أسئلة المحاضرة الثانية بيو (قبل التعديل)

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Questions and Answers

What type of acid is D-glucaric acid classified as?

  • Hydroxyl acid
  • Polycarboxylic acid
  • Monocarboxylic acid
  • Aldaric acid (correct)

How many carbon atoms are in D-glucaric acid?

  • 8
  • 5
  • 7
  • 6 (correct)

Which of the following characteristics does D-glucaric acid possess?

  • It is a five-carbon acid.
  • It is insoluble in water.
  • It contains both carbonyl and hydroxyl groups. (correct)
  • It is optically inactive.

From which sugar is D-glucaric acid derived?

<p>D-glucose (B)</p> Signup and view all the answers

What property of D-glucaric acid contributes to its optical activity?

<p>Presence of asymmetric carbon atoms (B)</p> Signup and view all the answers

What is the primary consequence of low levels of lactase enzyme?

<p>Undigested lactose (C)</p> Signup and view all the answers

What process occurs to lactose that fails to be digested due to lactase deficiency?

<p>Bacterial fermentation in the colon (D)</p> Signup and view all the answers

What byproducts are generated as a result of lactose fermentation in the colon?

<p>CO2, H2, and irritating organic acids (C)</p> Signup and view all the answers

What typically results from low levels of lactase in the digestive system?

<p>Bacterial fermentation of undigested lactose (B)</p> Signup and view all the answers

Which of the following is not a result of undigested lactose in the colon?

<p>Increased levels of lactase (B)</p> Signup and view all the answers

What gases are primarily produced due to bacterial fermentation of lactose in individuals with low lactase levels?

<p>Carbon dioxide and hydrogen (A)</p> Signup and view all the answers

What leads to the generation of large amounts of CO2 and H2 in the digestive system?

<p>Bacterial fermentation of undigested lactose (B)</p> Signup and view all the answers

Which of the following symptoms is commonly associated with lactose intolerance?

<p>Abdominal cramps (A)</p> Signup and view all the answers

What is a consequence of the irritating organic acids generated from lactose fermentation in the colon?

<p>Diarrhea (A)</p> Signup and view all the answers

Which best describes the process occurring in the colon due to undigested lactose in individuals with low lactase levels?

<p>Fermentation by bacteria (B)</p> Signup and view all the answers

Which type of glycosidic bond connects two α-glucose molecules?

<p>α 1-4 glycosidic (D)</p> Signup and view all the answers

Which of the following is classified as a reducing sugar?

<p>α-glucose (B)</p> Signup and view all the answers

What is the process used to break down starch in the body?

<p>Hydrolysis by Amylase (A)</p> Signup and view all the answers

Which type of glycosidic bond is found in cellulose?

<p>β 1-4 glycosidic (D)</p> Signup and view all the answers

Which statement concerning dextran is correct?

<p>Dextran contains both α 1-6 and α 1-4 glycosidic bonds. (A)</p> Signup and view all the answers

What defines a painful digestive upset?

<p>Painful digestive upsets (D)</p> Signup and view all the answers

Which of the following is NOT a characteristic commonly associated with disaccharides?

<p>They directly cause lactose intolerance. (C)</p> Signup and view all the answers

Which of the following statements about sugar derivatives is accurate?

<p>They participate in various biochemical reactions. (B)</p> Signup and view all the answers

Which of the following contains both a disaccharide and a sugar derivative?

<p>Cellulose and sucrose (A)</p> Signup and view all the answers

What is a common result of the improper digestion of certain disaccharides?

<p>Painful digestive upsets (D)</p> Signup and view all the answers

What change occurs to the last hydroxyl carbon of D-glucuronic acid?

<p>It is converted to a carboxylic group. (B)</p> Signup and view all the answers

D-glucuronic acid is derived from glucose through which biochemical process?

<p>Oxidation by glucose oxidase enzyme. (C)</p> Signup and view all the answers

Which functional group is present in D-glucuronic acid as a result of the last carbon's transformation?

<p>Carboxylic group. (B)</p> Signup and view all the answers

Which of the following accurately describes the role of glucose oxidase in the formation of D-glucuronic acid?

<p>It facilitates the oxidation of glucose, creating an acid form. (D)</p> Signup and view all the answers

What distinguishes D-glucuronic acid from other sugar derivatives?

<p>It contains a carboxylic acid group derived from glucose. (D)</p> Signup and view all the answers

Which statement accurately describes D-glucaric acid?

<p>It is derived from D-glucose and is both water-soluble and optically active. (D)</p> Signup and view all the answers

Which characteristic is not associated with D-glucaric acid?

<p>It is derived from D-mannose. (C)</p> Signup and view all the answers

Which feature differentiates D-glucaric acid from other dicarboxylic acids?

<p>Its ability to be optically active. (B)</p> Signup and view all the answers

Which structural feature is crucial for the properties of D-glucaric acid?

<p>The combination of both carbonyl and hydroxyl groups. (A)</p> Signup and view all the answers

What role does the hydroxyl carbon play in D-glucaric acid?

<p>It is responsible for the molecule's hydrophilicity. (B)</p> Signup and view all the answers

What is maltose primarily composed of?

<p>2 α-glucose molecules (D)</p> Signup and view all the answers

Which statement correctly describes maltose?

<p>It is formed from the hydrolysis of starch. (B)</p> Signup and view all the answers

Which of the following sugars is not classified as a disaccharide?

<p>Glucose (D)</p> Signup and view all the answers

What alternative name is commonly used for maltose?

<p>Malt sugar (D)</p> Signup and view all the answers

Which structural characteristic is unique to maltose?

<p>Forms through an α-1,4 bond linkage (D)</p> Signup and view all the answers

What distinguishes homodisaccharides from heterodisaccharides?

<p>Homodisaccharides consist of one type of monosaccharide, while heterodisaccharides consist of different types. (B)</p> Signup and view all the answers

Which of the following is an example of a homodisaccharide?

<p>Maltose (B)</p> Signup and view all the answers

What defines heterodisaccharides compared to homodisaccharides?

<p>They can be made from one or more types of monosaccharides. (A)</p> Signup and view all the answers

Which of the following statements about maltose is correct?

<p>Maltose consists of two glucose molecules linked together. (C)</p> Signup and view all the answers

Which of the following best categorizes maltose within the context of saccharides?

<p>It is a homodisaccharide composed of two identical monosaccharides. (D)</p> Signup and view all the answers

Which property distinguishes anomeric carbon from free carbon in sugars?

<p>Anomeric carbon is involved in forming glycosidic bonds. (B)</p> Signup and view all the answers

What characteristic does sucrose possess in relation to its structure?

<p>It is a non-reducing sugar. (B)</p> Signup and view all the answers

Which statement is true regarding the linkage of carbohydrates that involves anomeric carbon?

<p>Linkages involving anomeric carbon are often found in disaccharides. (C)</p> Signup and view all the answers

In carbohydrate chemistry, which factor is critical for the classification of sugars as reducing or non-reducing?

<p>The configuration of the anomeric carbon. (D)</p> Signup and view all the answers

What impact does the presence of anomeric carbon have on carbohydrate functionality?

<p>It allows for greater structural diversity in polysaccharides. (B)</p> Signup and view all the answers

Flashcards

Lactase Deficiency

A condition resulting from the body's insufficient production of lactase, an enzyme required for digesting lactose.

Disaccharide

A sugar molecule composed of two monosaccharide units joined by a glycosidic bond.

Maltose

A type of disaccharide formed by the condensation of two glucose molecules, linked by an α(1→4) glycosidic bond.

Lactose

A type of disaccharide composed of glucose and galactose, linked by a β(1→4) glycosidic bond.

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Cellobiose

A type of disaccharide composed of two glucose molecules, linked by a β(1→4) glycosidic bond.

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Reducing Sugar

A sugar molecule that includes a free aldehyde or ketone group, making it reactive in certain chemical reactions.

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Heterodisaccharide

A sugar molecule composed of two different monosaccharide units.

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Homodisaccharide

A sugar molecule composed of two identical monosaccharide units.

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Starch

A complex carbohydrate that serves as a primary energy source in plants, composed of linear and branched chains of glucose molecules, connected by α(1→4) glycosidic bonds.

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Sucrose

A type of disaccharide formed by the condensation of glucose and fructose, linked by an α(1→β2) glycosidic bond.

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Cellulose

A type of carbohydrate that humans can't digest, due to the β(1→4) glycosidic linkage between glucose molecules, making it resistant to human digestive enzymes.

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Amylase

An enzyme that breaks down starch into smaller molecules like dextrins, maltose, and glucose, aiding in digestion.

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Dextrin

A product of starch breakdown, composed of branched chains of glucose molecules.

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Lactose Intolerance

A condition characterized by the inability to digest lactose due to insufficient lactase enzyme activity.

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Uronic Acid

A sugar acid formed by oxidizing the primary alcohol group of an aldose to a carboxyl group.

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Aldaric Acid

A sugar acid formed by oxidizing both the carbonyl and the last carbon atom of an aldose to carboxylic acid groups.

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Lactose Digestion

The process of breaking down lactose into simpler sugars, catalyzed by the enzyme lactase.

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Starch Degradation

The process of breaking down starch into simpler sugars, catalyzed by the enzyme amylase.

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Aldaric Acid Formation

The process of converting an aldose sugar into an aldaric acid, involving oxidation of both the carbonyl and the last carbon to carboxylic acid groups.

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Uronic Acid Formation

The process of converting an aldose Sugar into a uronic acid, involving oxidation of the primary alcohol group to a carboxylic acid.

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Lactose Fermentation

A condition characterized by the buildup of undigested lactose in the colon, leading to gases, bloating, and discomfort.

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Disaccharide Formation

The process of forming glycosidic bonds between two monosaccharide units, resulting in a disaccharide.

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Lactase Activity

The process of breaking down lactose into simpler sugars, catalyzed by the enzyme lactase.

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Amylase Activity

The process of breaking down starch into simpler sugars, catalyzed by the enzyme amylase.

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Aldaric Acid Oxidation

The process of converting an aldose sugar into an aldaric acid, involving oxidation of both the carbonyl and the last carbon to carboxylic acid groups.

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Uronic Acid Oxidation

The process of converting an aldose Sugar into a uronic acid, involving oxidation of the primary alcohol group to a carboxylic acid.

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Study Notes

Lactose Intolerance

  • Low lactase enzyme activity leads to undigested lactose
  • Undigested lactose ferments in the colon
  • Fermentation produces large amounts of CO2, H2, and irritable organic acids
  • These gases and acids cause abdominal cramps and diarrhea

Aldaric Acids

  • Aldaric acids contain both a carbonyl group and a hydroxyl group on the last carbon
  • D-glucaric acid is an example of an aldaric acid derived from D-glucose
  • Aldaric acids are 6-carbon sugar acids
  • They are water soluble and optically active

Disaccharides

  • Disaccharides are formed by the condensation of two monosaccharides
  • Common disaccharides:
    • Maltose: α 1-4 glycosidic bond between two α-glucose molecules
    • Cellobiose: β 1-4 glycosidic bond between two β-glucose molecules
    • Lactose: β 1-4 glycosidic bond between α-glucose and β-galactose
    • Sucrose: α 1-β 2 glycosidic bond between α-glucose and β-fructose

Reducing Sugars

  • Reducing sugars have a free anomeric carbon
  • They can reduce other compounds by donating electrons
  • Maltose, lactose, and cellobiose are reducing sugars
  • Sucrose is a non-reducing sugar

Starch Degradation

  • Starch is a polymer of glucose
  • Amylase hydrolyzes starch into dextrins, maltose, and glucose
  • Dextrins are branched polymers of glucose
  • Cellulose is a linear polymer of glucose with β 1-4 glycosidic bonds
  • Cellulose is not digestible by humans

Lactase Deficiency

  • Lactase deficiency leads to lactose intolerance
  • Symptoms include abdominal cramps, diarrhea, and gas
  • It occurs when the body does not produce enough lactase, an enzyme that digests lactose
  • Lactose intolerance is a common condition, particularly in adults

Uronic Acids

  • Formed when the primary alcohol of an aldose is oxidized to a carboxylic acid
  • Example: D-glucuronic acid from glucose
  • Water soluble and optically active

Aldaric Acids

  • Dicarboxylic acids
  • Both the carbonyl and the last carbon atom of an aldose are oxidized to carboxylic acid groups.
  • Example: D-glucaric acid from D-glucose

Disaccharides

  • Formed by the reaction of two monosaccharides
  • Joined by a glycosidic bond
  • Can be homodisaccharides or heterodisaccharides
  • Homodisaccharides are composed of the same monosaccharide units
  • Heterodisaccharides are composed of different monosaccharide units

Maltose

  • Has the other name "Malt sugar"
  • Is a homodisaccharide composed of two α-glucose molecules linked by an α(1→4) glycosidic bond
  • Important as a component of maltose syrup.

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