Ceramic Materials and Processing

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Questions and Answers

What is one of the main purposes of adding carbon black to vulcanized rubber?

  • To reduce roughness
  • To increase tear and abrasion resistance (correct)
  • To decrease tensile strength
  • To make the material less isotropic

Which matrix material is commonly used in fiber-reinforced materials?

  • Ceramics
  • Metals and polymers (correct)
  • Glass
  • Wood

How does the presence of fibers affect the toughness of composite materials?

  • Fibers increase toughness by requiring more energy to cause failure (correct)
  • Fibers weaken the bonding with the matrix, reducing toughness
  • Fibers reduce the toughness by making the material brittle
  • Fibers do not influence the toughness significantly

What characteristic must a good reinforcing fiber possess?

<p>High elastic modulus and reasonable ductility (C)</p> Signup and view all the answers

What property can be achieved through directional control of strong fibers in a composite?

<p>Anisotropic strength characteristics (B)</p> Signup and view all the answers

What is the key aspect of the extrusion method in ceramic processing?

<p>The binder must be removed after the process. (C)</p> Signup and view all the answers

Which of the following is a disadvantage of the slip casting method?

<p>Labour intensive and long cycle time. (A)</p> Signup and view all the answers

What material is primarily used in the injection moulding process for ceramics?

<p>Ceramic-plastic blend. (A)</p> Signup and view all the answers

What is a primary application of the jiggering process?

<p>Clay products like pottery. (D)</p> Signup and view all the answers

Which casting method allows for the production of thin sheets of ceramics?

<p>Doctor-blade method. (C)</p> Signup and view all the answers

In slip casting, what role does the gypsum mould play?

<p>It absorbs moisture from the slurry. (A)</p> Signup and view all the answers

Which statement is NOT true about the extrusion process?

<p>The orientation of ceramic particles is variable. (D)</p> Signup and view all the answers

What is the primary purpose of the drying process before firing ceramics?

<p>To remove moisture and minimize cracking (D)</p> Signup and view all the answers

Which process is referred to as 'maturing' in ceramics?

<p>The firing or sintering to achieve desired strength (C)</p> Signup and view all the answers

What type of ceramics includes materials used for tiles and insulators?

<p>Clay body ceramics (B)</p> Signup and view all the answers

What types of materials are typically used to create glazes?

<p>Inorganic compounds such as quartz and feldspar (D)</p> Signup and view all the answers

Which of the following methods can be used to glaze ceramics?

<p>Maturing both green compact and glaze in a single firing (D)</p> Signup and view all the answers

What is the significance of using diamond abrasives in the machining of ceramics?

<p>To increase dimensional accuracy and surface finish (B)</p> Signup and view all the answers

What characterizes the products made from whitewares?

<p>They include items like earthenwares and porcelain (D)</p> Signup and view all the answers

What is the main limitation of the method used to obtain the inner shape of ceramic products?

<p>It is restricted to axisymmetric parts (D)</p> Signup and view all the answers

Which type of feldspar is characterized by the chemical formula K2O.Al2O3.6SiO2?

<p>Potash feldspar (C)</p> Signup and view all the answers

What materials can ceramics be produced from?

<p>Clays and other minerals or chemically processed powders (A)</p> Signup and view all the answers

Which application is NOT typically associated with ceramic coatings?

<p>Internal combustion engines (B)</p> Signup and view all the answers

What characteristic do composite materials exhibit compared to their individual components?

<p>Properties that are distinctly different from those of the individual materials (A)</p> Signup and view all the answers

Which of the following is NOT an advantage of using composite materials?

<p>Higher costs and maintenance (D)</p> Signup and view all the answers

What is the main purpose of combining two or more materials into a composite?

<p>To enhance the properties by addressing weaknesses (D)</p> Signup and view all the answers

Which one of the following properties is NOT typically enhanced by composite materials?

<p>Increased fatigue problems (D)</p> Signup and view all the answers

Composite materials are classified based on what criteria?

<p>The types of starting materials used (B)</p> Signup and view all the answers

What is one of the materials that is NOT typically included in composite materials?

<p>Biological materials (D)</p> Signup and view all the answers

Ceramics can be classified as which of the following?

<p>Inorganic, non-metallic materials (D)</p> Signup and view all the answers

Which type of ceramic application focuses on environmental and chemical processing?

<p>Chemical processing ceramics (C)</p> Signup and view all the answers

What is a key characteristic of sheet glass?

<p>It can be heat-treated to increase its tensile strength. (D)</p> Signup and view all the answers

How is plate glass obtained?

<p>By rolling plastic glass to a thickness of about 31.75 mm. (C)</p> Signup and view all the answers

Which type of glass is known as 'Safety glass'?

<p>Laminated glass (C)</p> Signup and view all the answers

What method is used to produce glass tubes and rods?

<p>Wrapping molten glass around a rotating mandrel (B)</p> Signup and view all the answers

What process is similar to closed-die forging?

<p>Pressed glassware production (A)</p> Signup and view all the answers

Which type of glass is not typically recommended for automotive glazing due to imperfections?

<p>Sheet glass (A)</p> Signup and view all the answers

What enhances the strength of laminated glass?

<p>Placing transparent vinyl plastic between glass layers (B)</p> Signup and view all the answers

What is a primary application of pressed glassware?

<p>Eyeglasses (B)</p> Signup and view all the answers

What type of glass can be cast onto the surface of a molten tin bath?

<p>Plate glass (A)</p> Signup and view all the answers

In blown glassware production, what is done to obtain a preform?

<p>It is pressed with a punch after being shaped. (B)</p> Signup and view all the answers

What method is used to set up compressive stresses on the surface of glass?

<p>Chemical tempering (D)</p> Signup and view all the answers

Which glass production method employs a closed mould and relies on air pressure for shaping?

<p>Blowing (D)</p> Signup and view all the answers

In which glass processing method does the glass conform to the mould without applying pressure?

<p>Sagging (D)</p> Signup and view all the answers

What is a typical product application of the centrifugal casting method?

<p>TV picture tubes (B)</p> Signup and view all the answers

Which operation is used to relieve residual stresses from glass surfaces after production?

<p>Annealing (C)</p> Signup and view all the answers

Which of the following statements accurately describes the characteristics of enamels?

<p>Enamels are inorganic coatings made with refractory compounds that provide excellent corrosion resistance. (B)</p> Signup and view all the answers

What is the principal ingredient in porcelain enamels?

<p>Frit obtained from molten glass (A)</p> Signup and view all the answers

Which of the following accurately describes the application process of enamels?

<p>Enamels are typically applied in the form of a slurry and can dry through various methods. (A)</p> Signup and view all the answers

How does ruby serve as a laser material?

<p>It is an Al2O3 crystal doped with chromium ions. (D)</p> Signup and view all the answers

Which of the following best describes the process of producing glass?

<p>Glass is made by melt processing, distinct from ceramics production. (A)</p> Signup and view all the answers

Why is frit important in the production of porcelain enamels?

<p>It provides structural integrity after the coating is applied and fused. (D)</p> Signup and view all the answers

Which characteristic sets inorganic enamels apart from organic coatings?

<p>Inorganic enamels provide superior resistance to high temperatures. (C)</p> Signup and view all the answers

What is a significant application for the characteristics of ceramic coatings?

<p>They are frequently applied to enhance the performance of jet engine components. (A)</p> Signup and view all the answers

What is one major benefit of using enamels as coatings for metal surfaces?

<p>They provide excellent resistance to both corrosion and abrasion. (A)</p> Signup and view all the answers

Which additive is used to improve the mixing of ceramic materials?

<p>Wetting agent (A)</p> Signup and view all the answers

What is the main purpose of adding non-plastic materials to clay-based ceramics?

<p>To enhance the degree of vitrification during firing (C)</p> Signup and view all the answers

Which compacting technique typically involves the use of high tonnage presses?

<p>Dry pressing (C)</p> Signup and view all the answers

What is one limitation of pressing in dies for ceramic compaction?

<p>It limits the complexity of shapes that can be formed. (C)</p> Signup and view all the answers

Which method is employed to achieve uniform density in ceramic compaction?

<p>Iso-static pressing (A)</p> Signup and view all the answers

Which of the following additives is used as a deflocculent in ceramic-water suspensions?

<p>Sodium carbonate (B)</p> Signup and view all the answers

Which compaction method is referred to as 'wet pressing'?

<p>Involving high percentages of binders or water (D)</p> Signup and view all the answers

What characteristic differentiates acidic refractories from basic refractories?

<p>Acidic refractories are attacked by basic mediums. (A)</p> Signup and view all the answers

Which material is primarily used in applications that require high melting points and resistance?

<p>Silicon carbide, SiC (D)</p> Signup and view all the answers

What is the primary use of cubic boron nitride (CBN)?

<p>Cutting tool material (B)</p> Signup and view all the answers

Which of the following materials is commonly used in nuclear applications?

<p>Uranium dioxide, UO2 (B)</p> Signup and view all the answers

What is a key advantage of using boron carbide in industrial applications?

<p>Extremely hard material for wear resistance (C)</p> Signup and view all the answers

Which type of refractories would be best suited for extreme high-temperature applications like gas turbines?

<p>Nitrides (A)</p> Signup and view all the answers

What role do neutral refractories play in applications involving acidic and basic materials?

<p>Separate acidic and basic materials (D)</p> Signup and view all the answers

Which of the following materials is used in the production of turbine blades due to its high heat resistance?

<p>Chromium boride (B)</p> Signup and view all the answers

What is a notable property of silicon nitride, Si3N4, that makes it desirable for engine components?

<p>High hardness and toughness (C)</p> Signup and view all the answers

Which property makes cermet a favorable option for applications requiring thermal shock resistance?

<p>Greater thermal shock resistance than ceramics (A)</p> Signup and view all the answers

What makes cemented oxide materials a more cost-effective alternative to cemented carbides?

<p>Their manufacturing process is cheaper. (C)</p> Signup and view all the answers

Which of the following statements about abrasives is correct?

<p>Abrasives possess the ability to wear away softer materials. (C)</p> Signup and view all the answers

Which ceramics are commonly utilized in electronic applications due to their insulating properties?

<p>Silicon carbide and barium titanate (C)</p> Signup and view all the answers

What distinguishes yttralox in optical applications compared to other ceramics?

<p>It is free from pores, making it transparent. (C)</p> Signup and view all the answers

Which ceramic material is primarily associated with high-voltage insulators?

<p>Alumina (A)</p> Signup and view all the answers

In typical abrasive operations, which process is NOT commonly used?

<p>Sintering (D)</p> Signup and view all the answers

Which ceramic is known for its use as a thermistor due to semiconducting properties?

<p>Barium titanate (D)</p> Signup and view all the answers

What is a primary characteristic of cermets when compared to traditional ceramics?

<p>They exhibit better thermal stability. (C)</p> Signup and view all the answers

Which ceramic material is highly demanded for its dielectric properties?

<p>Mica (A)</p> Signup and view all the answers

Flashcards

Extrusion Forming

A ceramic-binder blend or a ceramic-water blend is extruded through a press to create shapes, often with internal openings. It's similar to squeezing toothpaste out of a tube.

Injection Molding for Ceramics

Mixes a ceramic powder with a plastic binder, then injects it into a mold to create complex shapes. Like how a plastic injection machine creates toys.

Slip Casting

Ceramic slurry is poured into a gypsum mold. The mold absorbs moisture, leaving the ceramic body against the mold's walls.

Doctor-Blade Method

A thin layer of ceramic slip is spread over a moving plastic belt, controlled by a blade. This creates thin ceramic sheets.

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Slip Casting: Rolling Method

Ceramic slip is rolled between rollers, then a layer is cast over a paper tape. The tape is burned off during firing.

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Jiggering

A forming process used for clay products, similar to a potter's wheel. Clay is placed in a mold and shaped with a jigger.

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Fiber-Reinforced Materials

A composite material where strong, thin fibers are embedded in a weaker matrix material. The fibers are typically arranged in a specific direction, providing high strength in that direction.

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Toughness

The ability of a material to withstand deformation without breaking. It's related to how much energy is needed to fracture the material.

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Tensile Strength

The property of a material that describes its resistance to stretching or breaking under tension.

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Anisotropic

Materials with properties that are different in different directions. These materials often have strong, directional fibers.

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Isotropic

A material with uniform properties in all directions. It can apply forces and withstand pressure equally in any direction.

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Composite Materials

Materials that combine two or more different substances to create a new material with enhanced properties.

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Ceramic

A material that is neither metallic nor organic, often made from clay or mineral powders, and commonly used in electronics and industrial applications.

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Ceramic Coatings

Ceramics are used in engine parts, cutting tools, and industrial wear components because of their high heat resistance and hardness.

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Sheet Glass

A type of glass produced by rolling molten glass into a flat sheet. It is commonly used for windows, mirrors, and tabletops.

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Plate Glass

A type of glass made by rolling molten glass to a specific thickness, then grinding and polishing it for optical flatness. It is often used for automotive glazing, storefront windows, and tracing tables.

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Chemical Processing and Environmental Ceramics

Ceramics are used in filters, membranes, catalysts (promoting chemical reactions), and catalyst supports in environmental and chemical processing.

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Composite Materials

The combination of two or more distinct materials, which can be organic, metallic, or ceramic, to create a material with unique properties.

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Laminated Glass

A type of safety glass made by sandwiching a layer of clear vinyl plastic between two sheets of plate glass. It prevents shattering and is widely used in vehicles and construction.

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How Composite Materials are Made

Composite materials are designed and manufactured, rather than occurring naturally as alloys.

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Drawn Glassware

Glass tubing and rods produced by drawing molten glass from a furnace onto a rotating cylindrical mandrel. It is used in gauges, pipes, and insulation.

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Maintaining Identity in Composites

The components of a composite material maintain their individual identities, even after being combined.

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Pressed Glassware

A type of glass created by pressing a measured amount of molten glass into steel or iron molds. This process is similar to forging metal.

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Strength and Weakness in Composites

The combination of materials in a composite material aims to compensate for weaknesses in one component with strengths in another.

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Blown Glassware

A type of glass produced by blowing molten glass into a mold to create hollow pieces with thinner walls. This method is used for creating bottles, jars, and decorative items.

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Heat Treatment of Sheet Glass

A technique used to increase the tensile strength of sheet glass by heat treating it. This process makes the glass stronger and more resistant to breakage.

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Unique Properties of Composites

Composite materials exhibit properties that are distinct from the individual materials used to make them.

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Properties of Composite Materials

Composite materials are sought out for their unique combinations of properties, including stiffness, strength, hardness, light weight, conductivity, corrosion resistance, and high-temperature performance.

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Wiremesh Glass

Adding wire mesh to molten glass during production to create a stronger, safer glass. It prevents the glass from shattering into large pieces.

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Tempered Glass

A type of glass that is heat-treated to increase its strength and resistance to shattering. It is often used in applications where safety is critical.

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Automotive Glass

A type of glass that is designed to be used in vehicles. It is made of laminated glass and is designed to stay intact even if broken.

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What is the shaping process where a tool is forced into rotating material?

A shaping process where a shaped tool is forced into rotating material, creating axisymmetric parts with limited dimensional accuracy.

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What is the purpose of firing or sintering in ceramic processing?

The process of heating a compacted ceramic product to achieve desired strength by removing moisture and binding particles.

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What is Glaze?

A glassy coating applied to ceramic products to make them water-tight and improve their appearance. It's made from inorganic compounds mixed with water into a slurry.

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What is the green state of a ceramic product?

The state of a ceramic product after compacting but before firing. It lacks desired strength.

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What is Bisque?

A matured ceramic product after firing. It is porous and ready for glazing.

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What is a ghost fire?

A low-temperature firing process to mature the glaze after it is applied to bisque.

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What is glazing a green compact?

The process of applying a glaze to a green compact before firing, resulting in a single firing process.

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What are clay products?

A type of ceramic ware that encompasses whitewares and stoneware. It includes products like tiles, sanitary ware, and insulators.

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What are whitewares?

Types of ceramic products characterized by their white color and fine-grained structure. They include earthenware, china, and porcelain.

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Plasticizer

A material added to ceramic mixtures to improve their plasticity and formability, making them easier to shape.

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Deflocculents

Chemicals added to ceramic suspensions to prevent particles from clumping together, creating a smooth, even mixture.

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Firing or Sintering

A process of heating a compacted ceramic product to remove moisture and bind particles together, achieving desired strength.

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Glaze

A glassy coating applied to ceramic products to make them waterproof and enhance their appearance.

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Green State

A state of a ceramic product after compacting but before firing. It lacks desired strength.

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Bisque

A matured ceramic product after firing. It is porous and ready for glazing.

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Ghost Firing

A lower temperature firing process to mature the glaze after it is applied to bisque.

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Acidic Refractory

A type of refractory material that resists attack by acidic substances but is vulnerable to basic environments.

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Neutral Refractory

Refractory materials that are used to separate acidic and basic materials because they are resistant to attack by both.

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Basic Refractory

A type of refractory material that is resistant to attack by basic substances but is vulnerable to acidic environments.

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Refractory Ceramic

A type of ceramic material that is made up of pure metallic oxides, carbides, borides, nitrides, and sulfides.

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Alumina (Al2O3)

The most commonly used oxide refractory ceramic, known for its high melting point and its use in various applications like cutting tools, spark plug insulators, and electronic circuits.

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Carbides

A material that has the highest melting point of all substances, commonly used for high-temperature applications due to its resistance.

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Silicon Carbide (SiC)

A type of carbide that is difficult to sinter but is used in high-temperature applications like resistance-heating elements and rocket nozzles due to its high melting point and resistance.

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Boron Carbide (B4C)

A type of ceramic material known for its extreme hardness, making it suitable for use in hard, abrasive applications such as grinding grits.

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Cubic Boron Nitride (CBN)

A type of nitride known for its high melting point and use in cutting tools and other applications.

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Abrasive

A hard material used to wear away a softer material, typically used in operations like scratching, grinding, cutting, rubbing, and polishing.

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What is Cermet used for?

A ceramic material, often used in cutting tools, crucibles, and jet engine nozzles, that offers improved thermal shock resistance while maintaining high refractoriness.

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Cutting Tool Materials

Ceramics, such as carbides, nitrides, oxides, and cermets, find various applications in cutting tools due to their hardness and wear resistance.

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Electrical & Magnetic Applications of Ceramics

Ceramics are widely used in electrical and electronic industries as insulators, semiconductors, dielectrics, ferroelectrics, and piezoelectric crystals due to their unique electrical properties.

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Ceramic Pigments

A material with exceptional durability, completely oxidized and resistant to chemical attack, which makes it valuable for pigments.

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Yttralox

A new ceramic material, known for its transparency and high-temperature resistance, finding uses in optical applications.

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Why are Ceramics Usually Opaque?

Ceramics generally appear opaque due to the presence of tiny pores that scatter light. However, materials like Yttralox, devoid of pores, exhibit transparency.

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Semiconducting Properties in Ceramics

Ceramics like SiC are used in resistors and heating elements of furnaces due to their semiconducting properties, allowing them to control and generate heat.

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Barium Titanate & Piezoelectricity

Barium titanate, a ceramic material, is often used in capacitors and transducers due to its piezoelectric properties, which convert mechanical energy into electrical energy or vice versa.

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Sagging

This method involves heating a sheet of glass over a mold, allowing it to soften and conform to the mold's shape.

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Spinning (Centrifugal Casting)

In this process, molten glass is forced against the walls of a rotating mold using centrifugal force. It then cools and solidifies.

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Thermal Tempering

This technique strengthens glass by rapidly cooling it. The rapid cooling sets up tensile stresses on the surface of the glass, making it stronger.

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Chemical Tempering

This method strengthens glass by heating it in a bath of molten salts. Larger ions in the salts replace smaller atoms on the surface of the glass, creating compressive stress.

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Finishing Operations

This process relieves residual stresses in glass, similar to annealing metals. It also includes finishing operations like cutting, drilling, grinding, and polishing to refine the glass.

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Enamels

A glass-like coating applied to metal products, providing excellent resistance to corrosion, high temperatures, and abrasion. They are made from refractory compounds and are applied as a slurry.

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Porcelain Enamel

A type of enamel made from highly durable alkaliborosilicate glass that is fused to metal substrates at high temperatures (above 425°C).

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Frit

A special glass of friable particles produced by quenching molten glass. It's a key ingredient in porcelain enamel.

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Clay Products

A type of ceramic ware that encompasses both whitewares and stoneware. This includes products like tiles, sanitary ware, and insulators.

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Whitewares

Types of ceramic products characterized by their white color and fine-grained structure. They include earthenware, china, and porcelain.

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Study Notes

Ceramic Materials and Their Processing

  • Ceramics are sensitive to flaws but with higher purity and improved processing, can be used for high-temperature structures.
  • Ceramics have low tensile strength (e.g., Alumina ~190 MPa) but high compressive strength (e.g., Alumina 1950-3500 MPa).
  • Ceramics lack ductility, making machining difficult. Shaping and turning of unfired or slightly fired ceramics is sometimes possible for small items.

Processing of Ceramics

  • Ceramic processing (except glass) follows a powder metallurgy approach.
  • Steps include: powder preparation, mixing/blending, compacting, and firing/sintering.

Preparation of Powders

  • Natural ceramics are mined and crushed/milled to powders.
  • Impurities are removed through various methods (screening, magnetism, filtration, etc.).
  • Manufactured ceramics (e.g., Alumina, Silicon Carbide, Silicon Nitride) are produced through high-temperature reactions (e.g., silicon metal with Nâ‚‚ gas).
  • Manufactured ceramics are then reduced to specific sizes and distributions.

Mixing and Blending

  • The purpose of mixing and blending ceramics is similar to powder metallurgy techniques.
  • Various materials (different ceramics, lubricants, binders) are combined.
  • Organic binders (polymers, waxes) and inorganic binders (clays, silicates) are used.
  • Lubricants (e.g., polymers, waxes) reduce friction and enhance flow. Water, Naâ‚‚CO₃, Naâ‚‚SiO₃ are added for mixing and plasticity.
  • Additives (e.g., Naâ‚‚CO₃, Naâ‚‚SiO₃) control foaming and sintering.

Compacting of Ceramics

  • Various powder metallurgy techniques are used for shaping ceramic powders.
  • Pressing (dry and wet), isostatic pressing, extrusion, slip casting, injection molding, and jiggering are applicable.
  • Isostatic pressing improves density uniformity of the compact.

Firing or Sintering

  • The green ceramic compact is fired or sintered to achieve the desired strength.
  • Drying at room temperature and low-temp. heating is the initial step to remove any moisture and prevent stresses during firing.
  • Slow heating and cooling can take several days or weeks.
  • Glazing (coating with a glassy material) can be done either before or after firing (bisque fire, followed by a subsequent glaze fire).

Product Applications

  • Clay-based ceramics (earthenware, china, porcelain, stoneware) are used in various applications (e.g., tableware, tiles, insulators, chemical reactors).
  • Refractories are high-temperature resistant ceramics (acidic, basic, neutral). Applications include furnace linings, boilers, flues, and regenerators, as well as high temperature applications in gas turbines.
  • Cutting tool materials include carbides, nitrides, oxides, and cermets, used for their hardness and heat resistance.
  • Electrical ceramics (insulators, semiconductors, dielectrics) are widely used in electronics, including capacitors, high voltage insulators, resistors, and heating elements.
  • Optical ceramics (e.g., Yttralox) find applications in optical components.
  • Enamels are inorganic coatings, often for metal products (both organic and inorganic coatings). They are highly corrosion-resistant and durable. Porcelain enamels are fired onto metal substrates.

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