Carbon and Its Allotropes

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Questions and Answers

What is the chemical formula for the compound used as baking soda?

  • Naâ‚‚CO₃
  • COâ‚‚
  • CaCO₃
  • NaHCO₃ (correct)

What is the chemical formula for the compound used in limewater?

  • CaCO₃ (correct)
  • COâ‚‚
  • NaHCO₃
  • Naâ‚‚CO₃

What is the chemical reaction that takes place when carbon dioxide is passed through an aqueous solution of sodium hydroxide?

  • 2NaOH + COâ‚‚ → Naâ‚‚CO₃ + Hâ‚‚O (correct)
  • Naâ‚‚CO₃ + Hâ‚‚O + COâ‚‚ → 2NaHCO₃
  • CaCO₃ + 2HCl → CaClâ‚‚ + Hâ‚‚O + COâ‚‚
  • 2NaHCO₃ → Naâ‚‚CO₃ + COâ‚‚ + Hâ‚‚O

Based on its interaction with limewater, which chemical property of carbon dioxide is being observed?

<p>Reactivity (C)</p> Signup and view all the answers

Which of the following is NOT a use of carbon dioxide?

<p>Used to make explosives (B)</p> Signup and view all the answers

What is the chemical reaction that occurs when carbon dioxide is passed through an aqueous solution of sodium carbonate?

<p>Na₂CO₃ + H₂O + CO₂ → 2NaHCO₃ (B)</p> Signup and view all the answers

The observation that carbon dioxide turns blue litmus paper red indicates what property of carbon dioxide?

<p>Acidity (B)</p> Signup and view all the answers

What is the chemical formula for the gas that is produced when dilute hydrochloric acid reacts with calcium carbonate?

<p>COâ‚‚ (C)</p> Signup and view all the answers

What method is used to collect the carbon dioxide gas in the experiment described?

<p>Upward displacement of air (B)</p> Signup and view all the answers

What property of carbon dioxide makes it suitable for being used in fire extinguishers?

<p>Acidity (B)</p> Signup and view all the answers

What is the main reason why coke is used as a reducing agent?

<p>Coke can react with metal oxides to remove oxygen and form carbon dioxide. (A)</p> Signup and view all the answers

What is the primary difference between saturated and unsaturated hydrocarbons?

<p>Saturated hydrocarbons contain only single bonds between carbon atoms, while unsaturated hydrocarbons have at least one double or triple bond. (A)</p> Signup and view all the answers

Which of the following is a saturated hydrocarbon?

<p>Ethane (CH₃—CH₃) (A), Propane (CH₃—CH₂—CH₃) (B)</p> Signup and view all the answers

Based on its electronic configuration, what is the maximum number of covalent bonds a carbon atom can form?

<p>4 (A)</p> Signup and view all the answers

What is the name of the compound formed by sharing one electron each with four hydrogen atoms by a carbon atom?

<p>Methane (CHâ‚„) (B)</p> Signup and view all the answers

Charcoal, a form of carbon produced from plants, has a significant application in which of the following?

<p>Purification of water and organic material. (C)</p> Signup and view all the answers

What is the primary reason for the strong and stable nature of a single bond between two carbon atoms?

<p>The equal sharing of electrons between the two carbon atoms. (B)</p> Signup and view all the answers

Which of the following is NOT an application of coke?

<p>Production of synthetic diamonds. (E)</p> Signup and view all the answers

What type of bond is formed when a carbon atom shares an electron with a hydrogen atom?

<p>Covalent bond (A)</p> Signup and view all the answers

What chemical reaction occurs when sodium bicarbonate and sulphuric acid are mixed in a fire extinguisher?

<p>2NaHCO3 + H₂SO₄ → Na₂SO₄ + 2 H2O + 2 CO₂↑ (C)</p> Signup and view all the answers

Why are COâ‚‚ fire extinguishers preferred for electrical fires?

<p>They do not cause corrosion and are non-conductors of electricity. (B)</p> Signup and view all the answers

Which statement is true regarding the properties of methane?

<p>Methane has a boiling point of -161.5 °C. (B)</p> Signup and view all the answers

What is produced when methane reacts with chlorine in the presence of ultraviolet light?

<p>Methyl chloride and hydrogen chloride (B)</p> Signup and view all the answers

Which of the following best describes the condition under which methane is formed from a mixture of hydrogen and carbon monoxide?

<p>At 300 °C in the presence of a nickel catalyst (D)</p> Signup and view all the answers

What is the name of the carbon allotrope that is shaped like a soccer ball?

<p>Fullerene (B)</p> Signup and view all the answers

Which type of coal has the highest carbon content?

<p>Anthracite (C)</p> Signup and view all the answers

What is the name of the carbon allotrope that is shaped like a tube?

<p>Buckytube (B)</p> Signup and view all the answers

Which of these are NOT properties of fullerene?

<p>They have a very high melting point. (C)</p> Signup and view all the answers

Which of the following are NOT an example of fullerene?

<p>C90 (B)</p> Signup and view all the answers

What is the first step in the formation of coal?

<p>Formation of Peat (C)</p> Signup and view all the answers

What is the name of the carbon allotrope used as a catalyst in water purification?

<p>Fullerene (C)</p> Signup and view all the answers

Which of the following statements correctly describes the arrangement of carbon atoms in graphite?

<p>Carbon atoms are arranged in layers that can slide over each other. (A)</p> Signup and view all the answers

What is the MAIN difference between graphite and fullerene?

<p>Their structural arrangement. (B)</p> Signup and view all the answers

What is the main element present in substances derived from plants and animals?

<p>Carbon (A)</p> Signup and view all the answers

Which of the following is NOT considered an organic compound?

<p>Water (A)</p> Signup and view all the answers

What is the Latin word from which the name 'carbon' is derived?

<p>Carbo (B)</p> Signup and view all the answers

Which of the following is an example of a free state of carbon?

<p>Diamond (A)</p> Signup and view all the answers

What does the black substance remaining in test tubes after heating substances like sugar, wool, and dry leaves indicate?

<p>The presence of carbon (C)</p> Signup and view all the answers

What is the chemical equation for the synthesis of urea from ammonium cyanate?

<p>$NH_4^+CNO \xrightarrow{Heat} NH_2CONH_2$ (A)</p> Signup and view all the answers

What is the primary reason why organic chemistry is also referred to as the chemistry of carbon compounds?

<p>Carbon forms strong bonds with itself and other elements, leading to a vast diversity of compounds. (D)</p> Signup and view all the answers

Flashcards

Element

A basic substance that cannot be broken down into simpler substances.

Carbon

A non-metallic element essential in organic compounds, present in free and combined forms.

Organic Compounds

Compounds that contain carbon, derived from living organisms.

Inorganic Compounds

Compounds not derived from living organisms, typically do not contain carbon.

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Allotropes of Carbon

Different structural forms of carbon that have distinct properties, like graphite and diamond.

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Synthesis of Urea

The process of creating an organic compound from inorganic materials, pioneered by Wohler with ammonium cyanate.

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Complete Combustion

Burning of a substance in oxygen producing carbon dioxide and water, leaving ash or residues.

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Uses of Coal

Coal is used as fuel, for coke production, and in electricity generation.

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Charcoal Formation

Charcoal is formed by burning wood with limited air supply.

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Coke

Coke is pure coal remaining after coal gas is extracted.

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Uses of Coke

Coke is used as fuel and reducing agent, also in gas production.

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Hydrocarbons

Compounds consisting solely of carbon and hydrogen.

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Valency of Carbon

Carbon has a valency of 4, forming four covalent bonds.

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Saturated Hydrocarbons

Hydrocarbons with only single bonds between carbon atoms.

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Unsaturated Hydrocarbons

Hydrocarbons containing at least one multiple bond between carbon atoms.

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Covalent Bonds

A covalent bond is formed by sharing electrons between atoms.

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Structural Formula of Methane

Methane's structural formula is CHâ‚„, showing four covalent C-H bonds.

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COâ‚‚ Fire Extinguishers

Fire extinguishers using carbon dioxide to put out fires, especially on electrical equipment.

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Chemical Reaction in Extinguishers

The reaction between sulphuric acid and sodium bicarbonate releasing carbon dioxide during fire extinguishing.

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Methane Properties

A colorless, highly flammable gas with a melting point of -182.5 °C and boiling point of -161.5 °C.

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Methane Combustion Reaction

The reaction of methane with oxygen producing carbon dioxide, water, and heat, releasing 213 kcal/mol.

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Chlorination of Methane

The reaction of methane with chlorine to produce methyl chloride and hydrogen chloride, occurs with UV light.

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Chemical reaction of CaCO₃ and HCl

The reaction produces CaClâ‚‚, Hâ‚‚O, and COâ‚‚.

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Properties of COâ‚‚

COâ‚‚ is colorless, odorless, and denser than air.

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Testing COâ‚‚ with Limewater

COâ‚‚ turns limewater milky due to calcium carbonate formation.

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Effect of COâ‚‚ on a burning candle

A burning candle is extinguished in COâ‚‚ due to lack of oxygen.

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Universal Indicator in COâ‚‚

COâ‚‚ turns universal indicator solution red, indicating acidity.

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Sodium Carbonate Formation

Na₂CO₃ is formed by reacting NaOH with CO₂.

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Sodium Bicarbonate Formation

NaHCO₃ (baking soda) is made from CO₂ and Na₂CO₃.

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Uses of COâ‚‚

Used in fizzy drinks, fire extinguishers, and preserving food.

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Fire Extinguisher Composition

Contains sodium bicarbonate and dilute sulfuric acid.

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Role of COâ‚‚ in Photosynthesis

Plants need COâ‚‚ for photosynthesis to produce glucose and oxygen.

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Graphite

A crystal made of many layers of carbon atoms that slip over each other.

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Graphene

A single layer of carbon atoms in graphite.

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Fullerene

An allotrope of carbon, rarely found in nature with structures like C60.

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Buckminsterfullerene (C60)

The first fullerene discovered, named for its dome-like shape.

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Buckytube (Carbon nanotube)

A cylindrical fullerene molecule formed from carbon atoms.

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Buckyball

A spherical fullerene molecule, resembling a soccer ball.

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Anthracite

The purest form of coal containing about 95% carbon.

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Charcoal

A non-crystalline carbon made from carbonizing organic materials.

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Study Notes

Carbon: An Important Element

  • Carbon is a non-metallic element found abundantly in nature, both free and in compounds.
  • Carbon's symbol is C, atomic number is 6, atomic mass is 12, electron configuration is 2,4, and valency is 4.
  • Carbon is a key component of organic compounds, from foodstuffs to fuels.
  • Organic compounds derived from plants and animals.
  • Inorganic compounds come from minerals.
  • Carbon is present in DNA and RNA.

Allotropes of Carbon

  • Carbon exists in different forms called allotropes, with different physical properties despite the same chemical properties.
  • Crystalline allotropes include diamond and graphite.
  • Diamond is the hardest naturally occurring substance, has high melting and boiling points with a density of 3.5 g/cm³.
  • Graphite is soft, slippery, and a conductor of electricity. Graphite has a layered structure with free electrons in each layer. Its density ranges from 1.9 to 2.3 g/cm³.

Fullerene: Another Allotrope

  • Fullerene is a carbon allotrope.
  • Buckminsterfullerene (C60) is a spherical fullerene molecule.
  • Fullerene molecules occur in small numbers in soot.
  • Fullerene is used as an insulator and a catalyst in water purification.

Coal and Coke

  • Coal, a fossil fuel, is a non-crystalline form of carbon.
  • Coal types include peat, lignite, bituminous coal, and anthracite, in increasing order of carbon content. Anthracite is the purest form.
  • Coke is a form of carbon remaining after removing coal gas.
  • Coke is used as fuel in factories and homes and as a reducing agent.

Hydrocarbons (Basic Organic Compounds)

  • Hydrocarbons contain only carbon and hydrogen atoms.
  • Methane (CH4) is a common hydrocarbon.
  • Methane is a colorless gas that is highly flammable and occurs in natural gas. Its melting point is -182.5°C and its boiling point is -161.5°C. Its density is less than that of water.
  • Methane is important in various industrial applications as a fuel.

Carbon Dioxide (CO2)

  • Carbon dioxide is a colorless, odorless gas.
  • CO2 occurs naturally in the atmosphere.
  • CO2 is released during combustion.
  • It is soluble in water.
  • It is used in various applications, including fire extinguishers, aerated drinks and cold storage.

Biogas Production

  • Biogas plants use anaerobic microbes to produce biogas from organic waste.
  • Biogas is a methane-rich fuel.

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