Boyle's Law Practical Experiment

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Questions and Answers

What is essential to ensure a correct graph is obtained in the experiment?

  • The temperature must remain constant throughout.
  • The water must be boiling at all times.
  • The plunger must not stick. (correct)
  • The air sample must be perfectly sealed.

What does the gradient of the line in the graph represent?

  • The relationship between length and temperature. (correct)
  • The initial length of the air sample.
  • The average temperature of the water.
  • The change in volume of the air with temperature.

How can the value of absolute zero be estimated from the graph?

  • By using the highest temperature reading.
  • By averaging the lengths measured at room temperature.
  • By substituting l = 0 into the equation l = mt + c. (correct)
  • By measuring the boiling point of the water.

What should be done to improve the cooling process of the water during the experiment?

<p>Pour some water out and replace it with cold water. (B)</p> Signup and view all the answers

What does the value c represent in the equation l = mt + c?

<p>The length of the air sample when temperature is 0 °C. (A)</p> Signup and view all the answers

What is the formula used to calculate the force exerted by the masses in the experiment?

<p>F = mg (A)</p> Signup and view all the answers

How is the pressure exerted by the force on the air sample calculated?

<p>P = F/A (D)</p> Signup and view all the answers

What unit is used to express the pressure of the air sample after calculations?

<p>Pascals (D)</p> Signup and view all the answers

What should be done to ensure the plunger in the syringe moves freely during the experiment?

<p>Position the clamp high enough above the plunger (D)</p> Signup and view all the answers

What is the purpose of subtracting the pressure exerted by the masses from standard atmospheric pressure?

<p>To determine the pressure of the air sample (D)</p> Signup and view all the answers

What is the initial condition of the air sample in the syringe before any masses are added?

<p>At standard atmospheric pressure (B)</p> Signup and view all the answers

What should be done with the rubber tubing during the setup of the apparatus?

<p>Pinch the tubing to stop air flow (D)</p> Signup and view all the answers

What is the mathematical relationship plotted on the graph after data collection?

<p>1/V against P (B)</p> Signup and view all the answers

Flashcards

Plunger Stickiness

Issue where the plunger does not move smoothly, affecting data accuracy.

Charles's Law

States that the volume of a gas is directly proportional to its temperature in Kelvin if pressure is constant.

Graph of l vs T

A graph plotting length (l) against temperature (T) to determine gas behavior.

Absolute Zero Estimate

Value of temperature at which volume of the gas would theoretically be zero, found from the graph.

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Graph Equation

Equation derived from the graph of l against T: l = mT + c.

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Boyle's Law

For a given mass of gas at constant temperature, the volume is inversely proportional to pressure.

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Cross-sectional area (A)

Area of the seal's cross-section, calculated as d²/4 in m².

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Force calculation (F)

Force exerted by the mass is F = mg, with g being 9.81 N/kg.

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Pressure (P)

Pressure exerted on the air sample is calculated as P = F/A in Pascals.

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Standard atmospheric pressure

Pressure at sea level, approximately 101 kPa.

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Initial volume measurement

Volume of air before applying any mass, measured at standard atmospheric pressure.

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Graph of 1/V against P

Graph plotting the inverse of volume (1/V) against pressure (P) to verify Boyle’s law.

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Mean volume of air sample

Average volume calculated from multiple measurements after adding weights.

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Study Notes

Boyle's Law Practical

  • Equipment: Syringe (10 ml), rubber tubing, pinch clamp, 100 g masses & holder, counterweight (2 kg), micrometer, ruler.
  • Procedure:
    • Measure rubber seal diameter using micrometer and convert to meters.
    • Calculate the cross-sectional area of the seal (A = Ï€d²/4).
    • Fill syringe with 4.0 ml of air.
    • Attach rubber tubing to the syringe nozzle ensuring a tight seal.
    • Secure the tubing with a pinch clamp.
    • Add masses to the mass holder and record volumes changes using the syringe scale.
    • Repeat with additional masses.
    • Repeat entire experiment for a second data set.
    • Calculate force exerted by masses using F = mg.
    • Calculate pressure exerted on air sample using pressure = Force/Area.
    • Convert pressure to kPa.
    • Calculate pressure of air sample by subtracting sample pressure from standard atmospheric pressure(101 kPa).
    • Plot a graph of 1/V against P (Volume against pressure).
    • Ensure graph passes through the origin to minimize errors and calculate the gradient(m)

Charles's Law Practical

  • Equipment: Capillary tube, elastic bands, ruler, thermometer, 2-liter beaker, hot water, heat-proof mat.
  • Procedure:
    • Set up apparatus as shown in diagrams.
    • Heat water in the beaker.
    • Carefully pour hot water into the beaker to submerge the air sample in the capillary tube.
    • Measure temperature(θ) and length(l) of air sample.
    • Allow water to cool slowly, taking readings of temperature and length of the air sample.
    • Repeat procedure until room temperature is reached.
    • Plot a graph of length (l) against temperature (θ).
    • Find the gradient (m) of the best straight line drawn through the plotted points.
    • Calculate the y-intercept (c) of the line.
    • Calculate absolute zero (θ₀) by substituting l = 0 into the equation.

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