Carbohydrates and Monosaccharides Quiz

Choose a study mode

Play Quiz
Study Flashcards
Spaced Repetition
Chat to Lesson

Podcast

Play an AI-generated podcast conversation about this lesson

Questions and Answers

What is the primary function of carbohydrates in living organisms?

  • Act as a source of energy (correct)
  • Form hormonal signals
  • Provide genetic information
  • Serve as cellular receptors

What distinguishes aldoses from ketoses?

  • The position of the hydroxyl group
  • The number of carbon atoms
  • The type of carbonyl group present (correct)
  • The ability to form polysaccharides

Which of the following is a structural characteristic of monosaccharides?

  • They are always found in linear form
  • They are larger than polysaccharides
  • They have a general formula of Cn(Hâ‚‚O)n (correct)
  • They contain one asymmetric carbon only

Which type of carbohydrate is formed by the linkage of two monosaccharides?

<p>Disaccharide (C)</p> Signup and view all the answers

What term describes carbohydrates that differ in configuration around only one asymmetric carbon?

<p>Epimers (C)</p> Signup and view all the answers

What type of ring structures can fructose form during cyclization?

<p>Both 5-membered and 6-membered rings (A)</p> Signup and view all the answers

In the D and L nomenclature system, which carbon is referenced to determine the configuration?

<p>The asymmetric carbon farthest from the carbonyl group (A)</p> Signup and view all the answers

Which of the following carbohydrates serves as a structural component in cell walls?

<p>Cellulose (A)</p> Signup and view all the answers

What is the result of oxidizing aldoses with Tollen's reagent?

<p>Production of a silver mirror (C)</p> Signup and view all the answers

Which reaction is responsible for converting an aldose to an alditol?

<p>Reduction with sodium borohydride (B)</p> Signup and view all the answers

What type of acid is formed when aldoses are oxidized to the carbonyl group?

<p>Aldonic acid (C)</p> Signup and view all the answers

The formation of an osazone is primarily associated with which functional group?

<p>Aldehyde group (A)</p> Signup and view all the answers

What type of configuration do pyranose sugars usually assume?

<p>Chair or boat configuration (C)</p> Signup and view all the answers

Which of the following correctly describes exhaustive methylation in carbohydrate chemistry?

<p>Only affects anomeric carbons (C)</p> Signup and view all the answers

Which statement correctly describes an anomer of glucose?

<p>α-anomer has the OH group below the ring, β-anomer above. (B)</p> Signup and view all the answers

What is the characteristic product resulting from glycoside formation?

<p>Acetal (D)</p> Signup and view all the answers

What reaction forms an intramolecular hemiacetal in glucose?

<p>The reaction of the C1 aldehyde with C5 OH (B)</p> Signup and view all the answers

What is the role of HNO3 in carbohydrate oxidation?

<p>To create aldaric acids (D)</p> Signup and view all the answers

Which of the following tests indicates the presence of reducing sugars?

<p>Benedict’s Test (C)</p> Signup and view all the answers

What defines a sugar alcohol?

<p>It lacks an aldehyde or ketone. (C)</p> Signup and view all the answers

What happens to the aldehyde group in sugar acids?

<p>It is oxidized to a carboxylic acid. (D)</p> Signup and view all the answers

How does N-acetylneuraminic acid affect glycoproteins?

<p>It imparts a negative charge due to its carboxyl group. (D)</p> Signup and view all the answers

What is formed when an amino group substitutes for a hydroxyl group in sugars?

<p>Amino sugar (D)</p> Signup and view all the answers

What is the primary function of sugar phosphates in biochemistry?

<p>They participate in various metabolic pathways. (C)</p> Signup and view all the answers

What is the length of GAG chains in proteoglycans?

<p>About 80 sugars long (C)</p> Signup and view all the answers

How do GAG gels function within the extracellular matrix?

<p>They regulate movement based on size and charge (D)</p> Signup and view all the answers

Which of the following describes the immune response to foreign blood group antigens?

<p>It recognizes the antigens as foreign and mounts an immune response (B)</p> Signup and view all the answers

What is the major component of cartilage mentioned in the content?

<p>Aggrecan (C)</p> Signup and view all the answers

What type of protein does decorin associate with in the extracellular matrix?

<p>Fibrous matrix proteins (A)</p> Signup and view all the answers

What is the primary function of peptidoglycan in bacterial cells?

<p>To provide mechanical support and prevent bursting (D)</p> Signup and view all the answers

What distinguishes glycoproteins from proteoglycans?

<p>The amount of carbohydrate content (A)</p> Signup and view all the answers

Which statement is true regarding glycosaminoglycans (GAGs)?

<p>They have disaccharide repeating units with charged groups (A)</p> Signup and view all the answers

Which of the following is a significant role of proteoglycans in animal cells?

<p>Cellular signaling and structural support (B)</p> Signup and view all the answers

What percentage of carbohydrates by weight can proteoglycans contain?

<p>As much as 95% (C)</p> Signup and view all the answers

What is a common structural characteristic of glycoproteins?

<p>Have oligosaccharide chains attached to polypeptide side-chains (C)</p> Signup and view all the answers

Which sugar derivatives are commonly found in the repeating units of glycosaminoglycans?

<p>Glucosamine or galactosamine (C)</p> Signup and view all the answers

What effect does penicillin have on bacterial cell walls?

<p>Inhibits cross-linking of peptidoglycan (D)</p> Signup and view all the answers

What type of linkage is found in sucrose?

<p>α(1→2) linkage (C)</p> Signup and view all the answers

Which term describes the type of bond linking two monosaccharides in a disaccharide?

<p>Glycosidic bond (C)</p> Signup and view all the answers

What is the full name of lactose?

<p>β-D-galactopyranosyl-(1→4)-α-D-glucose (D)</p> Signup and view all the answers

Which structural component contributes to the negative charge of sugar sulfates at physiological pH?

<p>Sulfate groups (A)</p> Signup and view all the answers

What does a ketal of fructose form?

<p>Fructoside (B)</p> Signup and view all the answers

Which type of saccharides provide structural integrity to organisms?

<p>Polysaccharides (C)</p> Signup and view all the answers

What distinguishes a homopolysaccharide from a heteropolysaccharide?

<p>Type of monosaccharides used (B)</p> Signup and view all the answers

Which disaccharide is derived from starch and linked by an α(1→4) glycosidic bond?

<p>Maltose (C)</p> Signup and view all the answers

Flashcards

Pentoses and hexoses cyclize

Pentoses and hexoses form cyclic structures by reacting the ketone or aldehyde group with a distal hydroxyl.

Anomers

Isomers of a cyclic sugar that differ only in the position of the hydroxyl group at the anomeric carbon.

Haworth projections

Representations that depict cyclic sugars as nearly planar rings.

Intramolecular hemiacetal

A reaction of the C1 aldehyde & C5 OH that creates a 6-membered pyranose ring.

Signup and view all the flashcards

Pyranose ring

The six-membered cyclic structure formed by the intramolecular hemiacetal reaction.

Signup and view all the flashcards

Sugar alcohols

Sugar derivatives where the carbonyl group is reduced to an alcohol group.

Signup and view all the flashcards

Sugar acids

Sugar derivatives where the aldehyde or ketone is oxidized to a carboxylic acid.

Signup and view all the flashcards

Deoxysugars

Sugar derivatives where a hydroxyl group is replaced by an hydrogen atom.

Signup and view all the flashcards

Carbohydrates

Compounds made up of carbon, hydrogen, and oxygen, often with the formula Cn(Hâ‚‚O)n, and serve as energy sources and structural components.

Signup and view all the flashcards

Monosaccharides

Simple sugars, the simplest form of carbohydrates.

Signup and view all the flashcards

Aldoses

Monosaccharides with an aldehyde group.

Signup and view all the flashcards

Ketoses

Monosaccharides with a keto group.

Signup and view all the flashcards

Cyclization

The process where monosaccharides form ring structures (pyranose or furanose) from linear structures.

Signup and view all the flashcards

D and L stereoisomers

Different spatial arrangements of atoms around a chiral carbon in a sugar. D and L configurations are used to describe the spatial arrangements in more complex sugar molecules.

Signup and view all the flashcards

Hemiacetal/Hemiketal Formation

Reactants that lead a cyclic structure when in a sugar form.

Signup and view all the flashcards

Mutarotation

The interconversion of α and β anomers of a sugar in solution.

Signup and view all the flashcards

Oxidation of Sugars

Chemical reactions that add oxygen to the sugars

Signup and view all the flashcards

Aldonic Acid

A sugar acid formed by oxidation of the aldehyde group of an aldose.

Signup and view all the flashcards

Reducing Sugars

Sugars that react with Tollen's or Benedict's reagents.

Signup and view all the flashcards

Reduction of Aldoses

Converting aldoses into alditols using sodium borohydride.

Signup and view all the flashcards

Osazone Formation

Formation of osazones by reaction of an aldose aldehyde group with reagents like hydroxylamine and phenylhydrazine.

Signup and view all the flashcards

Glycoside Formation

Formation of glycosides (acetals) by reaction of the anomeric carbon.

Signup and view all the flashcards

Esterification of Sugars

Reaction of sugar hydroxyl groups with acids, acid derivatives, or phosphates.

Signup and view all the flashcards

Glycosidic bond

A covalent bond that links two monosaccharides together, forming a disaccharide or polysaccharide.

Signup and view all the flashcards

Disaccharides

Carbohydrates formed by the linkage of two monosaccharides via a glycosidic bond.

Signup and view all the flashcards

Maltose: Structure

A disaccharide formed by the α(1→4) glycosidic linkage of two glucose molecules.

Signup and view all the flashcards

Sucrose: Structure

A disaccharide formed by the α(1→2) glycosidic linkage of glucose and fructose.

Signup and view all the flashcards

Lactose: Structure

A disaccharide formed by the β(1→4) glycosidic linkage of galactose and glucose.

Signup and view all the flashcards

Homopolysaccharides

Polysaccharides composed of only one type of monosaccharide.

Signup and view all the flashcards

Heteropolysaccharides

Polysaccharides composed of two or more different types of monosaccharides.

Signup and view all the flashcards

What is a proteoglycan?

A large molecule composed of a core protein with one or more glycosaminoglycans attached.

Signup and view all the flashcards

What are glycosaminoglycans (GAGs)?

Long, unbranched polysaccharide chains composed of repeating disaccharide units that are negatively charged.

Signup and view all the flashcards

What is the role of proteoglycans in the extracellular matrix (ECM)?

They form gels that act as selective sieves, regulating the movement of molecules and cells based on size and charge.

Signup and view all the flashcards

How do proteoglycans contribute to ECM structural integrity?

They associate with fibrous matrix proteins like collagen, providing structural support.

Signup and view all the flashcards

Blood Group Antigens

Carbohydrates attached to glycoproteins and glycolipids on red blood cells that act as antigenic determinants.

Signup and view all the flashcards

Peptidoglycan

A major component of bacterial cell walls, composed of linear polysaccharide chains cross-linked by short peptides. It gives structural rigidity to bacterial cells and prevents them from bursting due to high internal osmotic pressure.

Signup and view all the flashcards

What does penicillin inhibit?

Penicillin inhibits the cross-linking enzyme transpeptidase, which is responsible for forming the peptide bonds in peptidoglycan.

Signup and view all the flashcards

Glycosaminoglycans (GAGs)

Linear polysaccharide chains with repeating disaccharide units containing an amino sugar (glucosamine or galactosamine) modified with a negatively charged carboxylate or sulfate group. They form proteoglycans by attaching to proteins.

Signup and view all the flashcards

Proteoglycans

Large macromolecules composed of glycosaminoglycans (GAGs) covalently attached to proteins. Found primarily in animal cells.

Signup and view all the flashcards

Glycoproteins

Proteins that contain oligosaccharide chains covalently attached to their polypeptide side chains. Distinguished from other glycoproteins by the nature, quantity, and arrangement of their sugar side chains.

Signup and view all the flashcards

N-linkage

A type of glycosidic bond that connects the sugar to the nitrogen (N) atom of the asparagine side chain in a glycoprotein.

Signup and view all the flashcards

O-linkage

A type of glycosidic bond that connects the sugar to the oxygen (O) atom of the serine or threonine side chain in a glycoprotein.

Signup and view all the flashcards

Distinguishing feature of proteoglycans

Proteoglycans are distinguished from other glycoproteins by the nature, quantity, and arrangement of their sugar side chains. They contain a large amount of carbohydrates (up to 95% by weight) compared to other glycoproteins.

Signup and view all the flashcards

Study Notes

Carbohydrates

  • Carbohydrates are compounds containing carbon, hydrogen, and oxygen
  • They are crucial for energy storage, metabolic processes, and structural components in living organisms.
  • Common formula: Cn(H2O)n
  • Different classifications of carbohydrates include simple, oligosaccharide and complex, polysaccharides

Monosaccharides

  • Simplest form of carbohydrates
  • Aldoses have an aldehyde group, and ketoses have a ketone group
  • Classified by the number of carbon atoms (trioses, tetroses, pentoses, hexoses, heptoses)
  • Examples include glucose, fructose, galactose

Stereoisomers

  • D and L isomers are determined based on the configuration around the asymmetric carbon farthest from the aldehyde/ketone group in glyceraldehyde.
  • Epimers differ in configuration around only one chiral center.

Nomenclature of Monosaccharides

  • Based on the number of carbon atoms and the functional group (aldehyde or ketone)
  • Examples of monosaccharide names include glyceraldehyde, erythrose, ribose, glucose, fructose, mannose.

Cyclization of Sugars

  • Monosaccharides can form cyclic structures (hemiacetals or hemiketals) through intramolecular reactions.
  • This cyclization creates anomeric carbons (new chiral center) resulting in α and β anomers that differ in the position of the hydroxyl group at the anomeric carbon.
  • Haworth projections are used to visualize the cyclic forms.

Sugar Derivatives

  • Sugar alcohols are formed by reduction of the carbonyl group
  • Sugar acids are formed by oxidation of the aldehyde or ketone group.
  • Deoxy sugars have a hydroxyl group replaced by a hydrogen.

Reactions of Monosaccharides

  • Mutarotation, a change in the specific rotation of a sugar solution is the interconversion of the cyclic forms (α to β and vice versa)
  • Oxidation by chemicals (e.g., bromine water) or strong oxidizing agents such as nitric acid can further breakdown the carbon backbone, forming sugar acids
  • Osazone formation is a reaction that can differentiate between different ketoses.

Disaccharides

  • Composed of two monosaccharide units joined by a glycosidic bond.
  • Formation of glycosidic bonds involves the loss of a water molecule.
  • Examples include sucrose, maltose, lactose, cellobiose

Polysaccharides

  • Long chains of monosaccharides linked by glycosidic bonds
  • Can be branched or unbranched
  • Examples include starch, glycogen, cellulose, and chitin.

Other Carbohydrates

  • Peptidoglycan, a polymer that forms bacterial cell walls.
  • Glycoproteins and proteoglycans are proteins with covalently attached carbohydrate chains.
  • Glycosaminoglycans are long unbranched polysaccharides containing repeating disaccharide units.
  • Blood group antigens, which are oligosaccharides that are important in blood transfusions.

Studying That Suits You

Use AI to generate personalized quizzes and flashcards to suit your learning preferences.

Quiz Team

Related Documents

More Like This

Carbohydrate Classification and Structure
40 questions
Carbohydrate Classification and Monosaccharides
10 questions
Carbohydrates and Their Classification Quiz
10 questions
Use Quizgecko on...
Browser
Browser