Carbohydrates Chemistry & Metabolism

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Questions and Answers

What is true about monosaccharides?

  • They can be broken down into simpler sugars.
  • They are always composed of six carbon atoms.
  • They contain more than one sugar unit.
  • They cannot be hydrolyzed into simpler compounds. (correct)

Which of the following is classified as a disaccharide?

  • Glucose
  • Galactose
  • Sucrose (correct)
  • Starch

What characterizes an aldopentose?

  • It has five carbon atoms and an aldehyde group. (correct)
  • It has five carbon atoms and a ketone group.
  • It is a simple sugar with no functional groups.
  • It contains less than three carbon atoms.

What leads to lactose intolerance?

<p>Lactase deficiency. (D)</p> Signup and view all the answers

How does sucrose contribute to dental caries?

<p>By reacting with bacteria to produce acid. (C)</p> Signup and view all the answers

Which statement correctly describes the composition of starch?

<p>It is a polymer of glucose molecules. (C)</p> Signup and view all the answers

What occurs when human teeth are rinsed with a sucrose solution?

<p>The enamel suffers from demineralization. (B)</p> Signup and view all the answers

Which of the following best describes an oligosaccharide?

<p>Contains three to ten sugar units. (C)</p> Signup and view all the answers

Flashcards

Carbohydrates

Organic compounds containing carbon, hydrogen, and oxygen, often in a 1:2:1 ratio (e.g., Cn(H2O)n).

Monosaccharides

Simple sugars; cannot be hydrolyzed into simpler sugars.

Disaccharides

Two monosaccharides linked together by a glycosidic bond.

Polysaccharides

Long chains of monosaccharides linked together.

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Glycosidic bond

A bond that links monosaccharides together to form disaccharides and polysaccharides.

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Starch

A polysaccharide that serves as a storage form of energy in plants.

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Dental Caries

Tooth decay caused by acid production from bacteria on teeth, especially when consuming sugars like sucrose.

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Lactose Intolerance

Inability to digest lactose (milk sugar) due to insufficient lactase enzyme.

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Study Notes

Carbohydrates Chemistry & Metabolism

  • Carbohydrates are compounds derived from glycogen and glucose, such as starch and sucrose.
  • They are hydrated carbons (contain hydrogen and oxygen in the same proportion as Hâ‚‚O).
  • The formula of carbohydrates is Cn(Hâ‚‚O)n, where n = 3 or more.

Classification of Carbohydrates

  • Monosaccharides: Single sugar units that cannot be hydrolyzed into simpler compounds.
  • Disaccharides: Two sugar units linked together.
  • Oligosaccharides: 3-10 sugar units.
  • Polysaccharides: Polymers of more than 10 sugar units.

Classification of Monosaccharides

  • Classified by the number of carbon atoms (trioses, tetroses, pentoses, hexoses).
  • Classified by the active sugar group (aldoses or ketoses).
  • Further classified by both the active group and the number of carbon atoms (e.g., aldopentose, Aldohexose, ketohexose).

Disaccharides Examples

  • Maltose (Malt sugar): Glucose + Glucose
  • Lactose (Milk sugar): Galactose + Glucose
  • Sucrose (Cane sugar): Glucose + Fructose

Lactose Intolerance

  • Cause: Deficiency of lactase. This can be congenital (due to gene defect) or acquired (after surgery, infection). Aging can also lead to a reduction in lactase production.
  • Symptoms: Fermentation by intestinal bacteria causes gas production, distension, nausea, colic, and diarrhea.
  • Management: Intake of lactose-free milk and yogurt (lactose in yogurt is partially hydrolyzed during fermentation).

Sucrose and Dental Caries

  • Rinsing human teeth with sucrose solution for 3 minutes will lower plaque pH from 6.5 to 5.0, which remains low for 40 minutes.
  • The acid produced damages the enamel (causing demineralization).

Simple Polysaccharides

  • Starch: Plant storage carbohydrate. It has two types of chains:
    • Amylose: Straight chains of α-D glucose linked by α 1-4 glycosidic bonds.
    • Amylopectin: Branched chains of α-D glucose linked by α 1-4 and α 1-6 glycosidic bonds.
  • Glycogen: Animal storage carbohydrate, highly branched chains of α-D glucose linked by α 1-4 and α 1-6 glycosidic bonds.

Cellular Types of Carbohydrates (Summary Table)

Carbohydrate Source Subunit Bonds Branches
Cellulose Plant β-glucose 1-4 No
Starch (Amylose) Plant α-glucose 1-4 No
Starch (Amylopectin) Plant α-glucose 1-4, 1-6 Yes
Glycogen Animal α-glucose 1-4, 1-6 Yes

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