The conjugate base

What is a common buffering agent with a pKa value of 6.40?

  • Citric acid
  • Acetic acid
  • KH2PO4 (correct)
  • Borate

In a phosphate buffer system, what is the typical useful pH range?

<p>6.2 to 8.2 (D)</p> Signup and view all the answers

What is the general rule regarding the effective range of a buffer in relation to its pKa value?

<p>The effective range is +/- 1 pH unit of the pKa value of the weak acid (C)</p> Signup and view all the answers

What is a key criterion for selecting a buffer?

<p>Matching pKa value with the system (B)</p> Signup and view all the answers

Which of the following is NOT a typical criterion for selecting a buffer?

<p>High solubility (A)</p> Signup and view all the answers

What is the principal buffer in cells?

<p>$H_2PO_4^-/HPO_4^{2-}$ (A)</p> Signup and view all the answers

What happens to blood pH if someone hyperventilates?

<p>It increases (B)</p> Signup and view all the answers

If the buffering capacity of a solution is very high, what does that indicate about the concentrations of the weak acid and its conjugate base?

<p>High concentrations (B)</p> Signup and view all the answers

What is the pH of a solution after adding 1.5mL of 2.0M HCl to 10.0mL of water?

<p>5.58 (B)</p> Signup and view all the answers

If you add 1.5mL of 2.0M HCl to a buffer solution, what will happen to the buffer's pH?

<p>It will decrease (B)</p> Signup and view all the answers

In a mixture of 0.55M carbonic acid and 0.55M sodium hydrogen carbonate, what is the resulting pH when 1.5mL of 2.0M HCl is added?

<p>5.84 (B)</p> Signup and view all the answers

How does the addition of HCl impact the concentration of carbonic acid in the mixture of carbonic acid and sodium hydrogen carbonate?

<p>Increases (C)</p> Signup and view all the answers

What is the significance of maintaining a specific buffer ratio in a buffer system?

<p>To neutralize any added acid or base (C)</p> Signup and view all the answers

What happens when the concentrations of a weak acid and its conjugate base are equal in a solution according to the Henderson-Hasselbalch equation?

<p>The pH of the solution equals the pKa of the weak acid (B)</p> Signup and view all the answers

Which type of buffer contains a weak acid and its salt or a weak base and its salt?

<p>Buffer resistant to pH change (B)</p> Signup and view all the answers

How do buffers work when a strong base is added to a buffer solution?

<p>The weak acid absorbs the H+ to neutralize the base (D)</p> Signup and view all the answers

What happens when a strong acid is added to a buffer solution?

<p>The pH changes only slightly (C)</p> Signup and view all the answers

What characterizes a buffer's resistance to changes in pH?

<p>The ability of the buffer to absorb or release H+ ions without significant changes in pH (A)</p> Signup and view all the answers

What is the role of a weak acid in an aqueous solution?

<p>Exists as a conjugate acid-base pair (A)</p> Signup and view all the answers

How is the strength of an acid described?

<p>Quantified by Ka value (B)</p> Signup and view all the answers

Which concept connects the equilibrium constant (K) to the pH of a solution containing both an acid and a base?

<p>Henderson-Hasselbalch equation (B)</p> Signup and view all the answers

What is the ionization constant for water at 25°C?

<p>[H+] * [OH-] = 10^-7 (D)</p> Signup and view all the answers

What is the molar concentration of water used to calculate the ionization constant for water at 25°C?

<p>55.5 M (B)</p> Signup and view all the answers

What determines the polarity of a molecule?

<p>The geometry of the molecule and the polarity of the bonds (B)</p> Signup and view all the answers

What type of bonds are polar covalent bonds?

<p>Bonds where electrons are shared but not equally (D)</p> Signup and view all the answers

What is electronegativity in relation to a compound?

<p>The ability of an atom in a compound to draw electrons to itself (C)</p> Signup and view all the answers

How does the geometry of a molecule affect its polarity?

<p>It can determine whether the molecule is polar or nonpolar (B)</p> Signup and view all the answers

What does a polar covalent bond imply about electron sharing?

<p>Electrons are shared but not equally between atoms (B)</p> Signup and view all the answers

Which type of molecules tend to dissolve in water?

<p>Hydrophilic (D)</p> Signup and view all the answers

What type of interactions are very weak between nonpolar molecules?

<p>Van der Waals interactions (A)</p> Signup and view all the answers

What kind of molecules have characteristics of both hydrophobic and hydrophilic regions?

<p>Amphipathic molecules (D)</p> Signup and view all the answers

What is the term for a spherical arrangement of organic molecules in water solution?

<p>Micelle (B)</p> Signup and view all the answers

Which type of bonds are responsible for the attraction between temporary induced dipoles in micelle formation?

<p>Van der Waals interactions (D)</p> Signup and view all the answers

What does a Brønsted-Lowry acid donate?

<p>Proton (hydrogen ion) (D)</p> Signup and view all the answers

In the context of acids and bases, what does a Brønsted-Lowry base accept?

<p>Proton (hydrogen ion) (B)</p> Signup and view all the answers

What is the term for molecules that contain one or more hydrophobic and one or more hydrophilic regions?

<p>Amphipathic molecules (C)</p> Signup and view all the answers

What is the main type of bond responsible for forming hydrophobic interactions?

<p>Van der Waals interactions (C)</p> Signup and view all the answers

What is the key characteristic of micelles in aqueous solutions?

<p>Hydrophobic parts on the surface of the sphere (B)</p> Signup and view all the answers

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