Atomic Theory and Radioactivity
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Questions and Answers

How did Dalton's atomic theory differ significantly from Democritus's earlier proposal about atoms?

  • Dalton's theory was based on experimental evidence, whereas Democritus's was based on philosophical reasoning. (correct)
  • Dalton's theory proposed that atoms were indivisible, while Democritus suggested they could be further divided.
  • Dalton's theory included the concept of electrons, which was absent in Democritus's proposal.
  • Dalton's theory stated all atoms are the same, while Democritus stated all atoms are different.

Which of the following discoveries directly contradicted Dalton's initial atomic theory?

  • The plum pudding model proposed by J.J. Thomson.
  • The gold foil experiment conducted by Ernest Rutherford.
  • The discovery of radioactivity by Henri Becquerel. (correct)
  • The development of lab procedures during the time of alchemy.

J.J. Thomson's plum pudding model was a step forward in understanding atomic structure because it:

  • introduced the concept of orbiting electrons.
  • correctly identified the nucleus and the electron.
  • indicated the arrangement of positive and negative charges within the atom. (correct)
  • described the atom as a uniform, solid entity.

How did Rutherford's gold foil experiment change the understanding of atomic structure?

<p>It suggested that the positive charge was concentrated in a small nucleus. (A)</p> Signup and view all the answers

If an element emits beta particles, what can be inferred about the composition of its atoms based on the discoveries of Becquerel and Thomson?

<p>The atoms of the element contain negatively charged particles that can be emitted. (C)</p> Signup and view all the answers

According to Bohr's model, what happens to an electron when it is in a stationary state?

<p>It remains in its energy level without radiating or absorbing energy. (D)</p> Signup and view all the answers

Which of the following best describes the relationship between energy and wavelength in the electromagnetic spectrum?

<p>Energy and wavelength are inversely proportional; higher energy corresponds to shorter wavelengths. (C)</p> Signup and view all the answers

What is a primary limitation of the Bohr model of the atom?

<p>It can only accurately predict the spectra for single-electron systems. (B)</p> Signup and view all the answers

In the context of the Bohr model, what causes the emission of a photon with a specific wavelength?

<p>An electron transitioning from a higher energy level to a lower energy level. (D)</p> Signup and view all the answers

Why does electrostatic repulsion not cause the nucleus to break apart?

<p>Because the strong nuclear force counteracts electrostatic repulsion. (D)</p> Signup and view all the answers

If an electron transitions from the n=3 energy level to the n=2 energy level in a hydrogen atom, what type of electromagnetic radiation is emitted?

<p>Visible light (C)</p> Signup and view all the answers

Which color of visible light has the lowest energy and longest wavelength?

<p>Red (D)</p> Signup and view all the answers

How did Bohr's model address the instability issue presented by Rutherford's model?

<p>By suggesting that electrons exist only in specific, quantized energy levels where they do not radiate energy. (B)</p> Signup and view all the answers

Flashcards

Democritus' Atom

Proposed that matter is made of tiny individual particles called atoms.

John Dalton's Postulates

Five foundational principles defining atomic theory, including the identity and combination of atoms.

Types of Radiation

Henri Becquerel identified three types: Alpha (α), Beta (β), and Gamma (γ).

J.J. Thompson's Model

Proposed the 'plum pudding' model where electrons are embedded in a positively charged sphere.

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Rutherford's Nuclear Model

Described the atom with a dense nucleus and electrons orbiting it, discovered from the gold foil experiment.

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Bohr's Model

Describes electrons moving in circular orbits at specific energy levels.

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Bright line spectrum

Specific colors emitted by elements, visible in their line spectrum.

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Electromagnetic Spectrum

Range of visible and invisible electromagnetic energy.

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Orbiting Electron Energy Loss

Charged electrons lose energy and may fall into the nucleus.

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Bohr's First Postulate

Electrons exist only in specific circular orbits.

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Energy Levels Jump

Electrons transition between energy levels by absorbing energy.

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Energy and Wavelength Relationship

Energy is inversely proportional to wavelength (E = hc/λ).

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Limitations of Bohr Model

Could only explain single-electron systems, not multielectron systems.

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Study Notes

Atomic Theory Development

  • Democritus (400 BC): Proposed matter was composed of tiny particles called atoms, but his theory lacked experimental evidence. He coined the Greek term "atomos."

  • Alchemy (2000 years): Focus on transforming substances, such as trying to turn base metals into gold. Developed lab procedures but didn't fully understand atomic structure.

  • John Dalton (1805): A British schoolteacher who developed an atomic theory based on experimental data. Proposed the following postulates:

  • Elements are composed of tiny indivisible particles called atoms.

  • Atoms of the same element are identical, but atoms of different elements are different.

  • Atoms combine in simple whole-number ratios to form compounds.

  • Atoms are neither created nor destroyed in chemical reactions – they are rearranged.

Radioactivity and Subatomic Particles

  • Henri Becquerel (1896): Discovered radioactivity, the emission of energy from certain elements. Identified three types of radioactive emissions:
  • Alpha (α): Positively charged
  • Beta (β): Negatively charged
  • Gamma (γ): Neutral

Plum Pudding Model

  • J.J. Thomson (1897): Discovered the electron, a negatively charged subatomic particle. Proposed a "plum pudding" model of the atom: a positively charged sphere with negatively charged electrons embedded within it, like plums in pudding.

Nuclear Model

  • Ernest Rutherford (1911): Conducted the gold foil experiment, which demonstrated that the atom's mass and positive charge are concentrated in a small dense nucleus. Proposed a nuclear model of the atom: a dense, positively charged nucleus surrounded by negatively charged electrons. He discovered protons.

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Description

This lesson covers the development of atomic theory, from Democritus to John Dalton, including the contributions of alchemy. It also introduces the discovery of radioactivity by Henri Becquerel and the concept of subatomic particles. Key figures and their postulates are highlighted.

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