Podcast
Questions and Answers
What is the relationship between free energy change (ΔG) and exergonic reactions?
What is the relationship between free energy change (ΔG) and exergonic reactions?
- ΔG is negative and spontaneous (correct)
- ΔG remains zero throughout the reaction
- ΔG is positive and spontaneous
- ΔG is negative and nonspontaneous
In the equation ΔG = ΔH − TΔS, what does a positive ΔG imply about the reaction?
In the equation ΔG = ΔH − TΔS, what does a positive ΔG imply about the reaction?
- The reaction occurs without any change in free energy
- The reaction is nonspontaneous and absorbs energy (correct)
- The reaction is spontaneous and releases energy
- The reaction proceeds without any change in entropy
What role do enzymes play in chemical reactions regarding activation energy (EA)?
What role do enzymes play in chemical reactions regarding activation energy (EA)?
- Enzymes consume energy during the reaction
- Enzymes lower the activation energy needed to start a reaction (correct)
- Enzymes increase the activation energy required for a reaction
- Enzymes are only effective in exergonic reactions
Which statement is true about endergonic reactions?
Which statement is true about endergonic reactions?
What determines whether a chemical reaction occurs spontaneously?
What determines whether a chemical reaction occurs spontaneously?
What is the primary reason that spontaneous processes can perform work?
What is the primary reason that spontaneous processes can perform work?
What happens to the free energy of a system when an exergonic reaction occurs?
What happens to the free energy of a system when an exergonic reaction occurs?
Which factor does NOT influence the activation energy (EA) of a reaction?
Which factor does NOT influence the activation energy (EA) of a reaction?
What process describes the movement of water from an area of lower solute concentration to an area of higher solute concentration?
What process describes the movement of water from an area of lower solute concentration to an area of higher solute concentration?
In what type of solution does a cell not experience any net movement of water?
In what type of solution does a cell not experience any net movement of water?
What happens to plant cells in a hypertonic environment?
What happens to plant cells in a hypertonic environment?
Which type of transport protein assists the movement of ions across the plasma membrane?
Which type of transport protein assists the movement of ions across the plasma membrane?
What characterizes a hypotonic solution with respect to a cell's internal environment?
What characterizes a hypotonic solution with respect to a cell's internal environment?
How do channel proteins facilitate molecular movement across a membrane?
How do channel proteins facilitate molecular movement across a membrane?
What is the primary cause of wilting in plants during water loss?
What is the primary cause of wilting in plants during water loss?
What type of environment can create osmotic challenges for organisms lacking rigid cell walls?
What type of environment can create osmotic challenges for organisms lacking rigid cell walls?
What role do bile salts play in the digestion of fats?
What role do bile salts play in the digestion of fats?
What primarily causes the release of energy from ATP?
What primarily causes the release of energy from ATP?
What happens to fatty acids and monoglycerides once they are absorbed by epithelial cells?
What happens to fatty acids and monoglycerides once they are absorbed by epithelial cells?
Which of the following processes is NOT one of the main types of work done by ATP in a cell?
Which of the following processes is NOT one of the main types of work done by ATP in a cell?
Which of the following correctly describes chylomicrons?
Which of the following correctly describes chylomicrons?
Where are chylomicrons transported after their formation in epithelial cells?
Where are chylomicrons transported after their formation in epithelial cells?
In the context of cellular energy, what is a phosphorylated intermediate?
In the context of cellular energy, what is a phosphorylated intermediate?
What happens to the structure of a protein during ATP-powered transport work?
What happens to the structure of a protein during ATP-powered transport work?
In what form are triglycerides primarily stored in adipose cells?
In what form are triglycerides primarily stored in adipose cells?
How does increasing substrate concentration affect the rate of an enzyme-catalyzed reaction?
How does increasing substrate concentration affect the rate of an enzyme-catalyzed reaction?
What components are found in chylomicrons besides triglycerides?
What components are found in chylomicrons besides triglycerides?
Which enzyme is responsible for breaking down triglycerides into fatty acids and monoglycerides in the gut?
Which enzyme is responsible for breaking down triglycerides into fatty acids and monoglycerides in the gut?
What is the net free-energy change ($ ext{ΔG}$) for the coupled reaction involving glutamic acid and ATP hydrolysis?
What is the net free-energy change ($ ext{ΔG}$) for the coupled reaction involving glutamic acid and ATP hydrolysis?
What is the role of the active site on an enzyme?
What is the role of the active site on an enzyme?
What role do apolipoproteins play in chylomicrons?
What role do apolipoproteins play in chylomicrons?
Which statement accurately describes ATP’s function in coupling reactions?
Which statement accurately describes ATP’s function in coupling reactions?
What distinguishes enzymes in terms of reaction rates compared to other catalysts?
What distinguishes enzymes in terms of reaction rates compared to other catalysts?
What is an enzyme-substrate complex?
What is an enzyme-substrate complex?
Which stage of glucose metabolism accounts for the majority of ATP synthesis?
Which stage of glucose metabolism accounts for the majority of ATP synthesis?
What is the product of glycolysis that is crucial for the next step in cellular respiration?
What is the product of glycolysis that is crucial for the next step in cellular respiration?
During which phase of glycolysis is ATP utilized?
During which phase of glycolysis is ATP utilized?
Which enzyme is responsible for the conversion of pyruvate to acetyl CoA?
Which enzyme is responsible for the conversion of pyruvate to acetyl CoA?
What is the net gain of ATP from one molecule of glucose after glycolysis?
What is the net gain of ATP from one molecule of glucose after glycolysis?
Which of the following best defines substrate-level phosphorylation?
Which of the following best defines substrate-level phosphorylation?
Which process occurs in the cytoplasm regardless of the presence of oxygen?
Which process occurs in the cytoplasm regardless of the presence of oxygen?
What does oxidative phosphorylation primarily depend on?
What does oxidative phosphorylation primarily depend on?
Which pigment is primarily responsible for capturing light energy during photosynthesis?
Which pigment is primarily responsible for capturing light energy during photosynthesis?
What is the role of carotenoids in photosynthesis?
What is the role of carotenoids in photosynthesis?
Which part of the photosystem primarily accepts excited electrons?
Which part of the photosystem primarily accepts excited electrons?
What occurs when chlorophyll absorbs a photon of light?
What occurs when chlorophyll absorbs a photon of light?
Which structural component of chlorophyll differentiates chlorophyll a from chlorophyll b?
Which structural component of chlorophyll differentiates chlorophyll a from chlorophyll b?
What is emitted when excited electrons from chlorophyll return to the ground state?
What is emitted when excited electrons from chlorophyll return to the ground state?
What does the action spectrum for photosynthesis indicate?
What does the action spectrum for photosynthesis indicate?
What type of protein complex is found in the reaction-center of a photosystem?
What type of protein complex is found in the reaction-center of a photosystem?
Which photosystem operates first in the light reactions?
Which photosystem operates first in the light reactions?
What is the main product generated during the light reactions of photosynthesis?
What is the main product generated during the light reactions of photosynthesis?
Flashcards
Exergonic Reaction
Exergonic Reaction
A reaction that releases free energy, and proceeds spontaneously.
Endergonic Reaction
Endergonic Reaction
A reaction that absorbs free energy, and is not spontaneous.
Activation Energy
Activation Energy
The initial energy needed to start a chemical reaction.
Free Energy Change (ΔG)
Free Energy Change (ΔG)
Describes whether a reaction occurs spontaneously or not, and releases or requires energy.
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Catalyst
Catalyst
A chemical agent that speeds up a reaction without being consumed.
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Enzyme
Enzyme
A catalytic protein that speeds up reactions.
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Spontaneous Reaction
Spontaneous Reaction
A reaction that occurs without any external input of energy, and proceeds on its own.
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Transition State
Transition State
The intermediate state in a reaction, during which bonds are being broken and formed.
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ATP hydrolysis
ATP hydrolysis
The breakdown of ATP (adenosine triphosphate) into ADP (adenosine diphosphate) and inorganic phosphate, releasing energy.
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Energy Coupling
Energy Coupling
Using the energy released from an exergonic reaction to drive an endergonic reaction.
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Phosphorylation
Phosphorylation
The addition of a phosphate group to a molecule.
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Substrate
Substrate
The reactant that an enzyme acts on.
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Active Site
Active Site
The specific region on an enzyme where the substrate binds.
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Induced Fit
Induced Fit
The change in shape of an enzyme's active site as a substrate binds, improving binding and catalysis.
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Enzyme-substrate complex
Enzyme-substrate complex
The temporary complex formed when an enzyme binds to its substrate.
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Cellular work
Cellular work
The three main types of work performed by cells: chemical, transport, and mechanical.
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Enzyme Saturation
Enzyme Saturation
The point at which all enzyme molecules are active and working at maximum speed.
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Glycolysis
Glycolysis
The breakdown of glucose into two pyruvate molecules.
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Substrate-level phosphorylation
Substrate-level phosphorylation
A small amount of ATP produced directly during glycolysis and the citric acid cycle.
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Oxidative phosphorylation
Oxidative phosphorylation
Process generating most ATP during cellular respiration, powered by redox reactions.
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Pyruvate oxidation
Pyruvate oxidation
Conversion of pyruvate to Acetyl CoA, linking glycolysis to the citric acid cycle.
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Citric Acid Cycle
Citric Acid Cycle
Completes the breakdown of glucose.
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Energy Investment Phase (Glycolysis)
Energy Investment Phase (Glycolysis)
Phase of glycolysis where energy is used to rearrange the glucose molecule.
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Fat Digestion
Fat Digestion
The process of breaking down fats in the gut into absorbable components.
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Energy Payoff Phase (Glycolysis)
Energy Payoff Phase (Glycolysis)
Phase of glycolysis where energy is released, producing ATP and NADH.
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Cellular Respiration
Cellular Respiration
Overall process of harvesting energy from glucose.
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Bile Salts
Bile Salts
Cholesterol-like molecules that break down fat globules, making fats accessible to enzymes.
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Lipase
Lipase
An enzyme that breaks down triglycerides into fatty acids and monoglycerides.
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Chylomicrons
Chylomicrons
Water-soluble particles that transport absorbed fats (triglycerides) from the gut to other tissues.
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Lacteal
Lacteal
Lymphatic vessel in the small intestine villus, absorbing chylomicron-containing lymph.
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Triglycerides
Triglycerides
Major form of fat storage in the body, especially in adipose tissue.
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Fat Absorption
Fat Absorption
Process of absorbing digested fats (fatty acids, monoglycerides) into epithelial cells.
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Adipose Tissue
Adipose Tissue
Tissue that stores triglycerides as fat globules, providing energy reserve.
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Osmosis
Osmosis
The diffusion of water across a selectively permeable membrane from an area of high water concentration to an area of low water concentration.
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Tonicity
Tonicity
The ability of a surrounding solution to cause a cell to gain or lose water.
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Isotonic solution
Isotonic solution
A solution where the solute concentration is the same inside and outside the cell, resulting in no net water movement.
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Hypertonic solution
Hypertonic solution
A solution with a higher solute concentration than inside the cell, causing water to leave the cell.
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Hypotonic solution
Hypotonic solution
A solution with a lower solute concentration than inside the cell, causing water to enter the cell.
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Facilitated Diffusion
Facilitated Diffusion
Passive transport of molecules across a membrane with the help of transport proteins.
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Channel protein
Channel protein
A transport protein that provides a corridor allowing specific molecules or ions to cross the plasma membrane.
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Turgid (plant cell)
Turgid (plant cell)
A plant cell in a hypotonic solution that has swelled until the cell wall resists further water uptake, becoming firm.
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Chlorophyll a
Chlorophyll a
The primary pigment in photosynthesis, absorbing primarily red and blue light, reflecting green light.
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Chlorophyll b
Chlorophyll b
An accessory pigment that absorbs primarily blue and orange light, reflecting green light, slightly different in structure from chlorophyll a.
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Carotenoids
Carotenoids
Accessory pigments that absorb primarily blue and green light, reflecting yellow, orange, and red light. They also function in photoprotection.
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Absorption Spectrum
Absorption Spectrum
A graph showing the wavelengths of light absorbed by a pigment.
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Action Spectrum
Action Spectrum
A graph showing the rate of photosynthesis at different wavelengths of light.
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Photosystem
Photosystem
A complex of proteins and pigments that capture light energy, consisting of a reaction-center complex and light-harvesting complexes.
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Reaction-Center Complex
Reaction-Center Complex
The core of a photosystem, containing special chlorophyll a molecules and a primary electron acceptor, where light energy is converted to chemical energy.
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Light-Harvesting Complex
Light-Harvesting Complex
A part of a photosystem that surrounds the reaction-center complex, containing pigments that absorb light and transfer energy to the reaction center.
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Primary Electron Acceptor
Primary Electron Acceptor
A molecule in the reaction-center complex that receives excited electrons from chlorophyll a, initiating the flow of electrons in photosynthesis.
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What is the difference between absorption and action spectrum?
What is the difference between absorption and action spectrum?
The absorption spectrum shows the wavelengths of light absorbed by pigments, while the action spectrum shows the rate of photosynthesis at different wavelengths. The action spectrum is broader than the absorption spectrum because accessory pigments contribute to photosynthesis.
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Molecules to Cells
- All matter is composed of atoms
- Atoms are composed of subatomic particles (neutrons, protons, electrons)
- Neutrons and protons form the nucleus
- Electrons form a cloud around the nucleus
- Neutron and proton mass are almost identical and measured in daltons
- The periodic table shows electron distribution for each element
- Valence electrons in the outermost shell determine chemical behavior
- Elements with a full valence shell are chemically inert
Chemical Bonds
- Matter is anything that takes up space and has mass
- Atoms sometimes strip electrons from partners forming ions (charged atoms/molecules)
- Covalent bonds are the sharing of valence electrons
- A single covalent bond shares one pair of valence electrons
- A double covalent bond shares two pairs
- Hydrogen bonds form when a hydrogen atom covalently bonded to one electronegative atom draws to another electronegative atom
- Van der Waals interactions are weak attractions between molecules close together due to temporary charges
- Electronegativity is an atom's attraction for the electrons in a covalent bond
Biological Molecules
- Organisms are composed of matter
- All living things are comprised of four classes of large biological molecules: carbohydrates, lipids, proteins, and nucleic acids
- Macromolecules are large molecules consisting of monomers
- Enzymes catalyze chemical reactions
- The shapes of molecules determine function (e.g., enzymes)
Biological Organization
- Life can be studied at varying levels from molecules to the entire living planet
- Hierarchy of organization from molecules to communities to ecosystems
Energy Flow and Chemical Cycling
- Light energy comes from the sun
- Plants convert sunlight to chemical energy
- Organisms use chemical energy to do work
- Chemicals pass to organisms that eat the plants
- Heat is lost from the ecosystem
- Decomposers return chemicals to the soil
The Laws of Energy Transformation
- Thermodynamics is the study of energy transformations
- An open system exchanges energy and matter with surroundings
- A closed system exchanges energy but not matter
- An isolated system exchanges neither
- The first law of thermodynamics states that energy cannot be created or destroyed
- The second law of thermodynamics states that every energy transfer or transformation increases the entropy of the universe
- Entropy measures molecular disorder or randomness
- Free energy is a measure of a system's instability and tendency to change
Chemical reactions and Enzymes
- Chemical reactions are the making and breaking of chemical bonds
- Reactions can be forward to reverse and reach equilibrium (when forward and reverse speeds are equal)
- Enzymes are specialized macromolecules that speed up chemical reactions (catalysts) without being consumed
- Enzymes lower the activation energy (the initial energy needed for a chemical reaction)
- Substrate and active sites: the substrate molecule binds to the active site of the enzyme, fitting precisely lowering activation energy
Cellular Respiration
- Cellular respiration extracts energy from sugars and other fuels
- Chemical energy is converted from one form to another
- Kinetic energy is energy associated with movement
- Thermal energy is kinetic energy due to random movement
- Potential energy is energy that matter possesses because of its location or structure
- Chemical energy is potential energy available for release in a chemical reaction
- Molecules store energy based on chemical bonds
- ATP is the cell's energy shuttle
- ATP is composed of ribose (sugar), adenine (nitrogenous base), and phosphate groups
Photosynthesis
- Chloroplasts capture energy from sunlight
- Photosynthesis converts light energy to chemical energy
- The two stages of photosynthesis are light reactions and the Calvin cycle
Membranes
- Plasma membrane is the boundary that separates the living cell from its surroundings
- Plasma membrane exhibits selective permeability
- Transport proteins are often responsible for controlling passage across the membrane
- Phospholipids are the major component of cell membranes, arranged in a bilayer
- Cholesterol is a component in animal cell membranes
- The plasma membrane is a fluid mosaic of lipids, proteins and carbohydrates
- Many kinds of proteins are embedded in the phospholipid bilayer
Cellular Transport
- Diffusion is the passive movement of molecules across a membrane down a concentration gradient
- Osmosis is the diffusion of water across a selectively permeable membrane
- Active transport uses energy to move substances against their concentration gradients
Endocytosis and Exocytosis
- Endocytosis takes in molecules and matter from outside of the cell
- Exocytosis removes large molecules and matter from inside the cell
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