Bronsted Acids and Bases Quiz

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Questions and Answers

What are the conjugate bases for the Bronsted acids H2O and HF?

  • OH– and H2F+, respectively
  • H3O+ and F–, respectively
  • H3O+ and H2F+, respectively
  • OH– and F–, respectively (correct)

What is the conjugated acid of the O–2 ion?

  • O2+ (correct)
  • H3O+
  • H+
  • OH–

In the reaction NH3 + H2O → NH4+ + OH–, what role does water play?

  • Base
  • Both acid and base (correct)
  • Neutral
  • Acid

Which of the following can act both as a Bronsted acid and a Bronsted base?

<p>HSO4– (B)</p> Signup and view all the answers

In the equilibrium NH3 + H2O ⇌ NH4+ + OH–, identify X and Y in terms of conjugate acid and base.

<p>Base and acid (A)</p> Signup and view all the answers

Which of the following is least likely to behave as a Lewis base?

<p>BF3 (C)</p> Signup and view all the answers

Which compound is considered the weakest acid?

<p>HF (A)</p> Signup and view all the answers

For which substance is the dilution law applicable?

<p>CH3COOH (C)</p> Signup and view all the answers

If [OH–] = 5.0 × 10–5 M, what is the pH of the solution?

<p>9 + log 5 (A)</p> Signup and view all the answers

What is the pOH of a 0.002 M HNO3 solution?

<p>11 – log 2 (C)</p> Signup and view all the answers

What is the calculated pH of a 0.01 M NaOH solution?

<p>12 (C)</p> Signup and view all the answers

Given a hydroxide ion concentration of 8 × 10–11 M, what is the pH of the solution?

<p>4.9 (B)</p> Signup and view all the answers

From a pH of 3.31, what is the approximate concentration of [H+]?

<p>3.39 × 10–4 (D)</p> Signup and view all the answers

What is the [H3O+] concentration in a beer with a pH of 4.30?

<p>3.0 × 10–4 (B)</p> Signup and view all the answers

What is the pH of a solution if 2g of NaOH is dissolved to make 1 L?

<p>12.70 (B)</p> Signup and view all the answers

For a 100 ml solution of 10–2 M NaOH, what is the ratio of pH to pOH?

<p>2:1 (C)</p> Signup and view all the answers

What is the H+ ion concentration of a 5 × 10-3 M H2CO3 solution with 10% dissociation?

<p>5 × 10–2 (D)</p> Signup and view all the answers

If the pH of a 0.1 M weak acid is 3, what is its degree of dissociation?

<p>10% (C)</p> Signup and view all the answers

For 10–3 M H3PO3 with α = 10%, what is the expected pH?

<p>4.7 (B)</p> Signup and view all the answers

Calculate the Ka for a 10–2 M HCN solution that has a pOH of 10.

<p>Ka = 10–4 (A)</p> Signup and view all the answers

What would be the [H+] concentration of a 0.006 M benzoic acid (Ka = 6 × 10–5)?

<p>6 × 10–4 (B)</p> Signup and view all the answers

The pKb for fluoride ion at 25°C is 10.83. What is the ionization constant for hydrofluoric acid at this temperature?

<p>2.72 × 10–5 (D)</p> Signup and view all the answers

What is the concentration of OH- ions in a 0.01 M ammonia solution that is 5% ionized?

<p>0.005 M (C)</p> Signup and view all the answers

Calculate the molarity of nitrous acid at which its pH becomes 2 (Ka = 4.5 × 10–4).

<p>0.3333 (D)</p> Signup and view all the answers

Precipitation of AgCl will occur when equal volumes of which mixture are combined, given that its Ksp is 1.8 × 10–10?

<p>10–4 M AgNO3 and 10–4 M HCl (D)</p> Signup and view all the answers

At what pH will Mg2+ ions begin to precipitate as Mg(OH)2 from a 0.001 M solution, given its Ksp is 1.0 × 10–11?

<p>10 (C)</p> Signup and view all the answers

When 15 mL of 0.05 M AgNO3 is mixed with 45.0 mL of 0.03 M K2CrO4, will precipitation of Ag2CrO4 occur given its Ksp is 1.9 × 10–12?

<p>Yes, precipitation will occur. (A)</p> Signup and view all the answers

Which option represents the correct increasing order of solubility for the given solubility products?

<p>2, 1, 3 (D)</p> Signup and view all the answers

What is the concentration of CO32– ions when water reaches equilibrium with both CaCO3 and BaCO3, given their Ksp values?

<p>1.5 × 10–8 (B)</p> Signup and view all the answers

What percentage of dimethylamine is ionized in a 0.02 M solution when the ionization constant is 5.4 × 10–4?

<p>Approx. 10% (B)</p> Signup and view all the answers

What is the pH of a buffer solution containing 0.250 M benzoic acid and 0.150 M sodium benzoate with a Ka of 6.5 × 10–5?

<p>Approximately 4.2 (C)</p> Signup and view all the answers

What is the concentration of phenolate ion in a 0.05 M solution of phenol given its ionization constant is 1.0 × 10–10?

<p>2.2 × 10–6 (A)</p> Signup and view all the answers

What is a characteristic of a buffer solution?

<p>It maintains an almost constant pH (D)</p> Signup and view all the answers

Which buffer system maintains the pH of blood at around 7.4?

<p>H2CO3/HCO3– (A)</p> Signup and view all the answers

Calculate [H+] in mol/L of a solution that is 0.20 M in CH3COONa and 0.1 M in CH3COOH, given that Ka for CH3COOH is 1.8 × 10–5.

<p>1.1 × 10–5 (D)</p> Signup and view all the answers

For a desired pH of 6 using sodium acetate and acetic acid, what is the proper ratio of salt to acid (where Ka = 10–5)?

<p>10 : 1 (D)</p> Signup and view all the answers

What is the pH of a buffer solution containing 0.1M HCN (pKa = 9.30) and 0.2 M NaCN?

<p>9.61 (D)</p> Signup and view all the answers

What is the approximate pH of a solution made from 10 ml of 1N sodium acetate and 50 ml of 2N acetic acid (Ka = 1.8 × 10–5)?

<p>5 (B)</p> Signup and view all the answers

What is the pOh of a solution composed of 0.1 M NH4OH and 0.1 M NH4Cl which has a pH of 9.25?

<p>4.75 (A)</p> Signup and view all the answers

If the concentration ratio of a weak acid and its salt increases ten-fold, how does the pH of the solution change?

<p>Increases by one (A)</p> Signup and view all the answers

What is the pH of pure H2O?

<p>7 (C)</p> Signup and view all the answers

Which of the following is classified as an acid salt?

<p>NaHSO3 (D)</p> Signup and view all the answers

What will be the pH of a 1.0 M ammonium formate solution if Ka = 1 × 10–4 and Kb = 1 × 10–5?

<p>7.5 (C)</p> Signup and view all the answers

Which salt listed will not undergo hydrolysis?

<p>NH4Cl (D)</p> Signup and view all the answers

What is the correct formula for calculating pH in anionic hydrolysis?

<p>pH = pKw + pKa - pKb (B)</p> Signup and view all the answers

If pKb for CN at 25°C is 4.7, what is the expected pH of a 0.5M aqueous NaCN solution?

<p>11.5 (D)</p> Signup and view all the answers

What is the relationship between the Ksp values of salts M2X, QY2, and PZ2 when their solubilities are equal?

<p>Ksp(M2X) = Ksp(QY2) = Ksp(PZ2) (B)</p> Signup and view all the answers

If the pH of a solution increases from 3 to 6, how will the H+ ion concentration change?

<p>Reduced by 1000 times (D)</p> Signup and view all the answers

Flashcards

Conjugate base of H2O

The conjugate base of water (H2O) in the Brønsted-Lowry acid-base theory is hydroxide ion (OH–).

Conjugate base of HF

The conjugate base of hydrofluoric acid (HF) is fluoride ion (F–).

Conjugate acid of O–2

The conjugate acid of the oxide ion (O2−) is hydroxide ion (OH–).

Conjugate base of (CH3)2NH2+

The conjugate base of dimethylammonium ion ((CH3)2NH2+) is dimethylamine ((CH3)2NH).

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Bronsted acid of H2O in reaction with NH3

In the reaction NH3 + H2O → NH4+ + OH–, water acts as a Bronsted acid.

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Conjugate base of HNO3

The conjugate base of nitric acid (HNO3) is nitrate ion (NO3–).

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Amphoteric species

A species that can act both as a Brønsted-Lowry acid and a base.

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Bronsted acid and base in NH3 and H2O

In the reaction NH3(aq) + H2O(l) ⇌ NH4+(aq) + OH– (aq), H2O acts as an acid (donating a proton) while NH3 acts as a base (receiving a proton).

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Lewis acid-base reaction example

Reactions involving the formation of coordinate covalent bonds, where one reactant acts as the electron-pair acceptor (Lewis acid) and the other as the electron-pair donor (Lewis base).

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Species that can't be both acid and base

Some chemical species, like HCl, cannot function simultaneously as both a Brønsted-Lowry acid and a base.

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Least likely lewis base

A species that is not likely to donate an electron pair; for example, BF₃.

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Weakest acid

A Brønsted acid that does not readily donate a proton.

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Dilution law

An example of a law applicable in dilution of a weak electrolyte solution, typically for acids and bases, not neutral salts, like NaCl.

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pH calculation

pH is the negative logarithm of the hydrogen ion concentration. To calculate for pH = -log([H+])

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pH of a solution

A measure of the concentration of hydrogen ions (H+) in a solution, expressed on a logarithmic scale.

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[OH⁻]

Hydroxide ion concentration in a solution.

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pOH

A measure of the concentration of hydroxide ions (OH⁻) in a solution, expressed on a logarithmic scale.

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pH calculation

Determines the hydrogen ion concentration from pH, or the pH from H+ concentration.

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Kw (ionic product of water)

The equilibrium constant for the autoionization of water.

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pH of a base

pH greater than 7

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pH of an acid

pH less than 7

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pKw

Negative logarithm of Kw (the ionic product of water).

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Neutral solution

A solution with a pH = 7 at 25°C.

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Acid vs base

Acids release H+ in water and bases release OH- in water.

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pH scale

A scale used to measure the acidity or alkalinity of a solution.

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Relationship between pH and pOH

pH + pOH = pKw

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OH- ion concentration (0.01M NH3)

The concentration of hydroxide ions in a 0.01M ammonia solution that is 5% ionized is 0.0005 M

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H+ ion concentration (5  10⁻³ M H₂CO₃)

The concentration of hydrogen ions in a 5  10⁻³ M H₂CO₃ solution with 10% dissociation is 10⁻³M

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pH of 2.5 × 10⁻¹ M HCN

The pH of a 2.5 × 10⁻¹ molar HCN solution with a Ka of 4 × 10⁻¹⁰ is approximately 4.7.

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Molarity of Nitrous Acid (pH=2)

The molarity of nitrous acid at which its pH reaches 2, with a Ka of 4.5 × 10⁻⁴ is approximately 0.3333 M.

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Degree of dissociation (0.1M weak acid, pH = 3)

The degree of dissociation of a weak acid (HA) with a 0.1 M solution and a pH of 3 is approximately 10%.

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pH of 0.01 M acetic acid (1% ionized)

The pH of a 0.01 M acetic acid solution which is 1% ionised is approximately 3.

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α (10⁻² M NH₄OH, [OH⁻] = 10⁻³)

The degree of dissociation (α) for a 10⁻² M NH₄OH solution with a hydroxide ion concentration of 10⁻³ is 10%.

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pH of 10⁻³ M CH₃COOH (Ka = 10⁻⁵)

The pH of a 10⁻³ M CH₃COOH solution with a Ka of 10⁻⁵ is approximately 4.

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Ka for 10⁻² M HCN acid with pOH 10

The Ka value for a 10⁻² M HCN solution with a pOH of 10 is 10⁻⁴.

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Kb for fluoride ion (Ka for HF)

The Kb value for the fluoride ion is 2.9×10⁻¹¹ when the Ka value for hydrofluoric acid is 3.5×10⁻⁴

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Ionization Constant for X- (Ka for HX)

The ionization constant of X⁻ can be determined from the ionization constant of the acid (Ka), according to relationship between Ka and Kb with Kw.

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Buffer Solution

A solution that resists changes in pH when small amounts of acid or base are added.

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Blood Buffer

The buffer system in blood that maintains a nearly constant pH around 7.4.

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Buffer Components

A buffer solution typically consists of a weak acid and its conjugate base (or a weak base and its conjugate acid).

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Buffer pH Calculation

The pH of a buffer solution is determined using the Henderson-Hasselbalch equation.

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Buffer Ratio (Salt/Acid)

The ratio of the concentration of the conjugate base to the concentration of the weak acid determines the pH of a buffer solution.

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pH of a Buffer

The pH of a buffer solution is approximately equal to the pKa of the weak acid component.

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Strong Base addition to buffer

Strong bases react with the weak acid in the buffer, shifting the equilibrium and changing the buffer's pH.

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Weak Acid/Salt Ratio

Changing the ratio of weak acid to its salt alters the buffer's pH.

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Buffer Ionization

The amount of a weak acid that's ionized in a buffer solution

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pOH calculation in buffer

pOH can be calculated when a strong base is added to a weak acid buffer.

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Buffer Addition of HCl or NaOH

Adding small amounts of strong acids or bases (HCl or NaOH) to a buffer solution will cause little to no change in pH.

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Henderson-Hasselbalch Equation

A mathematical equation that allows for the calculation of the pH of buffer solutions.

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AgCl Ksp

Solubility product constant for silver chloride, indicating its solubility in water.

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pH of Pure H2O

The pH of pure water is 7.

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Precipitate AgCl

Formation of solid AgCl when mixing solutions.

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Acid Salt Example

A salt derived from a strong base and a weak acid.

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Mg(OH)2 Ksp

Solubility product constant for magnesium hydroxide.

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pH of Ammonium Formate

The pH of a 1.0 M ammonium formate solution is approximately 6.5.

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Mg2+ precipitation pH

The pH at which Mg2+ ions begin to precipitate as Mg(OH)2 from a solution.

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Salt Not Undergoing Hydrolysis

A salt that doesn't react with water (neutral salt).

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Anionic Hydrolysis pH Formula

pH = (1/2) * pKw + (1/2) * pKa - (1/2) * pKb

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Ag2CrO4 Ksp

Solubility product constant for silver chromate.

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Solubility increasing order

Relative order of solubility for salts.

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pH of NaCN solution

The pH of a 0.5M NaCN solution is approximately 11.5.

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Simultaneous solubility AB and AC

Calculating solubility of two salts in the same solution.

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Ksp Relation for Salts

If salts M2X, QY2, and PZ2 have equal solubilities, Ksp(M2X) = Ksp(QY2) = Ksp(PZ2).

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F- concentration in MgF2 and SrF2

Determining Fluoride ion concentration in a solution saturated by two specific compounds.

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Solubility Product of Ag2CrO4

The solubility product of silver chromate (Ag2CrO4) is 1.69 x 10^-12 using an Ag+ concentration of 1.5 x 10^-4 mol L-1.

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Ksp of AgCl

The Ksp for AgCl, given a solubility of 1.43 x 10^-4g/100mL at 25°C., is approximately 1 x 10^-10

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Solubility product value, CaCO3 and BaCO3

Finding equilibrium concentration of CO32- ion when two carbonate salts are present.

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Dimethylamine ionization constant

The constant for deprotonation of dimethylamine.

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Ksp Relation with Same Solubilities

If salts M2X, QY2, and PZ3 have the same solubilities, Ksp (M2X) = Ksp(QY2) < Ksp (PZ3).

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Ionization degree in 0.02M dimethylamine

The percentage of dimethylamine molecules that are ionized in a solution.

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pH Change and H+ concentration

Increasing the pH from 3 to 6 reduces the H+ ion concentration by 1000 times

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pOH of Beer

The pOH of a beer is 10.0.

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Phenol ionization constant

Constant for ionization of phenol.

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Phenolate ion concentration

Concentration of phenolate ion in a 0.05M phenol solution.

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Buffer solution pH

pH of a solution that resists drastic changes in pH.

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Study Notes

Ionic Equilibrium Questions for NEET 2025

  • This material contains questions on ionic equilibrium, a topic in physical chemistry relevant to the NEET 2025 exam.
  • The questions cover various concepts, including conjugate base/acid identification, Bronsted acid/base behavior, Lewis acid/base definitions, and calculations of pH/pOH values.
  • Key concepts include the identification of conjugate bases associated with water and hydrofluoric acid, the definition of conjugated acid of an ion, identification of conjugate base for a reactant in a certain reaction and identifying a Bronsted acid/base. Additional questions cover how water can act both as an acid and a base, how to solve for pH or pOH given certain concentrations.
  • Solutions to these questions are available in the accompanying class notes PDF. Students are advised not to seek answers directly.

Additional Notes

  • Note that different types of acid/base problems require different methodologies: Bronsted and Lewis acids/bases require identification of proton donation and electron pair acceptance, and questions regarding ion concentration or hydrolysis are tackled using appropriate formulas. These may include the use of the dissociation constant or other related constants.
  • The study material includes various problem types, requiring diverse approaches and formulas. The use of logarithm based calculations are also important.
  • Solutions to the questions are in separate PDF notes.
  • The study material is designed to help students practice and prepare for problem-solving in ionic equilibrium. A multitude of problems are presented, spanning multiple problem types, and requiring an understanding of formulas and methodologies related to different types of acid/base problems.

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