Boiling Point Elevation: NaCl Solution
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Questions and Answers

At 300 K, 36 g of glucose present per litre in its solution has an osmotic pressure of 4.98 bar. If the osmotic pressure of the solution is 1.52 bars at the same temperature, what would be its concentration?

0.061 M

18 g of glucose, $C_6H_{12}O_6$, (Molar Mass= 180 g mol$^{-1}$) is dissolved in 1 kg of water in a sauce pan. At what temperature will this solution boil (Kb for water = 0.52 K kg mol$^{-1}$)?

100.052 $^\circ$C

Calculate the boiling point of a solution prepared by adding 15.00 g of NaCl to 250.0g of water. ($K_b$ for water = 0.512 K kg mol$^{-1}$, (Molar mass of NaCl = 58.44 g)).

101.5 $^\circ$C

Flashcards

Boiling Point Elevation

The increase in boiling point of a solution compared to the pure solvent.

Colligative Property

A colligative property dependent on the number of solute particles in a solution.

Van't Hoff Factor (i)

Van't Hoff factor represents the number of particles a solute dissociates into in solution.

ΔTb Formula

The formula to calculate boiling point elevation.

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Kb

The molal boiling point elevation constant; depends on the solvent.

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W2

Grams of solute.

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W1

Grams of solvent.

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M2

Molar mass of solute.

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NaCl Dissociation

NaCl splits into Na+ and Cl-.

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Solution Boiling Point

The boiling point of the solution.

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Osmotic Pressure (π)

Pressure exerted by a solution across a semipermeable membrane.

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van't Hoff Equation

π = cRT, where c is molar concentration, R is the ideal gas constant, and T is temperature.

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Molar concentration

Moles of solute per liter of solution.

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R

Ideal Gas Constant.

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T

Temperature in Kelvin.

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Molar Mass

The mass of one mole of a substance.

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Solution

A homogeneous mixture of a solute dissolved in a solvent.

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Solute

The substance being dissolved.

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Solvent

The substance doing the dissolving.

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Freezing Point Depression

A colligative property; the decrease in the freezing point of a solution compared to the pure solvent.

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Study Notes

  • Problem: Calculating the boiling point of a solution made by adding 15.00 g of NaCl to 250.0 g of water.
  • Water's ebullioscopic constant (Kb) is 0.512 K kg mol-1.
  • NaCl's molar mass is 58.44 g.

Calculation Steps

  • ΔTb = (i * Kb * 1000 * W2) / (W1 * M2)
  • NaCl dissociates into Na+ and Cl- ions, resulting in i = 2.
  • W2 = 15.0 g (mass of NaCl)
  • W1 = 250.0 g (mass of water)
  • M2 = 58.44 g mol-1 (molar mass of NaCl)
  • Kb = 0.512 K kg mol-1
  • ΔTb = (2 * 0.512 * 1000 * 15.0) / (250.0 * 58.44) = 1.05 °C.
  • Boiling point of the solution = 100 + 1.05 = 101.5 °C.

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Description

Calculate the boiling point of a NaCl solution. The solution is made by adding 15.00 g of NaCl to 250.0 g of water. The boiling point elevation is calculated using the formula ΔTb = (i * Kb * 1000 * W2) / (W1 * M2).

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