Chem SI 12/2 Exam 2 Review

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Questions and Answers

What does the -ane ending indicate in the naming of hydrocarbons?

An alkane

What type of hydrocarbon is characterized by a specific six-carbon ring with three double bonds?

An aromatic hydrocarbon

Which of the following correctly describes the bond angle in alkanes?

  • 90 degrees
  • 109.5 degrees (correct)
  • 180 degrees
  • 120 degrees

Which of the following is NOT a characteristic of a functional group?

<p>It is a group of atoms that defines the overall structure of the molecule. (D)</p> Signup and view all the answers

What is the name given to the functional group containing an -OH group attached to a carbon atom?

<p>Alcohol</p> Signup and view all the answers

What is the ending of a hydrocarbon name that indicates an alcohol?

<p>-ol</p> Signup and view all the answers

What is the functional group that contains a -SH group attached to a tetrahedral carbon or an aromatic carbon?

<p>Thiol</p> Signup and view all the answers

What is the name given to the functional group containing a carbonyl group bonded to a hydrogen and an R group?

<p>Aldehyde</p> Signup and view all the answers

What is the name given to the functional group containing a carbonyl group bonded to two alkyl or aromatic rings?

<p>Ketone</p> Signup and view all the answers

What is the name given to the functional group containing a carbonyl group bonded to a nitrogen atom?

<p>Amide</p> Signup and view all the answers

What is the name given to the functional group containing a hydroxyl group directly attached to a benzene ring?

<p>Phenol</p> Signup and view all the answers

What is the name for a class of compounds containing an -NH2 group?

<p>Amine</p> Signup and view all the answers

Alkanes contain only single bonds which end in what suffix?

<p>-ane (D)</p> Signup and view all the answers

Alkenes contain one or more double bonds which end in what suffix?

<p>-ene (B)</p> Signup and view all the answers

What type of hydrocarbon has a specific six-carbon ring with three double bonds?

<p>Aromatic</p> Signup and view all the answers

The general naming structure of hydrocarbons is ______ - ______ - ______.

<p>prefix-root-ending</p> Signup and view all the answers

Match the following prefixes with the number of carbon atoms they represent.

<p>Meth = 1 Eth = 2 Prop = 3 But = 4 Pent = 5 Hex = 6 Hept = 7 Oct = 8 Non = 9 Dec = 10</p> Signup and view all the answers

What does the suffix '-ane' indicate in hydrocarbon naming?

<p>Alkane (C)</p> Signup and view all the answers

The hydroxyl group (-OH) is referred to as a carboxyl group.

<p>False (B)</p> Signup and view all the answers

What functional group is present in a compound that ends in the suffix '-ol'?

<p>Alcohol (B)</p> Signup and view all the answers

Which of the following functional groups primarily relates to ammonia, NH3?

<p>Amine (B)</p> Signup and view all the answers

What functional group is characterized by an oxygen atom connected to two carbon atoms, represented as R-O-R?

<p>Ether (D)</p> Signup and view all the answers

What functional group is characterized by a sulfur atom connected to a carbon atom and a hydrogen atom, represented as R-SH?

<p>Thiol (C)</p> Signup and view all the answers

What functional group is present in compounds prepared from carboxylic acids and typically ends in '-oate'?

<p>Ester (D)</p> Signup and view all the answers

What functional group is derived from carboxylic acids, and typically ends in '-amide'?

<p>Amide (A)</p> Signup and view all the answers

What functional group has a carbonyl group bonded to a hydrogen atom, and typically ends in '-al'?

<p>Aldehyde (D)</p> Signup and view all the answers

What functional group has a carbonyl group bonded to two alkyl groups, and typically ends in '-one'?

<p>Ketone (D)</p> Signup and view all the answers

What type of reaction involves the breaking and forming of bonds to produce new products?

<p>Chemical change (A)</p> Signup and view all the answers

The Law of Conservation of Mass states that atoms are destroyed in chemical reactions.

<p>False (B)</p> Signup and view all the answers

What must be equal on both the reactant and product sides of a balanced chemical equation?

<p>The number of atoms of each element</p> Signup and view all the answers

What does the enthalpy of a reaction represent?

<p>The energy change during a reaction (A)</p> Signup and view all the answers

Which type of reaction releases heat and results in a negative enthalpy change?

<p>Exothermic reaction (A)</p> Signup and view all the answers

Which type of reaction absorbs heat and results in a positive enthalpy change?

<p>Endothermic reaction (D)</p> Signup and view all the answers

Solvation involves the interaction between a solute and a solvent, leading to the formation of a solution

<p>True (A)</p> Signup and view all the answers

Which of these methods is used to express concentration in terms of mass of solute per mass of solution?

<p>Mass/volume (m/v) (A)</p> Signup and view all the answers

What does the concentration of a solution refer to?

<p>The amount of solute in a defined volume of solution (A)</p> Signup and view all the answers

What is the passage of water through a semipermeable membrane from a region of high water concentration to a region of low water concentration called?

<p>Osmosis (C)</p> Signup and view all the answers

Which of the following is the pressure that needs to be applied to the more concentrated solution to prevent osmosis?

<p>Osmotic pressure (D)</p> Signup and view all the answers

Reverse osmosis occurs when the pressure applied is greater than the osmotic pressure, causing water to flow against the gradient.

<p>True (A)</p> Signup and view all the answers

Which term refers to the concentration of a solution that has a higher solute concentration compared to another solution?

<p>Hypertonic (A)</p> Signup and view all the answers

Which term describes solutions that have the same concentration of solutes?

<p>Isotonic (C)</p> Signup and view all the answers

Which type of solution movement occurs from a higher solute concentration to a lower solute concentration?

<p>Dialysis (A)</p> Signup and view all the answers

Osmolarity represents the total concentration of all solute particles in a solution.

<p>True (A)</p> Signup and view all the answers

According to the Arrhenius definition, what do acids produce in water?

<p>Both B and C (B)</p> Signup and view all the answers

Flashcards

Alkanes

Hydrocarbons containing only single bonds.

Alkenes

Hydrocarbons containing one or more double bonds.

Alkynes

Hydrocarbons containing one or more triple bonds.

Aromatic Hydrocarbons

Hydrocarbons with a specific six-carbon ring with three double bonds.

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IUPAC Naming

A systematic method for naming organic compounds.

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Functional Groups

Specific groups of atoms that give molecules unique properties.

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Law of Conservation of Mass

In chemical reactions, atoms are neither created nor destroyed.

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Balancing Equations

Making the number of atoms of each elements equal on both sides of the equation

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Stoichiometry

Quantitative relationship between reactants and products in a chemical reaction.

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Polar Solvents

Solvents with a significant positive and negative end (e.g., water).

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Nonpolar Solvents

Solvents with no significant positive or negative ends (e.g., oil).

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Ion-dipole forces

Attractive forces between an ion and a polar molecule.

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Osmosis

Movement of solvent across a semipermeable membrane from low solute to high solute concentration.

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Osmotic Pressure

Pressure applied to prevent osmosis.

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Reverse Osmosis

Applying pressure to force solvent against the concentration gradient.

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Tonicity

Describing the relative concentrations of solutes in solutions.

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Hypertonic

Higher solute concentration compared to another solution.

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Hypotonic

Lower solute concentration compared to another solution.

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Isotonic

Same solute concentration as another solution.

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Molarity

Concentration expressed as moles of solute per liter of solution.

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Arrhenius Acid

Substance that produces H3O+ ions in water.

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What are the four classes of hydrocarbons?

The four classes of hydrocarbons are alkanes, alkenes, alkynes, and aromatics. Alkanes contain only single bonds, alkenes contain double bonds, alkynes contain triple bonds, and aromatics have a specific six-carbon ring with three double bonds.

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What is the ending for an alkane?

The ending for an alkane is -ane.

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What is the ending for an alkene?

The ending for an alkene is -ene.

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What is the ending for an alkyne?

The ending for an alkyne is -yne.

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What is the prefix used to indicate the number of carbons in a chain?

The prefix used to indicate the number of carbons in a chain is based on the number of carbons.

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What is the root used to identify if the hydrocarbon is an alkane, alkene, or alkyne?

The root used to identify the type of hydrocarbon is based on the type of bond. It is '-ane' for alkanes, '-ene' for alkenes, and '-yne' for alkynes.

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What is the purpose of the Law of Conservation of Mass in balancing equations?

The Law of Conservation of Mass states that in all chemical reactions, atoms are neither created nor destroyed. It ensures that the number of atoms on the reactant side equals the number of atoms on the product side for each element, ensuring the equation is balanced.

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How do polar solutes dissolve in polar solvents?

Polar solutes dissolve in polar solvents due to hydrogen bonding. Polar solutes break their hydrogen bonds, form new hydrogen bonds with the solvent, leading to a lower potential energy.

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How do nonpolar solutes dissolve in nonpolar solvents?

Nonpolar solutes dissolve in nonpolar solvents through weaker forces like dispersion forces or dipole-dipole interactions.

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How do ionic compounds dissolve in polar solvents?

Soluble ionic compounds dissolve in polar solvents because the ion-dipole forces are stronger than the ionic bonds. Ionic bonds between cations and anions are replaced by ion-dipole interactions with polar molecules, usually water.

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What are the units used to express concentration?

Concentration can be expressed in various units, including mass/volume (m/v) or % mass/ volume (%m/v), molarity (moles solute/liters solution), parts per million (ppm), and parts per billion (ppb).

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What is the difference between dilute and concentrated solutions?

Dilute solutions contain less solute compared to concentrated solutions, meaning they are diluted. Concentrated solutions have a higher amount of solute.

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What is osmosis? How does it occur?

Osmosis is the movement of solvent (usually water!) through a semipermeable membrane to equalize concentrations. It occurs when solutes cannot pass through the membrane, and the solvent moves to balance the solute concentrations on both sides.

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What is osmotic pressure?

Osmotic pressure is the amount of pressure needed to be applied to the more concentrated solution to prevent osmosis. It is a measure of the tendency of water to move across the membrane.

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What is reverse osmosis?

Reverse osmosis is the process where pressure greater than the osmotic pressure is applied to force water to flow against the concentration gradient, from a high solute concentration to a low solute concentration.

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What are hypertonic, hypotonic, and isotonic solutions?

Hypertonic solutions have a higher solute concentration compared to another solution. Hypotonic solutions have a lower solute concentration compared to another solution. Isotonic solutions have the same solute concentration as another solution.

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How does osmosis affect cells in different solutions?

In hypertonic solutions, water flows out of the cell causing it to shrink or crenate. In hypotonic solutions, water flows into the cell causing it to swell and potentially burst (hemolysis). In isotonic solutions, there is no net movement of water, and the cell stays normal.

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What are Brönsted-Lowry acids?

Brönsted-Lowry acids are proton donors. Protons are represented as H+.

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What are Brönsted-Lowry bases?

Brönsted-Lowry bases are proton acceptors. Protons are represented as H+.

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What is the difference between strong and weak acids and bases?

Strong acids and bases completely dissociate in water, meaning they donate/accept all their protons. Weak acids and bases only partially dissociate in water, meaning they donate/accept only some protons.

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What is Le Châtelier's Principle?

Le Chatelier's Principle states that if a change of conditions is applied to a system in equilibrium, the system will shift in a direction that relieves the stress. This applies to weak acid/base reactions.

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How does Le Châtelier's Principle work with changes in concentration?

If you remove a substance from a system in equilibrium, the reaction will shift towards making more of that substance to regain equilibrium. If you add a substance, the reaction will shift away from the substance to consume the excess.

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What is the relationship between pH and hydronium ion concentration?

pH is a measure of the hydronium ion (H3O+) concentration in a solution. The lower the pH, the higher the H3O+ concentration, and vice versa.

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What is a buffer?

A buffer is a solution that resists changes in pH when small amounts of acid or base are added. It helps maintain a stable pH.

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What do buffers consist of?

Buffers are made of a weak acid and its conjugate base or a weak base and its conjugate acid pair.

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What factors influence the buffer's effectiveness?

The pH range maintained by a buffer depends on the identity of the weak acid. The buffer capacity, which is the ability to resist pH changes, depends on the concentration of the buffer components.

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Study Notes

Exam 2 Review - Chem SI 12/2

  • Exam review session for Chem SI 12/2, Exam 2
  • Date of review: 12/03/2024
  • Instructor: Hallie Popat

Hydrocarbons

  • Alkanes: Contain only single bonds. End in -ane. Example: C2H6
  • Alkenes: Contain one or more double bonds. End in -ene. Example: C2H4
  • Alkynes: Contain one or more triple bonds. End in -yne. Example: C2H2
  • Aromatic: Hydrocarbons with a specific six-carbon ring with three double bonds. Example: C6H6
  • Saturated hydrocarbons: Contain only single bonds.
  • Unsaturated hydrocarbons: Contain double or triple bonds.

Naming

  • Naming hydrocarbons uses a system of prefixes, roots, and endings: "prefix-root-ending".

  • Prefixes: Indicate branched-chain substituents.

  • Root: Number of carbon atoms in the parent chain.

  • Ending: Ane (alkane), ene (alkene), or yne (alkyne).

  • Branches off the main chain and location of double or triple bonds are crucial for naming the molecule.

  • Roots associated with the number of carbon atoms are: -Meth: 1 -Eth: 2 -Prop: 3 -But: 4 -Pent: 5 -Hex: 6 -Hept: 7 -Oct: 8 -Non: 9 -Dec: 10

Functional Groups

  • Alcohols: Compounds containing an -OH group (hydroxyl). End in -ol.
  • Phenols: Hydroxyl group bonded to a benzene ring.
  • Thiols: Compounds containing a sulfhydryl group (-SH). End in -thiol.
  • Ethers: Contain an oxygen atom bonded to two carbon atoms. Example: R-O-R
  • Amines: Compounds containing a nitrogen atom.

Functional Groups (Continued)

  • Esters: Prepared from carboxylic acids. End in -oate. Example: RCOOR
  • Amides: Derivatives of carboxylic acids with a nitrogen group replacing the hydroxyl.
  • Aldehydes: Carbonyl group bonded to a hydrogen atom and an R-group. End in -al.
  • Ketones: Carbonyl group bonded to two alkyl groups or aromatic rings. End in -one.

Stoichiometry Calculations

  • For stoichiometry calculations, a flowchart approach is useful.
  • Determine the given amount.
  • Find the unknown amount, using molar masses and mole ratios.

Balancing Equations

  • The Law of Conservation of Mass: Atoms are neither created nor destroyed in a chemical reaction.
  • Balancing chemical equations ensures equal numbers of atoms of each element on both sides of the equation.

Energy Diagrams

  • Energy diagrams: Show energy pathways in a reaction.
  • Exothermic Reactions: Reactants have higher energy, energy is released when products are formed. ΔHrxn < 0
  • Endothermic Reactions: Products have higher energy, energy is absorbed when products are formed. ΔHrxn > 0

Polar Solutes and Polar Solvents

  • Polar solvents can dissolve polar solutes.
  • Interactions include hydrogen bonding between the solute and solvent.

Solute Concentration

  • Concentration = amount of solute in a given volume or mass of solution.
  • Units: Mass/Volume, Mass/Volume percent, Molarity (moles of solute/liter of solution), Parts per billion (ppb), Parts per million (ppm)

Osmosis

  • Osmosis is the movement of solvent (usually water) through a selectively permeable membrane to equalize concentrations, from a lower to higher concentrated solution.
  • Osmotic pressure: Pressure required to prevent fluid movement.
  • Reverse Osmosis: Pressure greater than osmotic pressure causes water to move against the gradient.

Tonicity

  • Hypertonic solution: Higher solute concentration than another solution; water moves out of the cell

  • Hypotonic solution: Lower solute concentration than another solution; water moves into the cell

  • Isotonic: Equal solute concentration between solutions

  • Osmosis and dialysis: Water moves from hypotonic solution to hypertonic to equalize concentration.

Arrhenius Acid-Base Definitions

  • Arrhenius acids produce H3O+ (hydronium) ions
  • Arrhenius bases produce OH- (hydroxide) ions

Brønsted-Lowry Acid-Base Definitions

  • Brønsted-Lowry acids are proton donors (H+)
  • Brønsted-Lowry bases are proton acceptors
  • Acidic hydrogens are usually found at the start of the acid formula
  • Key examples of acids: HCl, HC2H3O2

Acids and Bases Strength

  • Strong Acids/Bases: Dissociate completely in water.
  • Weak Acids/Bases: Dissociate partially in water and reversible reactions.

Le Châtelier's Principle

  • If a change is imposed on a system at equilibrium, the system will shift to relieve the stress.
  • Shifts equilibrium based on removal or addition of substances to either side of a solution. Addition/Removal of substance will effect the opposite side of the solution.

pH and Kw

  • pH: Measure of the hydronium ion concentration in solution. Physiological pH is between 7.35 and 7.45.
  • Kw: Ion-product constant for water ([H3O+][OH-]=1 × 10-14)

Buffers

  • Buffers resistant to pH changes.
  • Neutralizing small amounts of acid or base that are added.
  • Composed of weak acid and its conjugate base, or weak base and its conjugate acid.

Problems

  • Various problems relating to chemical concepts and calculations are present.

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