Cement: Properties, History, and Manufacturing
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Questions and Answers

The first ASTM specification was issued in ______.

1904

The raw materials required for the manufacture of Portland cement include calcareous materials such as limestone and ______.

chalk

The process of manufacture of cement includes grinding, mixing, and burning the materials in a ______ at high temperatures.

kiln

The temperature range for burning the raw materials in the kiln is about ______ to 1500°C.

<p>1300</p> Signup and view all the answers

Cement factories are established where raw materials are available in ______.

<p>plenty</p> Signup and view all the answers

After the clinker is formed, it is cooled and ground to fine powder with the addition of about ______ to 5% of gypsum.

<p>3</p> Signup and view all the answers

The mixture is fed into a rotary kiln, which is slightly ______.

<p>inclined</p> Signup and view all the answers

In the hottest part of the kiln, some 20 to 30 percent of the material becomes ______.

<p>liquid</p> Signup and view all the answers

False set refers to the abnormal stiffening of cement within a few minutes of mixing with ______.

<p>water</p> Signup and view all the answers

The total surface area of cement particles represents the material available for ______.

<p>hydration</p> Signup and view all the answers

Finer cement offers a greater surface area for hydration, leading to a ______ development of strength.

<p>faster</p> Signup and view all the answers

Unsoundness in cement is often due to an excess of lime (CaO) or an excess of ______.

<p>magnesia</p> Signup and view all the answers

Strength tests for cement are typically performed on cement–______ mortars.

<p>sand</p> Signup and view all the answers

It is recommended that there should be about 25-30 percent of cement particles of less than ______ micron in size.

<p>7</p> Signup and view all the answers

Field testing of cement is often sufficient for use in ______ works.

<p>minor</p> Signup and view all the answers

The reaction of cement with water is ______.

<p>exothermic</p> Signup and view all the answers

The liberation of heat during the hydration process is called ______ of hydration.

<p>heat</p> Signup and view all the answers

Calcium silicate hydrate is abbreviated as ______.

<p>C-S-H</p> Signup and view all the answers

Complete hydration cannot be obtained under a period of one year or ______.

<p>more</p> Signup and view all the answers

C3S produces a comparatively lesser quantity of calcium silicate hydrates and more quantity of ______.

<p>Ca(OH)2</p> Signup and view all the answers

Calcium hydroxide constitutes ______ to 25 percent of the volume of solids in the hydrated paste.

<p>20</p> Signup and view all the answers

C3S readily reacts with water and produces more ______ of hydration.

<p>heat</p> Signup and view all the answers

C2S hydrates rather slowly and is responsible for the ______ strength of concrete.

<p>later</p> Signup and view all the answers

After 28 days of curing, cement grains have been found to have hydrated to a depth of only ______.

<p>4μ</p> Signup and view all the answers

In hydraulic structures, the presence of Ca(OH)2 can make the concrete ______.

<p>porous</p> Signup and view all the answers

The main compounds of Portland cement include C3S, C2S, C3A, and ______.

<p>C4AF</p> Signup and view all the answers

C3S and C2S are the most important compounds responsible for the ______ of hydrated cement paste.

<p>strength</p> Signup and view all the answers

The calculation of the potential composition of Portland cement is often referred to as ______ composition.

<p>Bogue</p> Signup and view all the answers

The reaction between cement and water is known as the ______ of cement.

<p>hydration</p> Signup and view all the answers

The presence of C3A in cement is considered ______ as it contributes little to strength.

<p>undesirable</p> Signup and view all the answers

Minor compounds such as Na2O and K2O are known as ______.

<p>alkalis</p> Signup and view all the answers

C4AF reacts with gypsum and accelerates the ______ of silicates.

<p>hydration</p> Signup and view all the answers

The actual proportions of compounds in cement can vary considerably from ______ to cement.

<p>cement</p> Signup and view all the answers

Anhydrous cement does not bind aggregates until it is mixed with ______.

<p>water</p> Signup and view all the answers

Bogue's equations are used to determine the percentages of the main ______ in cement.

<p>compounds</p> Signup and view all the answers

Capillary pores may be fully filled with water or ______ with water.

<p>partly</p> Signup and view all the answers

The nominal diameter of gel pores is about ______ nm.

<p>3</p> Signup and view all the answers

For C3S and C2S compounds, an average of ______ % of water by weight of cement is required for chemical reaction.

<p>23</p> Signup and view all the answers

A total of ______ % of water by weight of cement is required for complete hydration.

<p>38</p> Signup and view all the answers

Excess water over 38 % will cause undesirable ______ cavities.

<p>capillary</p> Signup and view all the answers

Setting refers to a change from a fluid to a ______ stage.

<p>rigid</p> Signup and view all the answers

Initial setting time is the time elapsed from when water is added to cement until the paste starts losing its ______.

<p>plasticity</p> Signup and view all the answers

Flash set occurs in cement with insufficient ______ to control the rapid reaction of C3A with water.

<p>gypsum</p> Signup and view all the answers

The final setting time is when the paste has completely lost its ______ and has attained firmness.

<p>plasticity</p> Signup and view all the answers

If less than 38 % of water is used, complete hydration is not ______.

<p>possible</p> Signup and view all the answers

Flashcards

Heat of Hydration

The heat released during the chemical reaction of cement with water.

Rate of Hydration

The speed at which different components of cement react with water.

Calcium Silicate Hydrate (C-S-H)

A compound formed when cement reacts with water, essential for concrete strength.

Calcium Hydroxide (Ca(OH)2)

A byproduct of cement hydration, it can weaken concrete if it dissolves.

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Tricalcium Silicate (C3S)

The chemical compound in cement that hydrates quickly, giving early strength.

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Dicalcium Silicate (C2S)

The chemical compound in cement that hydrates slowly, responsible for long-term strength.

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Complete Hydration

Complete hydration of cement takes a very long time, even years.

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Cement Hydration

The process where cement particles react with water, forming new compounds.

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Curing (Concrete)

The process of curing concrete to allow it to gain strength.

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Later Strength

Strength developed in concrete over time due to the slow hydration of C2S.

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What is Portland cement?

Portland cement is a type of hydraulic cement that is often used because it is a strong and durable material.

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What are the raw materials used to make Portland cement?

Portland cement is made from a mixture of calcareous materials, such as limestone, and argillaceous material, such as shale or clay.

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Describe the steps involved in manufacturing Portland cement.

The process of making Portland cement involves grinding, mixing, burning, cooling, and grinding the raw materials in a carefully controlled way.

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What happens to the raw materials during the burning stage in cement production?

The raw materials are heated to a high temperature (1300-1500°C) in a rotary kiln, causing them to sinter and partially fuse into nodular clinker.

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What is a rotary kiln, and how is it used in cement production?

The rotary kiln is a long, cylindrical furnace that rotates to slowly move the material through the heat zone.

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Why is gypsum added to the clinker during cement production?

Gypsum is added to the clinker during the final grinding stage to control the setting time of the cement.

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What are the two main processes for producing Portland cement?

The 'wet' process involves mixing and grinding the raw materials with water, while the 'dry' process uses dry materials.

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What is the purpose of intergrinding the cooled clinker with gypsum?

The clinker, after cooling, is interground with gypsum to prevent rapid setting of the cement mixture.

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Bogue Composition

A method used to calculate the composition of Portland cement based on its oxide content. It provides estimates for the percentages of key cement compounds like C3S, C2S, C3A, and C4AF.

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Tricalcium Aluminate (C3A)

A cement compound that helps with early setting but provides little to no long-term strength. Its presence can even lead to expansion and cracking in concrete.

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Tetracalcium Aluminoferrite (C4AF)

A minor cement compound that reacts with gypsum and accelerates the hydration of silicates, which is the process of cement hardening.

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Hydration of Cement

The chemical reaction that happens when cement is mixed with water. It's the process that gives cement its binding abilities and hardens it.

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Adhesive Property of Cement

The ability of hardened cement paste to hold together fine and coarse aggregates, giving concrete its structural integrity.

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Hydrated Products of Cement

The product formed during cement hydration. These products are crucial for the strength and durability of concrete.

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Chemistry of Concrete

The study of the chemical reactions and processes that occur within concrete during its formation and hardening. It includes the understanding of the various compounds involved and their interactions.

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Gel pores

Tiny, interconnected spaces within the hardened cement paste, formed during hydration. These spaces are filled with gel water and contribute to the cement's strength.

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Capillary pores

Larger spaces within the hardened cement paste, often filled with air or water. They can reduce the overall strength of the cement.

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Bound water

Water that chemically combines with the cement during hydration. This water becomes a part of the hardened cement paste.

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Gel water

Water that is physically present within the gel pores of hardened cement paste. This water contributes to the overall moisture content and strength of the cement.

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Setting of cement

The point at which a cement paste transitions from a fluid to a solid state. This is the initial hardening process.

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Hardening of cement

The continuous increase in strength of a set cement paste over time. This is the process of getting stronger and harder.

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Initial setting time

The time elapsed from mixing cement with water until the paste begins to lose its fluidity and starts to harden.

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Final setting time

The time elapsed from mixing cement with water until the paste completely loses its fluidity and becomes a rigid solid.

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Flash set

A rapid hardening of the cement paste, often caused by insufficient gypsum control, leading to a quick loss of fluidity.

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What is False Set?

A rapid stiffening of cement paste soon after mixing with water, caused by a chemical reaction that releases little or no heat. It can be reversed by remixing the paste without adding more water.

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What is Fineness of Cement?

The total surface area of cement particles exposed to water, which determines the rate of hydration and strength development.

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What is Soundness of Cement?

The property of cement that allows it to withstand dimensional changes after setting, ensuring long-term stability of concrete structures.

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Unsoundness due to Lime (CaO)

A common cause of unsoundness in cement, where the cement expands after setting due to excessive lime content.

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Unsoundness due to Magnesia (MgO)

A common reason for unsoundness, where excess magnesium oxide (MgO) in cement can expand, causing cracks.

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What is a Cement-Sand Mortar Test?

A form of strength test used to determine the strength of cement by testing a mixture of cement and sand.

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What is Compressive Strength of Cement?

The ability of cement paste or hardened concrete to resist crushing forces, indicating its strength and durability.

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Study Notes

What is Cement?

  • Cement is a material with adhesive and cohesive properties, bonding mineral fragments into a whole.
  • Portland cement is primarily made from calcareous materials (e.g., limestone, chalk) and alumina and silica (e.g., clay, shale).
  • Hydraulic cements harden and set under water due to chemical reactions.

Historical Background

  • Cementing materials have been used in construction by ancient civilizations (e.g., Egyptians, Romans, Indians).
  • Joseph Aspdin, a Leeds builder, patented Portland cement in 1824.
  • The name "Portland" comes from a resemblance to a natural stone found in England.
  • Initially, cement was used to make mortar, later for concrete.

Manufacture of Portland Cement

  • Raw materials include calcareous and argillaceous materials (e.g., limestone, chalk, shale, clay).
  • The process involves grinding raw materials, mixing in specific proportions, burning in a kiln (1300-1500°C), cooling, and grinding to a fine powder, and adding gypsum (3-5%).
  • Two processes exist: wet and dry. Wet involves mixing and grinding raw materials in wet conditions, while dry does so in dry conditions.
  • The resulting powder is Portland cement.

Chemical Composition of Portland Cement

  • Cement's makeup involves lime, silica, alumina, and iron oxides.
  • Different oxides form various compounds: C3S, C2S, C3A, C4AF (Bogue compounds).
  • The relative proportions of these compounds affect cement properties.

Hydration of Cement

  • Cement's reaction with water is called hydration, a crucial process for strength development.
  • Hydrated products, like calcium silicate hydrates (C-S-H) and calcium hydroxide (Ca(OH)2) are vital.
  • The hydration process occurs at a decreasing rate, taking longer than a year to fully hydrate.
  • Heat is released during hydration.
  • Complete hydration requires water and fine particles of cement.

Setting and Hardening of Cement

  • Setting: The transition from fluid to solid stage.
  • Setting time involves the loss of plasticity. Initial setting is when the paste loses its plasticity momentarily, and final setting defines the time where the paste has attained sufficient firmness.
  • Hardening: Further strength development.
  • The rate of setting/hardening varies with cement type and external conditions.

Fineness of Cement

  • Finer cement has more surface area for hydration and faster strength development.
  • Cement particle size influences initial strength.

Types of Portland Cement

  • Different types cater to specific needs, like rapid hardening, low heat, or sulfate resistance.
  • Types include OPC, rapid, low heat, and sulfate resistant cement types.
  • Standard classifications exist based on strength and other properties.

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Explore the fascinating world of cement, highlighting its adhesive properties, historical significance, and manufacturing process. Learn how ancient civilizations contributed to cement's evolution and understand the steps involved in producing Portland cement. This quiz delves into essential aspects of one of the key materials in construction.

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