Biochemistry Overview

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Questions and Answers

What is the basic unit of carbohydrates?

  • Oligosaccharide
  • Disaccharide
  • Monosaccharide (correct)
  • Polysaccharide

Which type of chemical bond involves the donation or acceptance of electrons?

  • Van der Waals forces
  • Covalent bond
  • Ionic bond (correct)
  • Metallic bond

What best describes stereoisomers?

  • Molecules with different functional groups
  • Molecules with the same molecular formula and structural formula
  • Molecules with the same molecular formula but different geometric arrangements (correct)
  • Molecules with different molecular formulas but same geometry

Which property makes carbohydrates like polysaccharides nonsoluble and tasteless?

<p>High molecular weight (A)</p> Signup and view all the answers

What does stereochemistry primarily study?

<p>Three-dimensional arrangement of atoms in molecules (C)</p> Signup and view all the answers

What characterizes chiral centers in organic molecules?

<p>Having four different substituents (B)</p> Signup and view all the answers

What type of carbohydrate cannot be broken down into simpler sugars?

<p>Monosaccharide (D)</p> Signup and view all the answers

Which of the following statements about biomolecules is correct?

<p>Biomolecules are large, complex structures with high molecular weight. (D)</p> Signup and view all the answers

Which type of sugar contains more than 10 monosaccharides?

<p>Polysaccharide (A)</p> Signup and view all the answers

What functional group characterizes aldoses?

<p>Aldehyde group (B)</p> Signup and view all the answers

Which of the following sugars is found in milk?

<p>Erythrose (B)</p> Signup and view all the answers

What is the primary function of triglycerides in the body?

<p>Store energy (B)</p> Signup and view all the answers

Which component is described as having a hydrophilic head and a hydrophobic tail?

<p>Phospholipids (B)</p> Signup and view all the answers

Which of the following is NOT a functional group found in simple sugars?

<p>Amine (A)</p> Signup and view all the answers

Which type of lipid is primarily involved in forming cell membranes?

<p>Phospholipids (C)</p> Signup and view all the answers

Some sugars can convert into glucose in the body. Which of the following is one of them?

<p>Erythrose (C)</p> Signup and view all the answers

Which structure refers to a long chain of carbon atoms with attached functional groups?

<p>Hydrocarbon chain (A)</p> Signup and view all the answers

What type of bond links amino acids together to form proteins?

<p>Peptide bond (A)</p> Signup and view all the answers

What are nucleic acids primarily composed of?

<p>Nucleotide polymers (D)</p> Signup and view all the answers

What is the most abundant molecule in the human body, comprising about 65% of its weight?

<p>Water (B)</p> Signup and view all the answers

What characteristic of water molecules contributes to its polarity?

<p>Directional charge distribution (A)</p> Signup and view all the answers

Which process is primarily controlled by mRNA during protein synthesis?

<p>Translation (B)</p> Signup and view all the answers

Which type of fatty acid contains one or more double bonds in its hydrocarbon chain?

<p>Unsaturated fatty acid (B)</p> Signup and view all the answers

Which component of nucleotides distinguishes different nucleic acids?

<p>Nitrogenous base (D)</p> Signup and view all the answers

What property of water enables it to dissolve most biomolecules?

<p>Polarity (C)</p> Signup and view all the answers

What causes the higher melting and boiling points of water compared to other similar molecules?

<p>Hydrogen bonding (B)</p> Signup and view all the answers

Which of the following statements is true about the electronegativity of oxygen in water?

<p>Oxygen attracts electrons more effectively than hydrogen. (A)</p> Signup and view all the answers

What is the term for the energy required to break a chemical bond, such as those in water?

<p>Bond dissociation energy (D)</p> Signup and view all the answers

How does water interact with sodium chloride (NaCl) when dissolved?

<p>It hydrates and stabilizes the Na+ and Cl- ions. (A)</p> Signup and view all the answers

What characteristic of water makes it 'water-hating'?

<p>It repels non-polar substances. (A)</p> Signup and view all the answers

What is the significance of the partial positive charge in water molecules?

<p>It allows water to function as a good solvent. (A)</p> Signup and view all the answers

What does the term 'hydrophilic' refer to regarding substances in water?

<p>Substances that are attracted to water. (B)</p> Signup and view all the answers

What characterizes a supersaturated solution?

<p>It has more solute than a saturated solution. (C)</p> Signup and view all the answers

Which factor does NOT affect the rate of solubility?

<p>Color of the solute. (A)</p> Signup and view all the answers

What is the primary method for separating a mixture using differences in boiling points?

<p>Distillation (B)</p> Signup and view all the answers

In a closed system, what is exchanged?

<p>Only energy. (C)</p> Signup and view all the answers

What does the term 'diluted solvent' refer to?

<p>A solvent with little solute dissolved in it. (B)</p> Signup and view all the answers

Which statement about polar solvents is correct?

<p>They are effective for dissolving polar and ionic solutes. (A)</p> Signup and view all the answers

What describes a closed system in thermodynamics?

<p>Nothing can enter or leave the system. (B)</p> Signup and view all the answers

Which process involves separating substances by particle size?

<p>Filtration (C)</p> Signup and view all the answers

What is the first law of thermodynamics about energy?

<p>Energy can change forms but is not created or destroyed. (C)</p> Signup and view all the answers

What does the second law of thermodynamics state about entropy?

<p>Entropy increases in isolated systems over time. (C)</p> Signup and view all the answers

At absolute zero, what is the entropy of a perfect solid?

<p>Its entropy is at absolute zero. (D)</p> Signup and view all the answers

What does a higher enthalpy indicate about a system at constant pressure?

<p>The system has more energy available to perform work. (D)</p> Signup and view all the answers

What is Gibbs free energy used to measure?

<p>The maximum amount of work obtainable from a system. (D)</p> Signup and view all the answers

What indicates that a reaction is non-spontaneous in terms of Gibbs free energy?

<p>ΔG is positive. (D)</p> Signup and view all the answers

How does the freedom of movement change when a solid substance turns into a liquid?

<p>It increases, thus entropy increases. (C)</p> Signup and view all the answers

What happens to the Gibbs free energy at equilibrium?

<p>ΔG is equal to zero at equilibrium. (A)</p> Signup and view all the answers

Flashcards

Biochemistry

The study of the chemical processes occurring within and relating to living organisms.

Biomolecules

Compounds that are essential components of living organisms.

Monomer

A small molecule that serves as a building block for a larger molecule.

Polymer

A large molecule composed of repeating structural units (monomers).

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Chemical Bonding

The forces that hold two or more atoms together.

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Stereoisomers

Molecules with the same molecular formula but different arrangements of atoms in space.

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Stereochemistry

The study of the three-dimensional arrangement of atoms in molecules.

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Carbohydrates

A class of biomolecules primarily composed of carbon, hydrogen, and oxygen, serving as a major source of energy.

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Monosaccharides

Simple sugars with one, two or more carbons. For example, Glucose and Fructose are monosaccharides, which are the most basic forms of sugar.

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Disaccharides

Carbohydrates formed by the joining of two monosaccharides.

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Carbohydrates

Organic compounds with ratios of carbon, hydrogen, and oxygen.

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Aldoses

Sugars that have aldehyde group as a functional group.

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Lipids

Fats, oils, and waxes, important for energy storage and cell structure.

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Triglycerides

Lipids that function as energy storage.

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Unsaturated fats

Fats with one or more double bonds in their fatty acid chains.

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Phospholipids

Lipids that form cell membranes due to hydrophilic head and hydrophobic tail.

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Fatty Acids

Organic molecules with a hydrocarbon chain and a carboxyl group.

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Amino Acids

Building blocks of proteins, having an amino and a carboxyl group.

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Nucleic Acids

Biological polymers, formed from nucleotides.

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Protein Synthesis

Process of creating proteins using information in DNA.

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Water

Most abundant substance in cells, a polar molecule.

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Glycerol

A simple alcohol used to form fats.

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Peptide Bond

A covalent bond binding amino acids to form proteins.

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Hydrocarbon Chain

Chain of carbon and hydrogen atoms.

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Zeroeth Law

If two systems are each in thermal equilibrium with a third system, then they are in thermal equilibrium with each other.

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Saturated solution

A solution that contains the maximum amount of solute that can dissolve at a given temperature.

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Supersaturated solution

A solution that contains more solute than it can normally dissolve at a given temperature.

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First Law of Thermodynamics

Energy cannot be created or destroyed, only changed.

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Filtration

A method to separate a mixture by using a filter to remove solid particles from a liquid.

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Second Law of Thermodynamics

The entropy of an isolated system always increases.

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Distillation

A method that separates liquids with different boiling points by vaporizing and condensing them.

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Third Law of Thermodynamics

A perfect crystal at absolute zero has zero entropy.

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Dynamic steady state

A state where changes occur, but the overall composition and concentration stays relatively constant.

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Entropy (ΔS)

Measure of disorder/randomness in a system.

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Open system

A system that exchanges matter and energy with its surroundings.

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Enthalpy

Measure of heat content at constant pressure.

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Closed system

A system that exchanges energy but not matter with its surroundings.

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Gibbs Free Energy (G)

Maximum amount of work a thermodynamic system can do at constant temperature and pressure.

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Spontaneous Reaction

A reaction that occurs naturally. ΔG is negative.

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Thermodynamics

The study of the relationship between heat, work, temperature, and energy.

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Study Notes

Biochemistry

  • Chemistry of living beings, studying structure, composition, and chemical reactions of substances.
  • Biomolecules are compounds of carbon with various functional groups.
  • Major biomolecules: carbohydrates, lipids, proteins, and nucleic acids.

Chemical Bonding

  • Chemical bonding joins atoms.
  • Covalent bonds involve sharing electrons.
  • Metallic bonds involve electron movement.

Stereoisomers

  • Stereoisomers have the same molecular formula and bonded atom sequence but different 3D arrangements.
  • Geometric isomers have different spatial arrangements around a double bond.
  • Optical isomers are mirror images of each other that cannot be superimposed.

Carbohydrates

  • Monosaccharides are the basic units.
  • Oligosaccharides consist of 2-10 monosaccharides.
  • Polysaccharides have more than 10 monosaccharides.

Lipids

  • Lipids are hydrophobic and insoluble in water.
  • Fats, phospholipids, and steroids are types of lipids.

Proteins

  • Proteins are polymers of amino acids.
  • Have diverse functions like structure, support, and enzymes.
  • Protein structures: primary, secondary, tertiary, and quaternary.

Nucleic Acids

  • Nucleic acids (DNA and RNA) store and transmit genetic information.
  • Constructed from nucleotides.

Water

  • Water is a polar molecule.
  • Its polarity leads to hydrogen bonds.
  • Crucial for biological processes and cellular shape.
  • Has a high specific heat, high boiling point and high surface tension.

Solutions

  • A solution is a homogenous mixture of a solute and a solvent.
  • Concentration refers to the amount of solute in the solvent.
  • Types include saturated, unsaturated, and supersaturated solutions.

Factors affecting dissolving

  • Temperature, pressure, and the nature of the solute and solvent affect the dissolving rate.

Separating Mixtures

  • Physical methods like filtration, distillation, and chromatography are used to separate mixtures.

Thermodynamics

  • Discusses energy changes and transfer in processes.
  • Laws of thermodynamics govern these changes.
  • Entropy is a measure of disorder in a system.
  • Enthalpy and Gibbs free energy are related to energy changes in systems.

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