Atoms and Molecules Overview

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Questions and Answers

What key distinction did scientists recognize by the end of the eighteenth century?

Scientists recognized the difference between elements and compounds.

What two important laws of chemical combination did Antoine Lavoisier establish?

The law of conservation of mass and the law of definite proportions.

Explain the law of conservation of mass.

The law of conservation of mass states that mass can neither be created nor destroyed in a chemical reaction.

Why is it important to weigh the flask before and after mixing solutions X and Y?

<p>It demonstrates the law of conservation of mass by showing that mass remains constant.</p> Signup and view all the answers

What happens when solutions X and Y are mixed, according to the context provided?

<p>A chemical reaction occurs when the solutions are mixed.</p> Signup and view all the answers

Why should a cork be placed on the mouth of the flask during the experiment?

<p>The cork prevents the escape of gases that may be produced during the reaction.</p> Signup and view all the answers

Who was John Dalton and what was his contribution to chemistry?

<p>John Dalton was a scientist who presented the atomic theory in 1808, which was a turning point in the study of matter.</p> Signup and view all the answers

What does the law of definite proportions entail?

<p>The law of definite proportions states that a chemical compound contains its constituent elements in fixed ratios by mass.</p> Signup and view all the answers

What is the ratio of the mass of hydrogen to the mass of oxygen in water according to Dalton's atomic theory?

<p>The ratio is always 1:8.</p> Signup and view all the answers

According to Dalton's atomic theory, how are atoms characterized in terms of their properties?

<p>Atoms of a given element are identical in mass and chemical properties.</p> Signup and view all the answers

What implication does Dalton's postulate that 'atoms cannot be created or destroyed' have in chemical reactions?

<p>It implies that during chemical reactions, the total number of atoms remains constant.</p> Signup and view all the answers

In ammonia, what is the ratio of nitrogen to hydrogen by mass?

<p>The ratio is always 14:3.</p> Signup and view all the answers

What are the smallest particles that compose all matter according to Dalton's theory?

<p>Atoms are the smallest particles that compose all matter.</p> Signup and view all the answers

What did Dalton contribute to the understanding of the divisibility of matter?

<p>Dalton established that matter consists of indivisible particles called atoms.</p> Signup and view all the answers

What does it mean when it is stated that 'atoms combine in the ratio of small whole numbers'?

<p>It means that atoms bond in specific ratios to form compounds.</p> Signup and view all the answers

What is the atomicity of oxygen in a diatomic molecule?

<p>The atomicity of oxygen in a diatomic molecule is 2.</p> Signup and view all the answers

How many atoms of hydrogen are present in a water molecule?

<p>There are 2 atoms of hydrogen in a water molecule.</p> Signup and view all the answers

What is an anion?

<p>An anion is a negatively charged ion.</p> Signup and view all the answers

What role do ions play in compounds composed of metals and non-metals?

<p>Ions form charged species that are essential for creating ionic compounds.</p> Signup and view all the answers

What is the atomicity of phosphorus?

<p>The atomicity of phosphorus is tetra-atomic, meaning it has 4 atoms.</p> Signup and view all the answers

What elements are involved in the formation of sodium chloride (NaCl)?

<p>Sodium (Na) and chlorine (Cl) are the elements involved in the formation of sodium chloride.</p> Signup and view all the answers

What is the simplest ratio of atoms in a molecule of water?

<p>The simplest ratio of atoms in a water molecule is 2:1 for hydrogen to oxygen.</p> Signup and view all the answers

Identify the atomicity and type of helium as an element.

<p>Helium has a monoatomic atomicity, meaning it consists of 1 atom.</p> Signup and view all the answers

What is the significance of the atomic mass unit in the context of carbon and oxygen?

<p>The atomic mass unit is defined as the mass of one carbon atom, allowing us to compare the masses of other elements, like assigning oxygen an atomic mass of 1.33 u.</p> Signup and view all the answers

Why are some element symbols derived from Latin or other languages?

<p>Some element symbols are derived from Latin, German, or Greek to maintain historical significance and consistency in chemical notation.</p> Signup and view all the answers

How does the mass of carbon compare to the mass of oxygen in the formation of carbon monoxide?

<p>In the formation of carbon monoxide, 3 g of carbon combines with 4 g of oxygen, resulting in the ratio of 4/3 times the mass of carbon.</p> Signup and view all the answers

What unique properties do element symbols provide in chemistry?

<p>Element symbols provide a standardized way to represent chemical elements, making it easier to communicate chemical formulas and reactions.</p> Signup and view all the answers

Give two examples of elements whose symbols are derived from their Latin names.

<p>Iron (Fe from ferrum) and sodium (Na from natrium) are two examples where symbols are derived from Latin names.</p> Signup and view all the answers

What is the relationship between carbon's atomic mass and oxygen's atomic mass in the given context?

<p>Carbon is assigned an atomic mass of 1.0 u, while oxygen is given an atomic mass of approximately 1.33 u, indicating oxygen's heavier weight relative to carbon.</p> Signup and view all the answers

Why is it more convenient to use whole numbers or values close to whole numbers for atomic masses?

<p>Using whole numbers or values near whole numbers simplifies calculations and enhances comprehension in stoichiometric equations.</p> Signup and view all the answers

What is the chemical formula for carbon monoxide, and what elements does it consist of?

<p>The chemical formula for carbon monoxide is CO, consisting of one carbon atom and one oxygen atom.</p> Signup and view all the answers

What is the formula unit mass of sodium oxide (Na2O)?

<p>61.98 u</p> Signup and view all the answers

What is the formula unit mass of aluminium chloride (AlCl3)?

<p>133.33 u</p> Signup and view all the answers

Calculate the formula unit mass of sodium sulfide (Na2S).

<p>78.04 u</p> Signup and view all the answers

What is the formula unit mass of magnesium hydroxide (Mg(OH)2)?

<p>58.33 u</p> Signup and view all the answers

Identify the formula unit mass of zinc oxide (ZnO).

<p>81.38 u</p> Signup and view all the answers

What is the formula unit mass of potassium carbonate (K2CO3)?

<p>138.21 u</p> Signup and view all the answers

Calculate the molecular mass of carbon dioxide (CO2).

<p>44.01 u</p> Signup and view all the answers

What is the molecular mass of methane (CH4)?

<p>16.04 u</p> Signup and view all the answers

What is the relationship between atomic mass and gram atomic mass, specifically for hydrogen?

<p>The atomic mass of hydrogen is 1 u, and the gram atomic mass is 1 g, which means that 1 g of hydrogen contains 1 mole of hydrogen atoms.</p> Signup and view all the answers

How can one derive the number of moles from a given mass of a substance?

<p>The number of moles can be calculated using the formula $n = \frac{\text{given mass}}{\text{molar mass}}$.</p> Signup and view all the answers

What is the significance of Avogadro's number in the context of moles?

<p>Avogadro's number, $6.022 \times 10^{23}$, represents the number of particles (atoms or molecules) in one mole of a substance.</p> Signup and view all the answers

Explain how the conversion from atomic mass to gram molecular mass is achieved in molecules like water.

<p>To convert from atomic mass to gram molecular mass, the numerical value remains the same but the unit changes from u to g; for water, 18 u becomes 18 g.</p> Signup and view all the answers

How does the molar mass of oxygen relate to its atomic mass?

<p>The molar mass of oxygen is 16 g, which corresponds to its atomic mass of 16 u, meaning 16 g contains one mole of oxygen atoms.</p> Signup and view all the answers

Flashcards

Law of Conservation of Mass

Mass is neither created nor destroyed in a chemical reaction.

Chemical Reaction

A process where substances rearrange to form new substances.

Law of Constant Proportions

Elements combine in fixed ratios by mass in a chemical compound.

Elements

Fundamental substances that cannot be broken down further.

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Compounds

Substances formed by the chemical combination of two or more elements.

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Antoine Lavoisier

Scientist who established laws of chemical combination

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John Dalton

Scientist who proposed the atomic theory.

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Atomic Theory

Theory proposing that matter is made up of tiny, indivisible particles called atoms.

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Dalton's Atomic Theory

A theory proposing that all matter is composed of extremely small, indivisible particles called atoms.

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Atoms

Tiny particles that make up all matter (elements, compounds, and mixtures).

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Indivisible particles

Atoms cannot be created or destroyed in a chemical reaction.

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Water composition

Water always contains hydrogen and oxygen in a 1:8 mass ratio, regardless of the source.

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Elements in compounds

Elements in a compound combine in fixed proportions by mass.

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Ammonia composition

Ammonia has nitrogen and hydrogen in a 14:3 mass ratio.

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Atomic theory postulates

Six statements that describe the basic ideas behind Dalton's atomic theory.

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Molecule

A group of two or more atoms bonded together, forming a distinct unit.

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Atomicity

The number of atoms present in a molecule of an element.

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Monoatomic

An element that exists as single atoms.

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Diatomic

An element that exists as two atoms bonded together.

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Polyatomic

An element that exists as more than two atoms bonded together.

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Ionic Compound

A compound formed by the electrostatic attraction between oppositely charged ions.

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Anion

A negatively charged ion.

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Cation

A positively charged ion.

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Atomic Mass Unit (amu)

A unit of mass defined as 1/12th the mass of a carbon-12 atom. It is used to express the masses of atoms and molecules.

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Unified Mass (u)

The current standard unit for atomic mass, replacing the older ‘amu’. It is equal to the mass of one atom of carbon-12.

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Chemical Symbol

A one or two-letter abbreviation that represents an element. The first letter is always capitalized.

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Carbon Monoxide (CO)

A compound formed by the chemical combination of carbon and oxygen in a fixed ratio of 3 g carbon to 4 g oxygen.

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Atomic Mass of Carbon

If we define the atomic mass unit as the mass of one carbon atom, then the atomic mass of carbon is 1.0 u.

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Atomic Mass of Oxygen

In the CO molecule, the atomic mass of oxygen would be 1.33 u, assuming carbon's atomic mass is 1 u.

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Why use whole numbers for atomic mass?

It is convenient to express atomic masses as whole numbers or nearly whole numbers to simplify calculations and comparisons.

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Elements and Symbols

Elements are pure substances that cannot be broken down further. They have unique names and chemical symbols.

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Gram Atomic Mass

The mass of one mole of atoms of an element expressed in grams. It is numerically equal to the atomic mass in atomic mass units (u).

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Molar Mass

The mass of one mole of a substance (atom or molecule) expressed in grams. For a molecule, it's numerically equal to the molecular mass in atomic mass units (u)

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Mole

A unit of amount of substance. One mole contains 6.022 × 10^23 particles (atoms or molecules).

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Avogadro's Number

The number of particles (atoms or molecules) in one mole of a substance, equal to 6.022 × 10^23

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Formula Unit Mass

The sum of atomic masses of all atoms in a formula unit of a compound. It's calculated like molecular mass but used for ionic compounds.

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Formula Unit

The smallest unit of an ionic compound that represents its composition.

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What is the formula unit mass of NaCl?

The formula unit mass of NaCl is 58.5 u. It is calculated by adding the atomic masses of sodium (Na) and chlorine (Cl): 23 u + 35.5 u = 58.5 u.

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Mole Concept

A way to express the quantity of a substance in terms of the number of its molecules or atoms, rather than their masses. It allows us to understand the ratios of reactants and products in a chemical reaction.

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What is the significance of the chemical reaction 2H2 + O2 → 2H2O?

This equation shows that two molecules of hydrogen (2H2) react with one molecule of oxygen (O2) to produce two molecules of water (2H2O). This illustrates the mole concept, where the coefficients represent the relative number of molecules involved in the reaction.

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How does the mole concept relate to chemical reactions?

The mole concept helps us understand the proportions of reactants and products in a chemical reaction. It allows us to predict how much of a product will be formed based on the amount of reactants used.

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What is the difference between molecular mass and formula unit mass?

Molecular mass refers to the mass of a molecule, which is a neutral group of atoms held together by covalent bonds. Formula unit mass refers to the mass of a formula unit, which is the smallest unit of an ionic compound, consisting of ions held together by electrostatic forces.

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Why is the mole concept a more convenient way to express the quantity of a substance than mass?

The mole concept provides a direct measure of the number of molecules or atoms involved in a chemical reaction. This makes it easier to understand the stoichiometry of the reaction and predict the amounts of products formed.

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Study Notes

Atoms and Molecules

  • Ancient Indian and Greek philosophers pondered the unseen form of matter and its divisibility.
  • An Indian philosopher (Maharishi Kanad) proposed that matter could be divided into smaller and smaller particles (Parmanu).
  • Another Indian philosopher (Pakudha Katyayama) elaborated this idea, suggesting particles exist in combined forms.
  • Ancient Greek philosophers (Democritus and Leucippus) proposed the idea of indivisible particles (atoms).
  • Antoine Lavoisier established the law of conservation of mass.
  • This law states that mass is neither created nor destroyed in a chemical reaction.
  • Lavoisier and Joseph Proust also established the law of constant proportions.
  • This law states that elements in a compound are always present in definite proportions by mass.
  • John Dalton developed an atomic theory explaining the conservation of mass and constant proportions.
  • Dalton's atomic theory proposes that all matter is made up of atoms, atoms are indivisible and cannot be created or destroyed in a chemical reaction, atoms of the same element have identical mass and chemical properties, atoms of different elements have different masses and chemical properties, atoms combine in small whole number ratios to form compounds, and atoms are constant in a given compound.
  • Dalton's theory was based on experiments and the laws of chemical combination.
  • Atoms are extremely small, often measured in nanometres.
  • Modern atomic symbols use one or two letters.
  • The first letter is always capitalized, and any subsequent are lowercase.
  • Dalton's atomic theory proposed the concept of atomic mass.
  • Atomic mass is determined by comparing an atom's mass to the mass of a reference atom (carbon-12).
  • Atomic mass units (u) are used for atomic mass.
  • Atoms exist as molecules and ions.

Molecules

  • Molecules are groups of two or more atoms bonded together.
  • A molecule is the smallest particle of an element that exists independently and reflects all the properties of the element.
  • Molecules are made of the same type of atoms in an element or of different types of atoms in a compound.
  • Atomicity is the number of atoms in a molecule.
  • Molecules of some elements (e.g. argon, helium) are monoatomic.
  • Molecules of other elements (e.g. oxygen, hydrogen, nitrogen) are diatomic.
  • Some elements (e.g. phosphorus, sulphur) can be polyatomic.
  • Molecules of compounds consist of different types of atoms present in definite proportion.
  • Compounds have a specified ratio by mass.

Molecular mass

  • It is the sum of the atomic masses of all the atoms in a molecule.
  • Molecular mass is expressed in atomic mass units (amu). This value is often the same numerical value as the molecular mass in grams (the molar mass.)

Mole Concept:

  • A mole represents 6.022 × 10²³ atoms or molecules in a substance.
  • One mole of a substance has a mass equal to its relative atomic mass, expressed in grams (gram atomic mass), relative molecular mass (gram molecular mass) or relative formula mass (gram formula units).

Chemical Formulae

  • Chemical formulae used to represent the composition of compounds and molecules.
  • Valency (combining power) helps establish a chemical formula.
  • Chemical formulae are usually consistent with the laws of conservation of mass and constant proportions.

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