Chem 161 Exam 3 Review
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Questions and Answers

Which element has a larger atomic radius?

  • F
  • Rb (correct)
  • Na
  • Cl

What phenomenon causes cations to be smaller than their parent atoms?

  • Loss of electrons leading to less electron-electron repulsion (correct)
  • Increased electron repulsion
  • Decreased nuclear charge
  • Additional energy levels being added

Which ion is larger than its neutral atom?

  • Cl-
  • O2- (correct)
  • Mg2+
  • K+

Which of the following trends describes the atomic radius as you move down a group in the periodic table?

<p>Atomic radius increases (B)</p> Signup and view all the answers

Why does the electronegativity generally decrease as you move down a group in the periodic table?

<p>Increased distance of electrons from nucleus reduces attraction (C)</p> Signup and view all the answers

What is the maximum number of electrons that can occupy a single orbital?

<p>2 (B)</p> Signup and view all the answers

Which principle states that electrons fill lower energy levels before higher ones?

<p>Aufbau Principle (D)</p> Signup and view all the answers

What distinguishes paramagnetic substances from diamagnetic substances?

<p>Presence of unpaired electrons (B)</p> Signup and view all the answers

What is the term for the state where an electron configuration deviates from the ground state by having higher energy levels filled?

<p>Excited state (B)</p> Signup and view all the answers

Which rule describes how electrons are distributed between degenerate orbitals?

<p>Hund's Rule (D)</p> Signup and view all the answers

Which of the following configurations corresponds to a stable state?

<p>[Ar] 4s2 3d5 3p6 (B)</p> Signup and view all the answers

What do valence electrons determine about an element's chemical properties?

<p>The type of bonds it can form (A)</p> Signup and view all the answers

Flashcards

Atomic Radius

A measure of the size of an atom, representing how close electrons are to the nucleus.

Cation vs Atom Size

Cations are smaller than their corresponding neutral atoms because losing electrons reduces electron-electron repulsion, pulling the remaining electrons closer to the nucleus.

Anion vs Atom Size

Anions are larger than their corresponding neutral atoms due to the addition of electrons, increasing electron-electron repulsion and pushing the electron cloud further out.

Zeff

Effective nuclear charge, the net positive charge experienced by an electron in the atom.

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Electron Energy Levels

Distinct energy states occupied by electrons within an atom, represented by the principal quantum number 'n'.

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Quantum Numbers

Sets of numbers that describe the properties of an electron in an atom, including its energy level, shape of the orbital, orientation of the orbital, and spin direction (n, l, ml, ms).

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Aufbau Principle

Electrons fill lower energy levels first when creating electron configurations of atoms.

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Hund's Rule

When filling degenerate (same energy) orbitals, electrons fill each orbital separately before pairing up.

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Pauli Exclusion Principle

No two electrons in an atom can have the same four quantum numbers (n, l, ml, ms).

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Ground State

The lowest possible energy state of an electron configuration.

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Excited State

Electron configurations that do NOT follow the Aufbau and Hund's Rule.

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Valence Electrons

Electrons in the outermost shell of an atom.

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Paramagnetic

Materials with unpaired electrons, attracted to magnets.

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Study Notes

Chem 161 Exam 3

  • Exam 3 is on Thursday, November 21st
  • Focus on chapters 7, 8, and 9
  • A quarter of the exam will include review questions from previous material
  • No assignments due on Saturday

Exam 3 Details

  • Bring a pencil, photo ID, and calculator
  • A photo ID is required to submit the exam
  • Room assignments are based on last name
    • Students with last names A-L go to SPAL 155
    • Students with last names M-Z go to BIL 152

Guest Speaker Information

  • Billy Pieper, Director of Strategic Partnerships and Mortgage at ASB
  • Senior Vice President and Director of Strategic Partnerships for American Savings Bank
  • Played college football and baseball at UCLA
  • Professional baseball with the Kansas City Royals
  • Master of Business Administration degree from the University of Hawaii at Mānoa
  • Shares financial knowledge with University of Hawaii students at Ma'noa's Shidler College of Business
  • Hui Kapili - Building a better Hawai`i together

Schrödinger Equation

  • Input: Quantum numbers (n, l, m, ml)
  • Output: Probability map showing where an electron can exist in an atom (orbital)
  • The Schrödinger equation describes how electrons exist in atoms

Periodic Table

  • Periodic table used to determine electron orbital patterns
  • s, p, d, f blocks
  • Full, empty, or half-filled electron shells tend to be more stable
    • Example: Ca: [Ar]4s2 Cr: [Ar]4s13d5
  • valence electrons primarily determine element properties
  • Electron configuration defines how electrons fill atomic orbitals

Rules for Electron Orbital Filling

  • Pauli Exclusion Principle: No two electrons can have the same four quantum numbers (n, l, ml, ms). Maximum of 2 electrons per orbital.
  • Aufbau Principle: Electrons fill lower energy levels first (ground state).
  • Hund's Rule: When filling degenerate orbitals (same energy), electrons fill each orbital individually before pairing up.

Ground State vs. Excited State Configurations

  • Configurations following all rules are ground state
  • Configurations that violate the rules are excited state

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Prepare for your upcoming Chem 161 Exam 3 by focusing on chapters 7, 8, and 9. This exam will also include review questions from previous material, so be sure to review past content. Remember to bring the necessary materials and check your room assignments based on your last name.

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