Atomic Theory: Scientists & Models

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Questions and Answers

Democritus' atomic theory, while foundational, lacked a key element crucial to modern scientific theories. What was this missing element?

  • A defined concept of elements and compounds.
  • Experimental evidence to support its claims. (correct)
  • The concept of electrons and their role in chemical bonding.
  • Mathematical equations to predict atomic behavior.

Dalton's Atomic Theory included several postulates that revolutionized the understanding of matter. Which of the following statements accurately reflects one of Dalton's key postulates?

  • Atoms combine in variable ratios to form compounds, depending on reaction conditions.
  • Atoms of different elements can be transformed into each other during chemical reactions.
  • Atoms are divisible and composed of subatomic particles.
  • Atoms of the same element have identical masses and properties. (correct)

J.J. Thomson's Cathode Ray Tube experiment was pivotal in disproving a key tenet of Dalton's Atomic Theory. Which statement best describes how Thomson's work challenged Dalton's model?

  • It confirmed the existence of a dense, positively charged nucleus.
  • It proved that all atoms of the same element are identical.
  • It showed that atoms combine in simple, whole-number ratios.
  • It demonstrated that atoms could be split into smaller, charged particles. (correct)

Rutherford's Gold Foil experiment led to a revolutionary model of the atom. What key observation from this experiment was most influential in concluding that atoms have a small, dense, positively charged nucleus?

<p>Some alpha particles were deflected at large angles. (C)</p> Signup and view all the answers

While Rutherford's model was a significant advancement, it failed to explain certain phenomena related to electron behavior. What key question remained unanswered by the Nuclear Model?

<p>Why electrons do not collapse into the nucleus due to electrostatic attraction. (C)</p> Signup and view all the answers

Bohr's model introduced the concept of quantized energy levels for electrons. How did this concept explain the discrete spectral lines observed in hydrogen's emission spectrum?

<p>Electrons can only absorb or emit energy in specific amounts when transitioning between energy levels. (B)</p> Signup and view all the answers

Chadwick's discovery of the neutron resolved a crucial discrepancy in atomic masses. Which of the following best describes the problem Chadwick addressed?

<p>The observed mass of atoms was greater than the mass predicted by the number of protons. (D)</p> Signup and view all the answers

Each atomic model contributed to a more complete understanding of atomic structure. Considering the progression from Dalton to Chadwick, what is a major conceptual difference between Dalton's model and Chadwick's model?

<p>Dalton's model considered atoms indivisible, while Chadwick's model included subatomic particles. (A)</p> Signup and view all the answers

The Gold Foil experiment provided evidence that most of the atom is empty space. If alpha particles were fired at a screen of tightly packed bowling balls, what result would disprove the conclusion of the Gold Foil experiment?

<p>All alpha particles pass through the bowling balls without changing direction. (D)</p> Signup and view all the answers

Both Thomson and Rutherford proposed models involving charged particles within the atom. What is the most significant difference between their models' arrangement of positive and negative charges?

<p>Thomson proposed electrons embedded in a positive medium, while Rutherford proposed a central positive nucleus with orbiting electrons. (D)</p> Signup and view all the answers

Bohr's model accounted for the specific wavelengths of light emitted by excited hydrogen atoms. If an atom had 4 possible electron orbits, how many potential wavelengths of light could it emit?

<p>6 (B)</p> Signup and view all the answers

Chadwick's discovery of the neutron had implications beyond just correcting atomic mass calculations. Which of the following was a DIRECT consequence of this discovery?

<p>The groundwork for nuclear physics and understanding nuclear stability. (A)</p> Signup and view all the answers

Consider the historical progression of atomic models. What fundamental assumption, present in Dalton's model, was challenged by BOTH Thomson's and Rutherford's experiments?

<p>Atoms are indivisible. (C)</p> Signup and view all the answers

Suppose you are asked to design a new experiment that would test a prediction made by Bohr's model, but not by Rutherford's. What is one hypothesis of Bohr's model that is NOT present in Rutherford's?

<p>Observing the wavelength of light emitted when electrons transition between energy levels. (A)</p> Signup and view all the answers

If an element was discovered that emitted a continuous spectrum of light (all wavelengths), which statement would reflect the theoretical implications of that discovery?

<p>It disproves Bohr's theory that electrons exist at specific energy levels. (B)</p> Signup and view all the answers

Imagine performing the Gold Foil experiment using a radioactive material that emits only electrons instead of alpha particles. What result would be MOST likely?

<p>The electrons would be scattered at a wide range of angles. (D)</p> Signup and view all the answers

How did Chadwick's discovery explain the existence of isotopes (atoms of the same element with different masses)?

<p>Isotopes have a different number of neutrons. (C)</p> Signup and view all the answers

If Rutherford had used a thicker gold foil in his experiment, how might the results and his subsequent conclusions be different?

<p>More alpha particles would have been deflected or absorbed, potentially obscuring the observation of large-angle deflections. (D)</p> Signup and view all the answers

Consider a hypothetical element which, when heated, emits only two distinct wavelengths of light. Based on Bohr's model, what can you infer about that element?

<p>Its electrons can only occupy three distinct energy levels. (B)</p> Signup and view all the answers

How would the observed behavior of electrons in Thomson's Plum Pudding model differ from that in Rutherford's Nuclear model if an external electric field were applied?

<p>In Thomson's model, electrons drift with the 'pudding' while in Rutherford's model, electrons' orbits would be distorted. (A)</p> Signup and view all the answers

Flashcards

Democritus' Atomic Theory

Proposed atoms are indivisible particles called 'atomos,' differing in size, shape, and motion. Changes in matter result from rearrangement of atoms.

Dalton's Atomic Theory

Atoms of the same element are identical. Atoms combine in whole-number ratios. Atoms cannot be created or destroyed.

Thomson's Plum Pudding Model

Atoms consist of negatively charged electrons embedded in a positively charged cloud.

Rutherford's Nuclear Model

Atoms have a small, dense, positively charged nucleus containing protons. Most of the atom is empty space.

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Bohr's Planetary Model

Electrons orbit the nucleus in fixed energy levels. Electrons jump between levels by absorbing or emitting photons.

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Chadwick's Discovery of Neutrons

Neutral particles, called neutrons, exist within the nucleus alongside protons, explaining atomic mass discrepancies.

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Study Notes

  • Outlined are the key scientists and their models that contributed to the development of the atomic theory

Democritus (c. 460 – 370 BC)

  • Proposed the concept of "atomos," small, indivisible particles as the fundamental component of all matter.
  • Matter transformation arises from atoms rearranging, not from their destruction.
  • Atoms are considered eternal, indestructible, and vary in size, shape, and motion.
  • His theory lacked experimental backing, and was purely philosophical, relying on logical reasoning.
  • Developed the Indivisible Solid Atom (Billiard Ball Model)

John Dalton (1803)

  • Developed the Solid Sphere Model to describe the observations from his experiments.
  • Atoms of different elements possess different masses, while atoms of the same element share identical mass and properties.
  • Matter consists of indivisible atoms.
  • Atoms combine in fixed, whole-number ratios to form compounds, as described by the Law of Multiple Proportions.
  • Chemical reactions involve rearranging atoms, and atoms cannot be created or destroyed which aligns with the Law of Conservation of Mass.
  • Provided experimental support for his atomic theory through chemical reactions and gas laws.

J.J. Thomson (1897)

  • Introduced the Plum Pudding Model of the atom.
  • Atoms are not indivisible, demonstrated by the discovery of electrons.
  • The atom consists of negatively charged electrons within a positively charged "pudding" or cloud.
  • Conducted the Cathode Ray Tube Experiment and observed the deflection of negatively charged particles (electrons).
  • The model could not account for atomic stability or the nucleus.

Ernest Rutherford (1911)

  • Introduced the Nuclear Model of the atom.
  • Atoms feature a small, dense, positively charged nucleus comprised of protons.
  • Most of the atom is empty space where electrons move around the nucleus.
  • Conducted the Gold Foil Experiment, observing deflections of alpha particles when directed at a thin gold sheet.
  • The nuclear model supplanted Thomson’s Plum Pudding Model.
  • The model did not explain electron arrangement or why electrons do not collapse into the nucleus.

Niels Bohr (1913)

  • Studied hydrogen emission spectra to find that electrons only absorb/emit energy at set frequencies.
  • Proposed electrons orbit the nucleus in fixed energy levels (quantized orbits).
  • Explained spectral lines in hydrogen, but it was not as successful for more complex atoms.
  • Proposed the Planetary Model.
  • Electrons can transition between energy levels by absorbing or emitting photons of specific energies.

James Chadwick (1932)

  • Introduced the Quantum Mechanical Model (with Neutrons)
  • Conducted the Beryllium Experiment by bombarding beryllium with alpha particles, which led to the detection of neutron radiation.
  • Concluded that neutrons, neutral particles, exist in the nucleus alongside protons.
  • Neutrons account for atomic mass discrepancies and contribute to nuclear stability.
  • Discovery of the neutron paved the way for advancements in nuclear physics and quantum mechanics.

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