Chem 161 Exam 3 Review
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Questions and Answers

Which element has a larger atomic radius?

  • F
  • Rb (correct)
  • Na
  • Cl
  • What phenomenon causes cations to be smaller than their parent atoms?

  • Loss of electrons leading to less electron-electron repulsion (correct)
  • Increased electron repulsion
  • Decreased nuclear charge
  • Additional energy levels being added
  • Which ion is larger than its neutral atom?

  • Cl-
  • O2- (correct)
  • Mg2+
  • K+
  • Which of the following trends describes the atomic radius as you move down a group in the periodic table?

    <p>Atomic radius increases</p> Signup and view all the answers

    Why does the electronegativity generally decrease as you move down a group in the periodic table?

    <p>Increased distance of electrons from nucleus reduces attraction</p> Signup and view all the answers

    What is the maximum number of electrons that can occupy a single orbital?

    <p>2</p> Signup and view all the answers

    Which principle states that electrons fill lower energy levels before higher ones?

    <p>Aufbau Principle</p> Signup and view all the answers

    What distinguishes paramagnetic substances from diamagnetic substances?

    <p>Presence of unpaired electrons</p> Signup and view all the answers

    What is the term for the state where an electron configuration deviates from the ground state by having higher energy levels filled?

    <p>Excited state</p> Signup and view all the answers

    Which rule describes how electrons are distributed between degenerate orbitals?

    <p>Hund's Rule</p> Signup and view all the answers

    Which of the following configurations corresponds to a stable state?

    <p>[Ar] 4s2 3d5 3p6</p> Signup and view all the answers

    What do valence electrons determine about an element's chemical properties?

    <p>The type of bonds it can form</p> Signup and view all the answers

    Study Notes

    Chem 161 Exam 3

    • Exam 3 is on Thursday, November 21st
    • Focus on chapters 7, 8, and 9
    • A quarter of the exam will include review questions from previous material
    • No assignments due on Saturday

    Exam 3 Details

    • Bring a pencil, photo ID, and calculator
    • A photo ID is required to submit the exam
    • Room assignments are based on last name
      • Students with last names A-L go to SPAL 155
      • Students with last names M-Z go to BIL 152

    Guest Speaker Information

    • Billy Pieper, Director of Strategic Partnerships and Mortgage at ASB
    • Senior Vice President and Director of Strategic Partnerships for American Savings Bank
    • Played college football and baseball at UCLA
    • Professional baseball with the Kansas City Royals
    • Master of Business Administration degree from the University of Hawaii at Mānoa
    • Shares financial knowledge with University of Hawaii students at Ma'noa's Shidler College of Business
    • Hui Kapili - Building a better Hawai`i together

    Schrödinger Equation

    • Input: Quantum numbers (n, l, m, ml)
    • Output: Probability map showing where an electron can exist in an atom (orbital)
    • The Schrödinger equation describes how electrons exist in atoms

    Periodic Table

    • Periodic table used to determine electron orbital patterns
    • s, p, d, f blocks
    • Full, empty, or half-filled electron shells tend to be more stable
      • Example: Ca: [Ar]4s2 Cr: [Ar]4s13d5
    • valence electrons primarily determine element properties
    • Electron configuration defines how electrons fill atomic orbitals

    Rules for Electron Orbital Filling

    • Pauli Exclusion Principle: No two electrons can have the same four quantum numbers (n, l, ml, ms). Maximum of 2 electrons per orbital.
    • Aufbau Principle: Electrons fill lower energy levels first (ground state).
    • Hund's Rule: When filling degenerate orbitals (same energy), electrons fill each orbital individually before pairing up.

    Ground State vs. Excited State Configurations

    • Configurations following all rules are ground state
    • Configurations that violate the rules are excited state

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    Description

    Prepare for your upcoming Chem 161 Exam 3 by focusing on chapters 7, 8, and 9. This exam will also include review questions from previous material, so be sure to review past content. Remember to bring the necessary materials and check your room assignments based on your last name.

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