CEM 141 – Chapter 2 Study Notes
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CEM 141 – Chapter 2 Study Notes

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Questions and Answers

What describes the relationship between wavelength and frequency in electromagnetic radiation?

  • They are directly proportional.
  • Wavelength increases as frequency increases.
  • They are independent of each other.
  • Wavelength decreases as frequency increases. (correct)
  • Which component of electromagnetic radiation refers to the height of the peaks?

  • Amplitude (correct)
  • Wavelength
  • Frequency
  • Energy
  • In the speed of light equation, which variable represents wavelength?

  • c
  • λ (correct)
  • E
  • ν
  • Which type of electromagnetic radiation has the highest energy?

    <p>X-rays</p> Signup and view all the answers

    Why do He atoms interact through London Dispersion Forces (LDFs) instead of forming covalent bonds?

    <p>He is a noble gas with a complete electron shell.</p> Signup and view all the answers

    What happens to the energy of light as its frequency increases?

    <p>It increases.</p> Signup and view all the answers

    Which wavelength is most likely associated with red light?

    <p>700 nm</p> Signup and view all the answers

    Which statement is true regarding light?

    <p>Light exhibits both wave and particle properties.</p> Signup and view all the answers

    Which statement accurately describes core electrons?

    <p>They do not participate in chemical reactions.</p> Signup and view all the answers

    What is the electron configuration for chlorine (Cl)?

    <p>[Ne] 3s2 3p5</p> Signup and view all the answers

    According to the Aufbau principle, how are electrons added to orbitals?

    <p>From lower energy to higher energy orbitals.</p> Signup and view all the answers

    How many valence electrons does phosphorus (P) have?

    <p>5</p> Signup and view all the answers

    Which of the following elements is classified as a p-block element?

    <p>Chlorine (Cl)</p> Signup and view all the answers

    What is the core and valence electron configuration for oxygen (O)?

    <p>Core: 2, Valence: 4</p> Signup and view all the answers

    According to Hund's Rule, what is the correct way to fill orbitals?

    <p>Single electrons must occupy each orbital before pairing occurs.</p> Signup and view all the answers

    What is the total number of core and valence electrons in bromine (Br)?

    <p>28 core, 7 valence</p> Signup and view all the answers

    What is the reason for the significant increase in the third ionization energy of magnesium?

    <p>Change from valence to core electron removal</p> Signup and view all the answers

    Which factor contributes most significantly to the increase in ionization energy as more electrons are removed from an atom?

    <p>Decreased electron shielding</p> Signup and view all the answers

    Given the trend in ionization energies, which element in period three is likely to have the highest first ionization energy?

    <p>Phosphorus (P)</p> Signup and view all the answers

    Which of the following statements about ionization energies is true?

    <p>Ionization energy increases with the removal of each successive electron.</p> Signup and view all the answers

    What trend is observed in the successive ionization energies of magnesium based on the provided values?

    <p>There are large jumps in energy required for successive ionizations.</p> Signup and view all the answers

    What does the Bohr model suggest about the movement of electrons?

    <p>Electrons are found in fixed orbits with defined energy levels.</p> Signup and view all the answers

    What is a key feature of the energy levels in the Bohr model?

    <p>Energy levels have associated quantum numbers.</p> Signup and view all the answers

    What happens when an electron transitions to a higher energy level?

    <p>A photon is absorbed.</p> Signup and view all the answers

    What is the result of an electron moving to a lower energy level?

    <p>A photon is emitted.</p> Signup and view all the answers

    Which of the following does the Bohr model NOT successfully explain?

    <p>Energy transitions in multi-electron atoms.</p> Signup and view all the answers

    How are the energies of photons related to electron transitions?

    <p>Equal to the difference in energy between two energy levels.</p> Signup and view all the answers

    What misconception about energy levels does the Bohr model address?

    <p>Energy levels are the same as physical orbits.</p> Signup and view all the answers

    Which of the following describes the concept of quantum numbers in relation to Bohr's model?

    <p>Quantum numbers are used to define allowed energy levels.</p> Signup and view all the answers

    What evidence supports the wave nature of electrons?

    <p>Interference pattern of electrons passing through Al foil</p> Signup and view all the answers

    What fundamental principle states that we cannot know both the position and energy of an electron accurately?

    <p>Heisenberg Uncertainty Principle</p> Signup and view all the answers

    How does the quantum model of the atom differ from the Bohr model regarding electrons?

    <p>Electrons are treated as waves in the quantum model</p> Signup and view all the answers

    During the double slit experiment, what do electrons display that indicates their wave properties?

    <p>Interference patterns</p> Signup and view all the answers

    What must be true about the energy of electrons in an atom according to modern quantum theory?

    <p>Electrons can only have certain quantized energies</p> Signup and view all the answers

    What does the revival of Schrödinger's work represent in terms of electron behavior in atoms?

    <p>Incorporating wave mechanics into atomic theory</p> Signup and view all the answers

    Which of the following statements about the Bohr model is true?

    <p>It is based on classical physics with circular orbits.</p> Signup and view all the answers

    In relation to atomic structure, how are the positions of electrons described in quantum mechanics?

    <p>Electrons exist in probabilistic clouds of locations.</p> Signup and view all the answers

    Study Notes

    Electrons and Orbitals

    • Understanding the atomic structure requires knowledge of where electrons are located and their influence on element properties.
    • Electrons in helium interact through London Dispersion Forces (LDFs), while hydrogen forms covalent bonds.

    Electromagnetic Radiation

    • Electromagnetic radiation refers to waves of electric and magnetic fields, seen in various forms such as radio waves and X-rays.
    • Key characteristics include wavelength (λ) in meters and frequency (ν) in Hertz (Hz).
    • The speed of light (c) is a constant at 3.00 × 10^8 m/s, governing the relationship λ × ν = c.
    • Energy of light increases with frequency and decreases with increasing wavelength, unaffected by amplitude.

    Bohr Model of the Atom

    • Developed by Niels Bohr, suggesting electrons move in fixed orbits around the nucleus, each with a specific energy level.
    • Electrons transition between energy levels by absorbing or emitting photons; energy of photons corresponds to the energy difference between levels.

    Limitations of the Bohr Model

    • Works only for hydrogen and does not account for other elements, necessitating a move to a more complex model.
    • Electrons are not in defined orbits, as illustrated by the Heisenberg Uncertainty Principle, which states simultaneous measurement of energy and position isn't possible.

    Quantum Mechanics and Orbitals

    • Erwin Schrödinger’s application of quantum mechanics describes electrons as wave-like entities.
    • Atomic orbitals represent regions around the nucleus where electrons are likely to be found, with each orbital having a specific energy level.
    • Orbitals are not literal orbits but energy levels; quantized energy levels determine electron behavior.

    Electron Configuration

    • Understanding valence and core electrons is crucial; core electrons comprise closed shells that are stable and unreactive, while valence electrons influence chemical reactivity.
    • Electron configurations detail the distribution of electrons across orbitals, with notation indicating the last noble gas and any remaining electrons.

    Ionization Energies

    • Ionization energy (IE) is influenced by effective nuclear charge, atomic size, and the shell from which an electron is removed.
    • Observing trends in ionization energy provides insights into element reactivity and stability, with notable jumps indicating the removal of core electrons.

    Practical Applications

    • Students should be able to write electron configurations for various elements, understand the concept of core versus valence electrons, and explain ionization processes and trends among elements.
    • Encouraged to engage during lectures for insights beyond these notes, including questions regarding complex topics like Schrödinger's cat.

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    This quiz covers the essential内容 from Chapter 2 of CEM 141. It emphasizes the importance of taking detailed notes during lectures, including answers to questions and additional explanations. Use these concise notes as a foundation for further study and seek clarification during office hours.

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