Biochemistry Overview

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Questions and Answers

Which type of saccharide is composed of only one sugar unit?

  • Tetrasaccharide
  • Trisaccharide
  • Monosaccharide (correct)
  • Disaccharide

What functional group is found in aldoses?

  • Alcohol
  • Carbonyl
  • Aldehyde (correct)
  • Ketone

What structural component is characteristic of proteins?

  • Nucleotides
  • Monosaccharides
  • Amino acids (correct)
  • Fatty acids

Which of the following molecules is categorized as a triglyceride?

<p>Waxes (C)</p> Signup and view all the answers

Which molecule is considered the most abundant in the body and plays a critical role in cellular shape?

<p>Water (D)</p> Signup and view all the answers

Which of the following is a characteristic of glycosides?

<p>They can be derived from simple sugars. (C)</p> Signup and view all the answers

What type of bond links amino acids together in a protein?

<p>Peptide bond (A)</p> Signup and view all the answers

What is the primary role of carbohydrates in living organisms?

<p>Energy storage (A)</p> Signup and view all the answers

Which type of saccharide is specifically characterized by three sugar units?

<p>Trisaccharide (C)</p> Signup and view all the answers

What distinguishes nucleic acids from other biological macromolecules?

<p>They contain phosphate groups (C)</p> Signup and view all the answers

Which of the following components is NOT typically found in phospholipids?

<p>Carbohydrate chains (C)</p> Signup and view all the answers

Which functional group is NOT found in amino acids?

<p>Phosphate group (A)</p> Signup and view all the answers

What process describes the movement of water from a region of higher concentration to a lower concentration?

<p>Osmosis (A)</p> Signup and view all the answers

What type of sugar is primarily derived from fruits?

<p>Fructose (C)</p> Signup and view all the answers

Which type of bond is considered the strongest among the following?

<p>Ionic bond (D)</p> Signup and view all the answers

Which level of protein structure is characterized by the twisted and coiled formation?

<p>Secondary structure (A)</p> Signup and view all the answers

What characteristic of water allows it to exhibit both adhesion and cohesion?

<p>Its hydrogen bonding (A)</p> Signup and view all the answers

What role does mRNA play in protein synthesis?

<p>It transmits amino acid sequences (D)</p> Signup and view all the answers

What type of hydrocarbons are typically found in lipids?

<p>Long-chain hydrocarbons (D)</p> Signup and view all the answers

What occurs during osmotic lysis?

<p>Cell expansion and bursting (B)</p> Signup and view all the answers

In a hypertonic solution, which of the following statements is true?

<p>Water will move out of the cell. (D)</p> Signup and view all the answers

Which term describes a homogeneous mix of two or more substances?

<p>Solution (B)</p> Signup and view all the answers

What best describes an unsaturated solution?

<p>Can dissolve more solute at a given temperature. (A)</p> Signup and view all the answers

What term is used for the substances that dissolve a solute in a solution?

<p>Solvent (A)</p> Signup and view all the answers

What characteristic of oxygen contributes to the polarity of water molecules?

<p>Oxygen attracts electrons more strongly than hydrogen. (C)</p> Signup and view all the answers

What type of bonding allows water to have a higher boiling point compared to other similar-sized molecules?

<p>Hydrogen bonding between water molecules. (D)</p> Signup and view all the answers

How does water behave as a solvent for biomolecules?

<p>It easily dissolves most biomolecules due to its polarity. (A)</p> Signup and view all the answers

What is the significance of bond dissociation energy in water molecules?

<p>It is the energy required to break the hydrogen bonds between water molecules. (C)</p> Signup and view all the answers

What interaction allows water to stabilize sodium ions in solution?

<p>Hydration shells formed by water. (C)</p> Signup and view all the answers

What role do hydrogen bonds play in the structure of liquid water?

<p>They allow water to expand upon freezing. (C)</p> Signup and view all the answers

How does the polarity of water affect its interaction with charged biomolecules?

<p>Water stabilizes charged biomolecules through hydration. (C)</p> Signup and view all the answers

Which of the following best describes the term 'hydrophobic regions' in relation to water?

<p>They repel water and do not mix well with it. (B)</p> Signup and view all the answers

What does the first law of thermodynamics state regarding energy?

<p>Energy cannot be created or destroyed, only transformed. (A)</p> Signup and view all the answers

Which of the following statements correctly defines entropy?

<p>Entropy measures the disorder of a system. (D)</p> Signup and view all the answers

According to the second law of thermodynamics, what happens to the entropy of an isolated system?

<p>Entropy of the universe always increases. (A)</p> Signup and view all the answers

What occurs to the entropy of a solid when it transitions to a liquid state?

<p>Entropy increases due to increased freedom of movement. (D)</p> Signup and view all the answers

What is the purpose of gibbs free energy in thermodynamics?

<p>To quantify the energy available to do work at constant temperature and pressure. (C)</p> Signup and view all the answers

At equilibrium, when the products have lower energy than the reactants, what is the sign of ΔG?

<p>ΔG is negative, indicating a spontaneous reaction. (C)</p> Signup and view all the answers

What happens to the entropy of a perfect solid at absolute zero?

<p>The entropy is precisely zero. (C)</p> Signup and view all the answers

What does a high value of enthalpy indicate about the system?

<p>The system contains a high amount of energy at constant pressure. (D)</p> Signup and view all the answers

What defines a monomer in relation to biomolecules?

<p>A basic unit that links to form more complex structures (A)</p> Signup and view all the answers

Which type of bonding involves the transfer of electrons between atoms?

<p>Ionic bonding (C)</p> Signup and view all the answers

Stereoisomers are defined by which of the following characteristics?

<p>They have the same sequence of bonded atoms but different geometric arrangements. (B)</p> Signup and view all the answers

What is the main characteristic of carbohydrates?

<p>They are the most abundant source of energy and contain C, H, and O atoms. (D)</p> Signup and view all the answers

What distinguishes a polysaccharide from other carbohydrates?

<p>It is non-soluble and tasteless. (B)</p> Signup and view all the answers

How are chiral centers identified in a molecule?

<p>By having at least one carbon atom attached to four different substituents. (B)</p> Signup and view all the answers

Which of the following best describes the term 'stereochemistry'?

<p>It examines the 3-dimensional arrangement of atoms in molecules. (D)</p> Signup and view all the answers

What are oligosaccharides primarily characterized by?

<p>They can be further broken down into smaller monosaccharides. (B)</p> Signup and view all the answers

Flashcards

Biochemistry

The study of the chemical processes occurring within living organisms.

Biomolecule

A large, complex organic molecule, essential for life, found in living organisms.

Monomer

A small, simple molecule that can be linked together to form larger molecules called polymers.

Polymer

A large molecule composed of repeating structural units or monomer subunits.

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Chemical Bonding

The process of joining two or more atoms together through attractive forces.

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Stereoisomers

Molecules with the same molecular formula but different arrangements of atoms in space.

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Carbohydrates

A major class of biomolecules, primarily composed of carbon, hydrogen, and oxygen.

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Monosaccharides

The simplest form of carbohydrates; basic unit.

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Carbohydrates

Organic compounds composed of carbon, hydrogen, and oxygen, primarily serving as a source of energy.

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Monosaccharides

The simplest form of carbohydrates, containing 3 to 7 carbon atoms; cannot be hydrolyzed to smaller sugars.

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Disaccharides

Carbohydrates formed by combining two monosaccharides.

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Aldose

A monosaccharide containing an aldehyde functional group.

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Ketones

A monosaccharide containing a ketone functional group.

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Triglycerides

Lipids primarily used for energy storage.

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Fatty Acids

The building blocks of fats and oils; long hydrocarbon chains with a carboxyl group at one end.

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Phospholipids

Lipids containing a phosphate group, crucial to cell membrane structure.

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Fatty Acids

Building blocks of fats and oils, long hydrocarbon chains with a carboxyl group.

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Glycerol

Component of fats; an alcohol.

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Proteins

Large molecules made of amino acids, vital for structure and function.

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Amino Acids

Building blocks of proteins, differing in properties due to their side chains.

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Nucleic Acids

DNA and RNA; carry genetic information, made of nucleotides.

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Water

Most abundant substance in cells, polar molecule.

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Water Polarity

Water molecule with a slightly positive and negative end.

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Protein Synthesis

Formation of proteins using the information in mRNA.

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Water's Polarity

Water molecules have a slightly positive charge on the hydrogen atoms and a slightly negative charge on the oxygen atom.

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Hydrogen Bonding in Water

Attraction between the positive hydrogen of one water molecule and the negative oxygen of another water molecule.

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Water's High Specific Heat

Water resists temperature changes because of its extensive hydrogen bonding.

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Water as Universal Solvent

Water's polarity allows it to dissolve many substances, including salts and biomolecules.

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Water's High Boiling Point

A high boiling point due to the energy needed to break strong hydrogen bonds.

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Water's Role in Biomolecules

Water is crucial for many biological processes; it dissolves biomolecules.

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Hydrophilic

Substances that dissolve in water.

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Hydrophobic

Substances that are repelled by water.

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Osmosis

The movement of water across a selectively permeable membrane from an area of higher water concentration to an area of lower water concentration.

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Hypertonic Solution

A solution with a higher concentration of solutes outside the cell compared to inside. Water moves out of the cell.

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Adhesion

Attraction between unlike substances.

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Cohesion

Attraction between like substances (e.g., water molecules).

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Ionic Bond

A chemical bond formed by the transfer of electrons between atoms.

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Covalent Bond

A chemical bond formed by the sharing of electrons between atoms.

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Solution

A homogeneous mixture of two or more substances.

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Concentration (solution)

The amount of solute dissolved in a given amount of solvent.

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Zeroeth Law of Thermodynamics

If two thermodynamic systems are each in thermal equilibrium with a third, then they are in thermal equilibrium with each other.

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First Law of Thermodynamics

Energy cannot be created or destroyed, only changed from one form to another.

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Second Law of Thermodynamics

The entropy of an isolated system always increases over time.

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Third Law of Thermodynamics

The entropy of a perfect crystal at absolute zero is zero.

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Entropy

A measure of the disorder or randomness of a system.

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Enthalpy

Measure of the heat content of a system at constant pressure.

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Gibbs Free Energy

Amount of energy available to do work at constant temperature and pressure.

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Change in Gibbs Free Energy (ΔG)

The difference between the enthalpy change (ΔH) and the temperature multiplied by entropy change (TΔS).

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Study Notes

Biochemistry

  • Chemistry of living beings, encompasses the chemical processes in living organisms
  • Study of structure, composition, and chemical reactions of substances
  • Biomolecules: Compounds of carbon with various functional groups
    • Inorganic: Water, minerals (Small, low molecular weight, simple)
    • Organic: Carbohydrates, lipids, proteins, nucleic acids (Large, high molecular weight, complex structures)
  • Chemical Bonding: Joining of two or more atoms
    • Covalent: Sharing of electrons between nonmetals
    • Metallic: Electrons move freely between metals
    • Ionic: Donation or reception of electrons between atoms (metals and nonmetals)
  • Stereoisomers: Molecules with the same molecular formula and sequence of bonded atoms but different three-dimensional arrangements
    • Geometric isomers: Same molecular formula but differ in spatial arrangement around double bonds or cyclic structures
    • Optical isomers: Same formula but differ in arrangement of atoms around a central carbon atom
  • Carbohydrates
    • Monosaccharides: Basic unit, cannot be broken down further (e.g., glucose, fructose, galactose)
    • Oligosaccharides: 2-10 monosaccharides linked together (e.g., sucrose, lactose, maltose)
    • Polysaccharides: More than 10 monosaccharides (e.g., cellulose, starch, glycogen)
  • Lipids
    • Heterogeneous group of compounds, insoluble in water
    • Triglycerides, phospholipids, steroids, waxes. Essential components of cell membrane.
  • Proteins
    • Polymers of amino acids, crucial for a wide range of functions in the body
    • Primary, secondary, tertiary, and quaternary structure
  • Nucleic acids (DNA and RNA)
    • Polymers of nucleotides, essential for genetic information storage and protein synthesis

Water

  • Most abundant molecule in the human body (65% weight)
  • Polar molecule due to unequal distribution of electrons (partial positive and negative charges)
  • Hydrogen bonding allows water molecules to interact with other substances and form solutions easily
  • Unique properties including high boiling point, melting point, and heat capacity due to hydrogen bonding.
  • States: solid, liquid, and gaseous
  • Water as a solvent: dissolves many charged or polar molecules (hydrophilic)

Solutions

  • Homogeneous mixtures of two or more substances
    • Solute: Substance being dissolved
    • Solvent: Substance doing the dissolving
    • Concentration: Amount of solute in a solvent
    • Types of solutions: saturated, unsaturated, supersaturated
    • Factors affecting solubility: temperature, pressure, nature of solute and solvent

Separating Mixtures

  • Techniques such as filtration, distillation, and chromatography separate substances based on their physical properties
    • Filtration: Separating mixtures based on size
    • Distillation: Separating mixtures based on boiling point differences
    • Chromatography: Separating mixtures based on interactions with a stationary and mobile phase

Thermodynamics

  • Study of relationships between heat, work, temperature, and energy
  • Laws of Thermodynamics: describe energy transfer and transformations in chemical and physical processes
    • First Law: Energy cannot be created or destroyed, only transformed
    • Second Law: Entropy of the universe always increases in spontaneous processes
    • Third Law: Entropy of a perfect crystal at absolute zero is zero
  • Concepts like enthalpy, entropy, and Gibbs free energy are central to understanding spontaneous processes and energy changes in chemical and biological systems

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