Cement: Properties, History, and Manufacturing
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Questions and Answers

The first ASTM specification was issued in ______.

1904

The raw materials required for the manufacture of Portland cement include calcareous materials such as limestone and ______.

chalk

The process of manufacture of cement includes grinding, mixing, and burning the materials in a ______ at high temperatures.

kiln

The temperature range for burning the raw materials in the kiln is about ______ to 1500°C.

<p>1300</p> Signup and view all the answers

Cement factories are established where raw materials are available in ______.

<p>plenty</p> Signup and view all the answers

After the clinker is formed, it is cooled and ground to fine powder with the addition of about ______ to 5% of gypsum.

<p>3</p> Signup and view all the answers

The mixture is fed into a rotary kiln, which is slightly ______.

<p>inclined</p> Signup and view all the answers

In the hottest part of the kiln, some 20 to 30 percent of the material becomes ______.

<p>liquid</p> Signup and view all the answers

False set refers to the abnormal stiffening of cement within a few minutes of mixing with ______.

<p>water</p> Signup and view all the answers

The total surface area of cement particles represents the material available for ______.

<p>hydration</p> Signup and view all the answers

Finer cement offers a greater surface area for hydration, leading to a ______ development of strength.

<p>faster</p> Signup and view all the answers

Unsoundness in cement is often due to an excess of lime (CaO) or an excess of ______.

<p>magnesia</p> Signup and view all the answers

Strength tests for cement are typically performed on cement–______ mortars.

<p>sand</p> Signup and view all the answers

It is recommended that there should be about 25-30 percent of cement particles of less than ______ micron in size.

<p>7</p> Signup and view all the answers

Field testing of cement is often sufficient for use in ______ works.

<p>minor</p> Signup and view all the answers

The reaction of cement with water is ______.

<p>exothermic</p> Signup and view all the answers

The liberation of heat during the hydration process is called ______ of hydration.

<p>heat</p> Signup and view all the answers

Calcium silicate hydrate is abbreviated as ______.

<p>C-S-H</p> Signup and view all the answers

Complete hydration cannot be obtained under a period of one year or ______.

<p>more</p> Signup and view all the answers

C3S produces a comparatively lesser quantity of calcium silicate hydrates and more quantity of ______.

<p>Ca(OH)2</p> Signup and view all the answers

Calcium hydroxide constitutes ______ to 25 percent of the volume of solids in the hydrated paste.

<p>20</p> Signup and view all the answers

C3S readily reacts with water and produces more ______ of hydration.

<p>heat</p> Signup and view all the answers

C2S hydrates rather slowly and is responsible for the ______ strength of concrete.

<p>later</p> Signup and view all the answers

After 28 days of curing, cement grains have been found to have hydrated to a depth of only ______.

<p>4μ</p> Signup and view all the answers

In hydraulic structures, the presence of Ca(OH)2 can make the concrete ______.

<p>porous</p> Signup and view all the answers

The main compounds of Portland cement include C3S, C2S, C3A, and ______.

<p>C4AF</p> Signup and view all the answers

C3S and C2S are the most important compounds responsible for the ______ of hydrated cement paste.

<p>strength</p> Signup and view all the answers

The calculation of the potential composition of Portland cement is often referred to as ______ composition.

<p>Bogue</p> Signup and view all the answers

The reaction between cement and water is known as the ______ of cement.

<p>hydration</p> Signup and view all the answers

The presence of C3A in cement is considered ______ as it contributes little to strength.

<p>undesirable</p> Signup and view all the answers

Minor compounds such as Na2O and K2O are known as ______.

<p>alkalis</p> Signup and view all the answers

C4AF reacts with gypsum and accelerates the ______ of silicates.

<p>hydration</p> Signup and view all the answers

The actual proportions of compounds in cement can vary considerably from ______ to cement.

<p>cement</p> Signup and view all the answers

Anhydrous cement does not bind aggregates until it is mixed with ______.

<p>water</p> Signup and view all the answers

Bogue's equations are used to determine the percentages of the main ______ in cement.

<p>compounds</p> Signup and view all the answers

Capillary pores may be fully filled with water or ______ with water.

<p>partly</p> Signup and view all the answers

The nominal diameter of gel pores is about ______ nm.

<p>3</p> Signup and view all the answers

For C3S and C2S compounds, an average of ______ % of water by weight of cement is required for chemical reaction.

<p>23</p> Signup and view all the answers

A total of ______ % of water by weight of cement is required for complete hydration.

<p>38</p> Signup and view all the answers

Excess water over 38 % will cause undesirable ______ cavities.

<p>capillary</p> Signup and view all the answers

Setting refers to a change from a fluid to a ______ stage.

<p>rigid</p> Signup and view all the answers

Initial setting time is the time elapsed from when water is added to cement until the paste starts losing its ______.

<p>plasticity</p> Signup and view all the answers

Flash set occurs in cement with insufficient ______ to control the rapid reaction of C3A with water.

<p>gypsum</p> Signup and view all the answers

The final setting time is when the paste has completely lost its ______ and has attained firmness.

<p>plasticity</p> Signup and view all the answers

If less than 38 % of water is used, complete hydration is not ______.

<p>possible</p> Signup and view all the answers

Study Notes

What is Cement?

  • Cement is a material with adhesive and cohesive properties, bonding mineral fragments into a whole.
  • Portland cement is primarily made from calcareous materials (e.g., limestone, chalk) and alumina and silica (e.g., clay, shale).
  • Hydraulic cements harden and set under water due to chemical reactions.

Historical Background

  • Cementing materials have been used in construction by ancient civilizations (e.g., Egyptians, Romans, Indians).
  • Joseph Aspdin, a Leeds builder, patented Portland cement in 1824.
  • The name "Portland" comes from a resemblance to a natural stone found in England.
  • Initially, cement was used to make mortar, later for concrete.

Manufacture of Portland Cement

  • Raw materials include calcareous and argillaceous materials (e.g., limestone, chalk, shale, clay).
  • The process involves grinding raw materials, mixing in specific proportions, burning in a kiln (1300-1500°C), cooling, and grinding to a fine powder, and adding gypsum (3-5%).
  • Two processes exist: wet and dry. Wet involves mixing and grinding raw materials in wet conditions, while dry does so in dry conditions.
  • The resulting powder is Portland cement.

Chemical Composition of Portland Cement

  • Cement's makeup involves lime, silica, alumina, and iron oxides.
  • Different oxides form various compounds: C3S, C2S, C3A, C4AF (Bogue compounds).
  • The relative proportions of these compounds affect cement properties.

Hydration of Cement

  • Cement's reaction with water is called hydration, a crucial process for strength development.
  • Hydrated products, like calcium silicate hydrates (C-S-H) and calcium hydroxide (Ca(OH)2) are vital.
  • The hydration process occurs at a decreasing rate, taking longer than a year to fully hydrate.
  • Heat is released during hydration.
  • Complete hydration requires water and fine particles of cement.

Setting and Hardening of Cement

  • Setting: The transition from fluid to solid stage.
  • Setting time involves the loss of plasticity. Initial setting is when the paste loses its plasticity momentarily, and final setting defines the time where the paste has attained sufficient firmness.
  • Hardening: Further strength development.
  • The rate of setting/hardening varies with cement type and external conditions.

Fineness of Cement

  • Finer cement has more surface area for hydration and faster strength development.
  • Cement particle size influences initial strength.

Types of Portland Cement

  • Different types cater to specific needs, like rapid hardening, low heat, or sulfate resistance.
  • Types include OPC, rapid, low heat, and sulfate resistant cement types.
  • Standard classifications exist based on strength and other properties.

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Description

Explore the fascinating world of cement, highlighting its adhesive properties, historical significance, and manufacturing process. Learn how ancient civilizations contributed to cement's evolution and understand the steps involved in producing Portland cement. This quiz delves into essential aspects of one of the key materials in construction.

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