Podcast
Questions and Answers
What is the primary strategy to maximize the production of product D?
What is the primary strategy to maximize the production of product D?
- Increase the concentration of A significantly
- Use a batch reactor efficiently
- Utilize a PFR/PBR and select appropriate spacetime (correct)
- Use a CSTRs in series (correct)
In the reaction involving A, B, and C, what is the net reaction rate for species B?
In the reaction involving A, B, and C, what is the net reaction rate for species B?
- -rB = k1CA + k2CB
- -rB = k2CB
- rB,net = k1CA - k2CB (correct)
- rB,net = k2CA - k1CB
How does the concentration of A depend on spacetime Ï„ in a PFR?
How does the concentration of A depend on spacetime Ï„ in a PFR?
- CA = k1C0e^(-Ï„)
- CA = CA0e^(-k1Ï„) (correct)
- CA = CA0(1 - e^(-k1Ï„))
- dFA/dV = k1C0e^(-k1Ï„)
What must be determined to quench the reaction when the concentration of B is at its maximum?
What must be determined to quench the reaction when the concentration of B is at its maximum?
What is the effect of k1 on the concentration of A as described in the equations?
What is the effect of k1 on the concentration of A as described in the equations?
What characterizes parallel or competing reactions?
What characterizes parallel or competing reactions?
Why can't conversions be used in the analysis of multiple reactions?
Why can't conversions be used in the analysis of multiple reactions?
Which of the following best describes series reactions?
Which of the following best describes series reactions?
What is an essential factor to consider when selecting a reactor for multiple reactions?
What is an essential factor to consider when selecting a reactor for multiple reactions?
What type of reaction involves more than one reactant yielding a complex product?
What type of reaction involves more than one reactant yielding a complex product?
In independent reactions, how are the reactants characterized?
In independent reactions, how are the reactants characterized?
Which of these is NOT a characteristic of multiple reactions?
Which of these is NOT a characteristic of multiple reactions?
What is the role of a limiting reactant in a series reaction?
What is the role of a limiting reactant in a series reaction?
What is the rate expression for the disappearance of A in the reactor?
What is the rate expression for the disappearance of A in the reactor?
If the initial concentration of A ($C_{A0}$) is 4 mol/L, what is the concentration of A when XA = 0.9?
If the initial concentration of A ($C_{A0}$) is 4 mol/L, what is the concentration of A when XA = 0.9?
What is the value of the residence time ($ au$) when XA = 0.9?
What is the value of the residence time ($ au$) when XA = 0.9?
Which reaction condition leads to a higher yield of B?
Which reaction condition leads to a higher yield of B?
What factor is emphasized as key in the context of series reactions?
What factor is emphasized as key in the context of series reactions?
In calculating the mole balance on A, which equation is utilized?
In calculating the mole balance on A, which equation is utilized?
At a concentration of C_A = 0.4 mol/L, what is the yield of B?
At a concentration of C_A = 0.4 mol/L, what is the yield of B?
How does the yield of B in the CSTR compare to other reactors?
How does the yield of B in the CSTR compare to other reactors?
What is the expression for the overall yield of B in a PFR?
What is the expression for the overall yield of B in a PFR?
When integrating the mass balance for B, what value does dV correspond to in terms of dτ?
When integrating the mass balance for B, what value does dV correspond to in terms of dτ?
In the context of a CSTR, what is the relationship between the yield of B and the conversion of A at 90%?
In the context of a CSTR, what is the relationship between the yield of B and the conversion of A at 90%?
What is the initial concentration of A given in the reactions?
What is the initial concentration of A given in the reactions?
At 90% conversion of A, what is the expected concentration of B produced in a PFR?
At 90% conversion of A, what is the expected concentration of B produced in a PFR?
How is the rate of formation of B represented mathematically?
How is the rate of formation of B represented mathematically?
What factor affects the yield of B when using a CSTR compared to a PFR?
What factor affects the yield of B when using a CSTR compared to a PFR?
Which of the following equations correctly represents the rate of change of A in terms of its concentration?
Which of the following equations correctly represents the rate of change of A in terms of its concentration?
What does the expression $dCB/d\tau$ represent in the context of the equation?
What does the expression $dCB/d\tau$ represent in the context of the equation?
Under what condition does the optimal reactor volume $V_{opt}$ occur?
Under what condition does the optimal reactor volume $V_{opt}$ occur?
Which components of the system influence the expression for $dCB/d\tau$?
Which components of the system influence the expression for $dCB/d\tau$?
What relationship does $\tau_{opt} = \frac{1}{k_1 - k_2} \ln \frac{k_2}{k_1}$ suggest about the reaction rates?
What relationship does $\tau_{opt} = \frac{1}{k_1 - k_2} \ln \frac{k_2}{k_1}$ suggest about the reaction rates?
What does the equation $CB = \frac{k_1 CA0}{k_2 - k_1} (e^{-k_1 \tau} - e^{-k_2 \tau})$ define?
What does the equation $CB = \frac{k_1 CA0}{k_2 - k_1} (e^{-k_1 \tau} - e^{-k_2 \tau})$ define?
In the expression $V_{opt} = \tau_{opt} \cdot \upsilon_0$, what does $\upsilon_0$ represent?
In the expression $V_{opt} = \tau_{opt} \cdot \upsilon_0$, what does $\upsilon_0$ represent?
Which condition results in the maximum concentration of B according to the equations provided?
Which condition results in the maximum concentration of B according to the equations provided?
What mathematical method is applicable for solving $dCB$ in terms of $d\tau$?
What mathematical method is applicable for solving $dCB$ in terms of $d\tau$?
How is the concentration of reactant A represented in the context of reaction equations?
How is the concentration of reactant A represented in the context of reaction equations?
What is the expression for the yield of B in a Continuous Stirred Tank Reactor (CSTR)?
What is the expression for the yield of B in a Continuous Stirred Tank Reactor (CSTR)?
At 90% conversion of A, what is required to determine the concentration of B (CB) in a CSTR?
At 90% conversion of A, what is required to determine the concentration of B (CB) in a CSTR?
How is the rate of formation of B (rB) expressed in terms of concentration and time?
How is the rate of formation of B (rB) expressed in terms of concentration and time?
What is the relationship between the input and output flow rates for component A in a steady-state process?
What is the relationship between the input and output flow rates for component A in a steady-state process?
If the initial concentration of A (CA0) is 4 mol/L and the conversion of A is 90%, what is the remaining concentration of A (CA)?
If the initial concentration of A (CA0) is 4 mol/L and the conversion of A is 90%, what is the remaining concentration of A (CA)?
Which factor does not play a role in the calculation of yield (YB) in a CSTR?
Which factor does not play a role in the calculation of yield (YB) in a CSTR?
What represents the conversion of A at which the mole balance on A is evaluated?
What represents the conversion of A at which the mole balance on A is evaluated?
In the context of a PFR, how does the yield of B change with higher conversion rates of A?
In the context of a PFR, how does the yield of B change with higher conversion rates of A?
Flashcards
Multiple reactions
Multiple reactions
Multiple reactions refer to situations where more than one chemical reaction occurs simultaneously.
Parallel or competing reactions
Parallel or competing reactions
Reactions that happen at the same time and compete for the same reactants.
Series reactions
Series reactions
Reactions where the product of one reaction becomes the reactant for the next.
Independent reactions
Independent reactions
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Complex reactions
Complex reactions
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Concentration requirements
Concentration requirements
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Reactor selection
Reactor selection
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Desired product
Desired product
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Yield
Yield
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CSTR (Continuous Stirred Tank Reactor)
CSTR (Continuous Stirred Tank Reactor)
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PFR (Plug Flow Reactor)
PFR (Plug Flow Reactor)
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Space Time (Ï„)
Space Time (Ï„)
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Rate of Reaction (-rA)
Rate of Reaction (-rA)
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Conversion (XA)
Conversion (XA)
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Mole Balance (In - Out + Gen = Accum)
Mole Balance (In - Out + Gen = Accum)
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Overall Yield
Overall Yield
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What is overall yield?
What is overall yield?
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How to calculate yield of B?
How to calculate yield of B?
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What does the mass balance equation tell us?
What does the mass balance equation tell us?
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How to integrate mass balance for CB?
How to integrate mass balance for CB?
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What does the mole balance equation tell us?
What does the mole balance equation tell us?
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How to integrate mole balance for tau?
How to integrate mole balance for tau?
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What's a CSTR?
What's a CSTR?
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What's a PFR?
What's a PFR?
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Residence time
Residence time
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Rate of reaction
Rate of reaction
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Product concentration
Product concentration
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Target product concentration
Target product concentration
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Continuous stirred tank reactor (CSTR)
Continuous stirred tank reactor (CSTR)
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Time constant
Time constant
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Plug Flow Reactor (PFR)
Plug Flow Reactor (PFR)
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What is a series reaction?
What is a series reaction?
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What is the maximum concentration of intermediate (B) in a series reaction?
What is the maximum concentration of intermediate (B) in a series reaction?
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What is the optimal space time in a series reaction?
What is the optimal space time in a series reaction?
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Explain space time (Ï„) in reactor design.
Explain space time (Ï„) in reactor design.
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What is the optimal reactor volume (Vopt)?
What is the optimal reactor volume (Vopt)?
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What is the conversion (XA) in a chemical reaction?
What is the conversion (XA) in a chemical reaction?
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Describe the overall yield in reactor design.
Describe the overall yield in reactor design.
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Explain the rate of reaction (-rA) in chemical kinetics.
Explain the rate of reaction (-rA) in chemical kinetics.
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What is a CSTR (Continuous Stirred Tank Reactor)?
What is a CSTR (Continuous Stirred Tank Reactor)?
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What is a PFR (Plug Flow Reactor)?
What is a PFR (Plug Flow Reactor)?
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Study Notes
Chapter 6: Multiple Reactions
- This chapter, part of the ChE 324: Kinetics and Reactor Design (A) course, focuses on multiple reactions.
- Multiple reactions occur simultaneously, influencing each other and the products formed.
- Multiple reactions analysis is similar to single reactions, but conversion (X) cannot be used directly.
Reasons for Not Using Conversion (X)
- Multiple reactions often have more than one limiting reactant, unlike single reactions.
- Conversion is defined relative to the limiting reactant for a particular reaction. Thus, a reactant limiting in one reaction may not limit another.
- Multiple reactions imply more than one conversion value.
Classification of Multiple Reactions
- Parallel (competing): Reactions occur simultaneously, competing for reactants. Examples include parallel or competing reactions.
- Series: Reactions occur sequentially, one after another, with the product of one reaction being the reactant for the next. Examples include series reactions.
- Independent/Complex: Reactions aren't directly related. Examples include independent/complex reactions. These include crude oil cracking and complex reactions.
Concentration Requirements and Reactor Selection
- Plug Flow Reactor (PFR): Reactant concentration is high initially and decreases progressively towards the outlet.
- Continuous Stirred Tank Reactor (CSTR): Reactant concentration is consistently low at the reactor outlet.
- Semi-batch: Concentration of one reactant is high initially and decreases progressively. The concentration of the other reactants remains consistent.
Review: Multiple Reactions & Selectivity
-
Selectivity (SD/U): The ratio of the rate of formation of the desired product (D) to the rate of formation of the undesired product (U.)
- Instantaneous selectivity, SD/U
- Overall selectivity, SD/U
-
Yield (YD): The ratio of the moles of the desired product to the moles of the reactant at a specific operating time or point.
- Instantaneous yield (YD)
- Overall yield (YD)
-
Goal: Maximize selectivity and yield to enhance desired product formation.
Additional Topics
- More complex calculations for determining yields in various reactor types (CSTR, PFR).
- Detailed analysis of consecutive reactions.
- Optimizing reactor design parameters for maximum desired product formation in series reactions.
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