Atomic Structure and Quantum Numbers

Choose a study mode

Play Quiz
Study Flashcards
Spaced Repetition
Chat to Lesson

Podcast

Play an AI-generated podcast conversation about this lesson
Download our mobile app to listen on the go
Get App

Questions and Answers

Which subatomic particle has a positive charge?

  • Electron
  • Positron
  • Proton (correct)
  • Neutron

What is the approximate mass of a neutron?

  • 0.00055 u
  • 0 u
  • 1.0073 u
  • 1.0087 u (correct)

Which scientist's findings first hinted that atoms contained smaller particles?

  • William Crookes
  • Michael Faraday (correct)
  • Roentgen
  • Eugen Goldstein

What type of ray did William Crookes study in gas discharge tubes?

<p>Cathode rays (D)</p> Signup and view all the answers

What is the charge of an electron?

<p>-1 (B)</p> Signup and view all the answers

What is the atomic number of Hydrogen (H)?

<p>1 (A)</p> Signup and view all the answers

What does relative atomic mass take into account?

<p>The percentage abundance of isotopes. (D)</p> Signup and view all the answers

What instrument is used to determine the types of isotopes present in an element?

<p>Mass spectrometer (A)</p> Signup and view all the answers

What does the principal quantum number (n) primarily determine?

<p>Orbital size and energy level (B)</p> Signup and view all the answers

What are the allowed values for the principal quantum number (n)?

<p>Positive integers (C)</p> Signup and view all the answers

Which quantum number describes the shape of an orbital?

<p>Secondary quantum number (C)</p> Signup and view all the answers

What shape is associated with an 's' orbital?

<p>Spherical (A)</p> Signup and view all the answers

What does the magnetic quantum number specify?

<p>Orbital orientation (C)</p> Signup and view all the answers

What values are allowed for the spin quantum number?

<p>+1/2 and -1/2 (B)</p> Signup and view all the answers

If an atom has the quantum numbers n=4 and l=3, which sublevel is described?

<p>4f (D)</p> Signup and view all the answers

What does the magnetic quantum number do to the subshells?

<p>It splits the subshells into individual orbitals (D)</p> Signup and view all the answers

What is the subshell with the quantum numbers n=4, l=2?

<p>4d (C)</p> Signup and view all the answers

What are the magnetic quantum number values for a d orbital?

<p>-2, -1, 0, +1, +2 (A)</p> Signup and view all the answers

What are the allowed values of l for the shell with n=2?

<p>0, 1 (A)</p> Signup and view all the answers

How many electrons can inhabit all of the n=4 orbitals?

<p>32 (D)</p> Signup and view all the answers

What principle states that electrons occupy the lowest-energy orbitals available in the ground state of an atom?

<p>Aufbau principle (C)</p> Signup and view all the answers

Which principle states that no two identical fermions can occupy the same quantum state simultaneously?

<p>Pauli exclusion principle (B)</p> Signup and view all the answers

What rule states that electrons will first fill each orbital with one electron before pairing up in any orbital, leading to the maximum total spin?

<p>Hund’s rule (D)</p> Signup and view all the answers

If an element has an atomic number of 20 and an atomic mass of 40, how many neutrons are present in the nucleus?

<p>20 (D)</p> Signup and view all the answers

Which of the following arranges the subatomic particles in order of increasing mass?

<p>electron &lt; proton &lt; neutron (A)</p> Signup and view all the answers

An atom of an element contains 17 protons, 18 neutrons, and 17 electrons. Which of the following statements is true?

<p>The element is neutral. (B)</p> Signup and view all the answers

Which of the following is true for isotopes of the same element?

<p>They have the same number of protons but different numbers of neutrons. (A)</p> Signup and view all the answers

Which of the following describes isobars?

<p>Atoms with the same mass number but different atomic numbers. (A)</p> Signup and view all the answers

Consider a sample of oxygen containing two isotopes: Oxygen-16 (16 u) with 99.76% abundance and Oxygen-18 (18 u) with 0.20% abundance. What is the approximate relative atomic mass of oxygen in this sample?

<p>16.00 u (A)</p> Signup and view all the answers

What is the primary function of a mass spectrometer?

<p>To determine the types of isotopes present, their exact masses, and their relative amounts in an element. (B)</p> Signup and view all the answers

Which quantum number is most closely related to the energy level of an electron?

<p>The principal quantum number. (C)</p> Signup and view all the answers

An element 'X' has two isotopes: X-20 and X-22. If the relative atomic mass of 'X' is 20.8, which of the following statements must be true regarding the abundance of the isotopes?

<p>X-20 is more abundant than X-22. (A)</p> Signup and view all the answers

What information does the secondary quantum number (l) provide about an electron?

<p>The shape of the electron's orbital. (C)</p> Signup and view all the answers

How many electrons does an element with an atomic number of 26 and a +2 charge possess?

<p>24 (D)</p> Signup and view all the answers

Which scientist discovered that atoms contained smaller particles through experiments with cathode rays, hinting at the existence of electrons?

<p>Michael Faraday (B)</p> Signup and view all the answers

If an electron has a principal quantum number of n=3, what are the possible values for its secondary quantum number (l)?

<p>0, 1, 2 (C)</p> Signup and view all the answers

What does the magnetic quantum number determine?

<p>The orientation of the orbital in space. (A)</p> Signup and view all the answers

Which of the following scientists is credited with discovering the proton through observations using a cathode ray tube?

<p>Eugen Goldstein (C)</p> Signup and view all the answers

Which shape is associated with a p orbital?

<p>Dumbbell (A)</p> Signup and view all the answers

What are the possible values for the spin quantum number?

<p>+1/2 and -1/2 (D)</p> Signup and view all the answers

How many electrons can the first energy level (n=1) hold?

<p>2 (C)</p> Signup and view all the answers

What subshell is defined by the quantum numbers n=5 and l=3?

<p>5f (A)</p> Signup and view all the answers

Which set of $m_l$ values is correct for a d orbital?

<p>-2, -1, 0, +1, +2 (C)</p> Signup and view all the answers

What are the possible values of the azimuthal quantum number (l) for the shell with a principal quantum number n=4?

<p>0, 1, 2, 3 (D)</p> Signup and view all the answers

How many electrons can the n=2 shell hold in total?

<p>8 (D)</p> Signup and view all the answers

According to the Aufbau principle, which orbital will be filled immediately after the 3p orbital?

<p>4s (D)</p> Signup and view all the answers

Which of the following is a consequence of Hund's rule when filling degenerate orbitals?

<p>Electrons will fill each orbital singly before any orbital is doubly occupied. (A)</p> Signup and view all the answers

Which of the following best describes the Pauli Exclusion Principle?

<p>No two electrons in the same atom can have the same set of four quantum numbers. (D)</p> Signup and view all the answers

How many orbitals are present in the f sublevel?

<p>7 (C)</p> Signup and view all the answers

Given the expanded electron configuration $1s^22s^22p^2$, what is the condensed electron configuration?

<p>[He] $2s^22p^2$ (C)</p> Signup and view all the answers

What is the magnetic quantum number ($m_l$) range for an f orbital?

<p>-3 to +3 (C)</p> Signup and view all the answers

For a subshell defined by the quantum numbers n=5 and l=3, what is the designation of this subshell?

<p>5f (D)</p> Signup and view all the answers

Which set of $m_l$ values correctly represents the magnetic quantum numbers for a d orbital?

<p>-2, -1, 0, +1, +2 (A)</p> Signup and view all the answers

What are the allowed values of the azimuthal quantum number (l) for an electron in the shell with a principal quantum number n=4?

<p>0, 1, 2, 3 (D)</p> Signup and view all the answers

A mass spectrometer provides data about an element. Which of the following cannot be directly determined from this data?

<p>The chemical reactivity of each isotope. (D)</p> Signup and view all the answers

Consider an atom with the principal quantum number $n = 3$. How many subshells (defined by the azimuthal quantum number, $l$) are possible?

<p>3 (D)</p> Signup and view all the answers

Which of the following sets of quantum numbers ($n, l, m_l, s$) is not allowed?

<p>$(4, 3, -4, +\frac{1}{2})$ (B)</p> Signup and view all the answers

If an electron is described by the quantum numbers $n=4$ and $l=2$, identify the correct designation and number of orbitals for this electron.

<p>4_d_, 5 orbitals (D)</p> Signup and view all the answers

An atom has a principal quantum number of $n=5$. What is the maximum number of electrons that can occupy this energy level?

<p>50 (D)</p> Signup and view all the answers

How does the magnetic quantum number ($m_l$) relate to the p orbitals?

<p>It defines the orientation of <em>p</em> orbitals in space. (D)</p> Signup and view all the answers

What is the shape of an atomic orbital when the azimuthal quantum number ($l$) is equal to 0?

<p>Spherical (A)</p> Signup and view all the answers

If the spin quantum number of one electron in an orbital is $+\frac{1}{2}$, what is the spin quantum number of the other electron occupying that orbital?

<p>$-\frac{1}{2}$ (B)</p> Signup and view all the answers

Which quantum number primarily dictates the energy level of an electron in a hydrogen atom?

<p>Principal quantum number (n) (C)</p> Signup and view all the answers

Which of the following best describes the role of the magnetic quantum number in defining the characteristics of an electron in an atom:

<p>It specifies the orientation in space of an electron's orbital. (A)</p> Signup and view all the answers

A newly discovered element 'Q' is found to have three isotopes: Q-246, Q-248, and Q-250. If the relative abundance of these isotopes are 65%, 25%, and 10% respectively, what is the relative atomic mass of element 'Q'?

<p>247.4 (C)</p> Signup and view all the answers

Which of the following statements regarding the movement of cathode rays in a gas discharge tube is most accurate, based on the historical context of their discovery?

<p>Cathode rays originate at the negative electrode and are attracted towards the positive electrode. (C)</p> Signup and view all the answers

Consider a neutral atom of element X with an atomic number of 35 and a mass number of 80. If this atom loses two electrons to form a +2 ion, how many protons, neutrons, and electrons does the resulting ion contain?

<p>35 protons, 45 neutrons, and 33 electrons (C)</p> Signup and view all the answers

Element X has two isotopes: X-28 and X-30. Isotope X-28 has a relative abundance of 80%, and isotope X-30 has a relative abundance of 20%. A sample of element X is ionized in a mass spectrometer. What would be the ratio of the ion current for X-28 to X-30?

<p>4:1 (D)</p> Signup and view all the answers

An atom of a certain element has 20 protons, 20 neutrons, and 20 electrons. Which of the following changes would result in creating an isotope of this element?

<p>Adding two neutrons to the nucleus. (D)</p> Signup and view all the answers

Consider two elements, A and B. Element A has 15 protons and 16 neutrons, while element B has 16 protons and 15 neutrons. Which of the following correctly describes the relationship between elements A and B?

<p>A and B are isobars. (B)</p> Signup and view all the answers

An atom has a mass number of 234 and contains 142 neutrons. Which of the following correctly identifies the number of protons and the element?

<p>92 protons, Uranium (U) (C)</p> Signup and view all the answers

Imagine that scientists discover a new element and name it Sahagunium (Sg). They find that Sahagunium has three isotopes: Sg-300 (50% abundance), Sg-302 (30% abundance), and Sg-304 (20% abundance). What is the relative atomic mass of Sahagunium?

<p>301.6 (B)</p> Signup and view all the answers

How did Michael Faraday's experiments contribute to the development of atomic theory?

<p>Faraday's work suggested that atoms contained smaller charged particles. (D)</p> Signup and view all the answers

Consider an ion $^{56}Fe^{2+}$. How many protons and neutrons are present in this ion?

<p>26 protons and 30 neutrons (C)</p> Signup and view all the answers

For a quantum number n=4, what is the designation of the subshell when l=2?

<p>4d (B)</p> Signup and view all the answers

What is the subshell designation for the quantum numbers n=5 and l=3?

<p>5f (C)</p> Signup and view all the answers

Which of the following sets of $m_l$ values correctly represents the magnetic quantum numbers for a d orbital?

<p>-2, -1, 0, +1, +2 (B)</p> Signup and view all the answers

What is the range of magnetic quantum number values ($m_l$) for an f orbital?

<p>-3, -2, -1, 0, 1, 2, 3 (B)</p> Signup and view all the answers

What are the possible values of the azimuthal quantum number (l) for an electron in the shell with a principal quantum number n=4?

<p>0, 1, 2, 3 (D)</p> Signup and view all the answers

How many electrons can the n=2 shell hold?

<p>8 (C)</p> Signup and view all the answers

According to the Aufbau principle, which of the following orbitals will fill immediately after the 2p orbital?

<p>3s (B)</p> Signup and view all the answers

Considering the historical development of atomic theory, which finding presented the most significant challenge to Dalton's initial model of the atom as an indivisible sphere?

<p>Thomson's discovery of the electron as a subatomic particle with a negative charge. (C)</p> Signup and view all the answers

If a neutral atom of an element has an atomic mass of 23 and contains 11 protons, how many neutrons are present in its nucleus, and what is the element?

<p>12 neutrons, Sodium (Na). (A)</p> Signup and view all the answers

Two atoms are considered to be isotopes if they have the same number of...

<p>protons but a different number of neutrons. (A)</p> Signup and view all the answers

What limitation does the magnetic quantum number impose on the distribution of electrons within a subshell?

<p>It confines electrons to specific spatial orientations within the subshell's orbitals. (A)</p> Signup and view all the answers

Two different atoms have the same mass number but different atomic numbers. What is the relationship between these two atoms?

<p>They are isobars. (A)</p> Signup and view all the answers

Imagine a newly discovered element, Element X, which has two stable isotopes: X-200 (with an abundance of 60%) and X-204 (with an abundance of 40%). What is the relative atomic mass of Element X?

<p>201.6 u (C)</p> Signup and view all the answers

Given that the relative atomic mass of an element is determined using a mass spectrometer, how would an error in the spectrometer's magnetic field strength most likely affect the results?

<p>It would cause inaccurate separation and detection of isotopes by mass. (D)</p> Signup and view all the answers

If a newly synthesized element is found to have a relative atomic mass significantly different from what was predicted based on the sum of its constituent protons and neutrons, what is the most likely explanation?

<p>The element contains a significant proportion of isotopes with very different neutron numbers. (D)</p> Signup and view all the answers

Which of the following is an accurate comparison of mass and charge between a proton, neutron and electron?

<p>Electron is negligible in mass compared to proton and neutron; proton and electron have equal, but opposite, charges. (B)</p> Signup and view all the answers

Suppose an atom has its principal quantum number changed from n=2 to n=4. What is the consequence of this change?

<p>The average distance of its electrons from the nucleus will increase, and so will its energy. (C)</p> Signup and view all the answers

Given the discovery of isotopes, which of Dalton's original postulates of atomic theory requires the most significant revision?

<p>Atoms of a given element are identical in size, mass, and other properties. (C)</p> Signup and view all the answers

How did Michael Faraday's work contribute to the development of atomic theory?

<p>Showed chemical reactions occur when electricity is passed through solutions: hint that atoms contained smaller particles. (A)</p> Signup and view all the answers

Which of the following scenarios would result in the creation of ions with different mass-to-charge ratios in a mass spectrometer, assuming all other variables remain constant?

<p>Introducing isotopes of the same element (C)</p> Signup and view all the answers

For an electron in an atom, how does the secondary quantum number (l) influence its probability distribution?

<p>It defines the three-dimensional shape of the orbital which influences the electron's spatial probability. It doesn't account for the spin. (D)</p> Signup and view all the answers

If cathode rays are passed through an electric field, how do they behave and what does this indicate about their composition?

<p>They are deflected towards the positive pole, proving they are made of negatively charged particles. (C)</p> Signup and view all the answers

If a hypothetical atom is found to violate the relationship between the principal quantum number (n) and the number of orbitals at that level, what would be the most likely implication?

<p>The fundamental laws of quantum mechanics as we understand them are incomplete. (D)</p> Signup and view all the answers

An atom of Cobalt (Co) has an atomic number of 27. If a particular isotope of Cobalt has 14 neutrons, what is the atomic mass of this isotope?

<p>41 (D)</p> Signup and view all the answers

A researcher discovers an atom with an unusual electron configuration, where two electrons in the same orbital have identical spin quantum numbers. What fundamental principle of quantum mechanics does this violate?

<p>The Pauli Exclusion Principle (D)</p> Signup and view all the answers

In a mass spectrometry experiment, what adjustment to the instrument would be required to accurately measure the mass-to-charge ratio of very heavy, highly charged ions?

<p>Increase the accelerating voltage and/or magnetic field strength (D)</p> Signup and view all the answers

Consider an atom in its ground state. If an electron transitions from the n=3 energy level to the n=5 energy level, what can be said about the energy change and the wavelength of the light involved?

<p>Energy is absorbed, and the wavelength of light is longer. (B)</p> Signup and view all the answers

For a subshell defined by the quantum numbers n=5 and l=3, what is the maximum number of electrons that can be accommodated?

<p>14 (D)</p> Signup and view all the answers

Consider an atom with the electron configuration $1s^22s^22p^63s^23p^64s^23d^5$. According to Hund's rule, what is the expected number of unpaired electrons in the 3d subshell?

<p>5 (D)</p> Signup and view all the answers

If an element has the condensed electron configuration $[Ar]4s^23d^{10}4p^3$, how many unpaired electrons does it have in its ground state?

<p>3 (D)</p> Signup and view all the answers

Which of the following electron configurations violates Hund's rule for the ground state of an atom?

<p>$1s^22s^22p_x^22p_y^02p_z^0$ (B)</p> Signup and view all the answers

An atom has a valence electron configuration of $ns^2np^4$. How many unpaired electrons are present in this atom's ground state?

<p>2 (C)</p> Signup and view all the answers

An element has the electron configuration $[Kr]5s^24d^{10}5p^2$. What are the possible values of the magnetic quantum number ($m_l$) for the outermost p electrons?

<p>-1, 0, +1 (B)</p> Signup and view all the answers

What set of quantum numbers (n, l, $m_l$) could describe an electron in a 4d orbital?

<p>(4, 2, -2) (B)</p> Signup and view all the answers

Given the historical timeline of subatomic particle discovery, which sequence correctly orders the scientists from earliest to latest discovery?

<p>Thomson, Rutherford, Chadwick (C)</p> Signup and view all the answers

Which of the following electron configurations represents an element in an excited state?

<p>$1s^22s^22p^63s^23p^64s^13d^5$ (B)</p> Signup and view all the answers

Consider an element 'X' that has two isotopes: X-28 and X-30. If the relative atomic mass of 'X' is closer to 28, which of the following can be logically inferred?

<p>The abundance of X-28 is greater than the abundance of X-30. (A)</p> Signup and view all the answers

If the value of the principal quantum number (n) is 3, what is the total number of orbitals possible?

<p>9 (B)</p> Signup and view all the answers

An atom of Cobalt (Co) has an atomic number of 27. If a particular isotope of Cobalt has 33 neutrons, what is the mass number of this isotope?

<p>60 (D)</p> Signup and view all the answers

What is the maximum number of electrons that can occupy a p subshell with a principal quantum number of n = 6?

<p>6 (B)</p> Signup and view all the answers

How did William Crookes' experiments with cathode ray tubes contribute to the understanding of atomic structure?

<p>They provided evidence for the existence of negatively charged particles within atoms. (D)</p> Signup and view all the answers

Suppose a new element, 'El', is synthesized. It has two stable isotopes: El-120 (80% abundance) and El-124 (20% abundance). A research team incorrectly calculates the relative atomic mass using a simple average instead of a weighted average. What type of error will result from this incorrect calculation?

<p>The calculated mass will be lower than the true relative atomic mass. (C)</p> Signup and view all the answers

If an element has an atomic number of 47, how many protons and electrons does a neutral atom of that element contain respectively?

<p>47 protons and 47 electrons (D)</p> Signup and view all the answers

Given the discovery of isotopes for a single element, which of Dalton's original postulates of atomic theory is directly challenged, and how is it revised in modern atomic theory?

<p>All atoms of a given element are identical in mass and properties; revised to acknowledge the existence of isotopes. (D)</p> Signup and view all the answers

Element Q has two isotopes: Q-200 and Q-204. A mass spectrometer analysis reveals that the ratio of the ion current for Q-200 to Q-204 is 3:1. What is the relative atomic mass of element Q?

<p>201 (A)</p> Signup and view all the answers

An ion has 26 protons, 30 neutrons, and 24 electrons. What is the charge and mass number of this ion?

<p>+2 charge, mass number 56 (C)</p> Signup and view all the answers

Which experimental finding by Michael Faraday provided initial evidence against Dalton's idea of indivisible atoms?

<p>The observation that passing electricity through certain chemical solutions caused chemical reactions which showed the atoms contained smaller particles (C)</p> Signup and view all the answers

An element's isotopes are analyzed using a mass spectrometer. Which adjustment to the spectrometer would be most crucial for accurately distinguishing between isotopes with very similar masses?

<p>Increasing the magnetic field strength to enhance ion separation. (D)</p> Signup and view all the answers

Consider an atom in an excited state with the electron configuration deviating from the Aufbau principle. Which of the following scenarios would lead to the emission of a photon with the highest energy as the electron returns to the ground state?

<p>An electron transitioning from n=6 to n=1. (A)</p> Signup and view all the answers

If an atom is found to have an electron with the quantum numbers n = 3, l = 2, $m_l$ = -2, and s = +1/2, and this electron is removed to form an ion, from which subshell was the electron removed?

<p>3d (A)</p> Signup and view all the answers

In a hypothetical universe, the spin quantum number (s) could have three possible values: -1, 0, and +1. Assuming all other quantum mechanical rules remain the same, what is the maximum number of electrons that could occupy a single orbital in this universe?

<p>3 (B)</p> Signup and view all the answers

How does the shape of an atomic orbital, as defined by the azimuthal quantum number (l), influence the types of chemical bonds an atom is likely to form?

<p>The spatial orientation of orbitals influences the directionality and overlap of electron clouds, affecting the geometry and strength of covalent bonds. (D)</p> Signup and view all the answers

Given the presence of an element with partially filled d orbitals, which statement correctly describes the implications for its chemical behavior?

<p>The variable oxidation states and catalytic properties result from the accessible <em>d</em> electrons. (B)</p> Signup and view all the answers

Consider an atom with the electron configuration [Ar] 4s² 3d⁵. Which of the following electronic transitions would result in the absorption of a photon with the shortest wavelength?

<p>An electron moving from the 3d orbital to a higher energy 4d orbital. (C)</p> Signup and view all the answers

Suppose a new element 'X' is discovered and its atoms are found to violate the Pauli Exclusion Principle. What would be the most likely consequence for the macroscopic properties of materials made from element 'X'?

<p>Materials made of 'X' would exhibit novel and unpredictable electrical and magnetic properties. (D)</p> Signup and view all the answers

Consider an atom that absorbs a photon of a specific wavelength, causing an electron to jump from the 2p orbital to a higher energy orbital. Which statement accurately describes the change in the quantum numbers of the electron?

<p>The principal quantum number (n) increases, and the azimuthal quantum number (l) may increase or stay the same. (B)</p> Signup and view all the answers

Suppose an atom's electron configuration is modified such that all of its electrons have the same spin quantum number. What would be the most immediate consequence of this change?

<p>The atom would violate the Pauli Exclusion Principle and collapse. (B)</p> Signup and view all the answers

For an electron described by the quantum numbers n=5, l=2, how many possible orientations (defined by $m_l$ values) does this orbital have in space?

<p>5 (B)</p> Signup and view all the answers

Consider a hypothetical atom with the electron configuration $1s^22s^22p^63s^23p^64s^23d^{10}4p^65s^1$. If this atom were to lose one electron to form a +1 ion, from which orbital would the electron most likely be removed?

<p>5s (D)</p> Signup and view all the answers

An electron in a multi-electron atom is described by the quantum numbers n = 4 and l = 1. Which of the following statements accurately describes the characteristics of this electron?

<p>It resides in a dumbbell-shaped orbital with three possible orientations. (B)</p> Signup and view all the answers

Consider an atom that has completely filled its n=1 and n=2 electron shells. How many electrons does this atom possess?

<p>10 (B)</p> Signup and view all the answers

For an electron in a hydrogen atom, which transition between energy levels would result in the emission of the highest energy photon?

<p>n = 2 to n = 1 (B)</p> Signup and view all the answers

Two electrons within the same atom both have n=3 and l=1. Which of the following quantum numbers MUST be different between these two electrons, according to the Pauli Exclusion Principle?

<p>Either $m_l$ or $m_s$ (D)</p> Signup and view all the answers

Consider a hypothetical element with a partially filled 3d subshell containing 6 electrons. According to Hund's rule, how many unpaired electrons would you expect this element to have in its 3d subshell?

<p>4 (B)</p> Signup and view all the answers

How does the energy difference between successive energy levels (n=1, n=2, n=3, etc.) in a hydrogen atom change as n increases?

<p>The energy difference decreases. (A)</p> Signup and view all the answers

If an electron is added to an atom and has a spin quantum number ($m_s$) of +1/2, what can be definitively stated about the electron that already occupied the same orbital before the addition?

<p>Its spin quantum number ($m_s$) was -1/2. (B)</p> Signup and view all the answers

Which of the following situations violates the Aufbau principle?

<p>Filling the 4s orbital after the 3d orbital. (B)</p> Signup and view all the answers

How does Hund's rule primarily influence the filling of degenerate orbitals within an atom?

<p>It specifies that electrons will fill each orbital singly before any orbital is doubly occupied, maximizing total spin. (D)</p> Signup and view all the answers

Which electronic configuration notation accurately represents the element vanadium (V), given its atomic number is 23?

<p>1s² 2s² 2p⁶ 3s² 3p⁶ 4s² 3d³ (B)</p> Signup and view all the answers

How does the presence of unpaired electrons in an atom influence its interaction with an external magnetic field?

<p>Atoms with unpaired electrons exhibit paramagnetism and are attracted to magnetic fields. (B)</p> Signup and view all the answers

Considering an element with the electron configuration [Ar] 4s² 3d⁴, what adjustment to the configuration results in a more stable state, and what is the general principle behind this change?

<p>Change to [Ar] 4s¹ 3d⁵, achieving a half-filled d subshell which increases stability. (B)</p> Signup and view all the answers

Which set of quantum numbers ($n, l, m_l, s$) defines the last electron added to complete the ground state electron configuration of oxygen (O), which has eight electrons?

<p>$(2, 1, -1, +\frac{1}{2})$ (A)</p> Signup and view all the answers

How does the Aufbau principle guide the process of writing electron configurations for elements?

<p>It states that electrons fill orbitals in order of increasing energy, starting with the lowest energy levels. (B)</p> Signup and view all the answers

What is the correct shorthand electron configuration for iron (Fe), given that it has an atomic number of 26?

<p>[Ar] 4s² 3d⁶ (D)</p> Signup and view all the answers

For an element with a ground state electron configuration ending in $4p^4$, determine its magnetic properties and valence electron count.

<p>Paramagnetic with 6 valence electrons (A)</p> Signup and view all the answers

How would you represent the ground state electron configuration of copper (Cu), element number 29, using shorthand notation, taking into account its known exception to Hund's rule?

<p>[Ar] 4s¹ 3d¹⁰ (B)</p> Signup and view all the answers

Which of the following orbital diagrams accurately represents the ground state electron configuration for nitrogen (N), element number 7, according to Hund's rule?

<p>↑↓ ↑ ↑ ↑ (C)</p> Signup and view all the answers

Which quantum number primarily determines the spatial orientation of an electron's orbital within an atom?

<p>Magnetic quantum number ($m_l$) (C)</p> Signup and view all the answers

Considering the Pauli Exclusion Principle, which of the following sets of quantum numbers could describe two electrons occupying the same atomic orbital?

<p>n=1, l=0, $m_l$=0, $m_s$=+1/2 and n=1, l=0, $m_l$=0, $m_s$=-1/2 (A)</p> Signup and view all the answers

If an atom has an electron with the quantum numbers n=4 and l=2, which subshell does this electron belong to, and how many orbitals are within this subshell?

<p>4d, 5 orbitals (C)</p> Signup and view all the answers

Which of the following statements accurately describes the relationship between the principal quantum number (n) and the energy of an electron?

<p>As 'n' increases, the energy of the electron increases, and it is further from the nucleus. (D)</p> Signup and view all the answers

How does the angular momentum quantum number (l) influence the shape of an atomic orbital?

<p><em>l</em> defines the three-dimensional shape of the orbital, such as spherical, dumbbell, or more complex forms. (C)</p> Signup and view all the answers

Within the n=3 energy level, what is the total number of orbitals available, considering all possible values of l and $m_l$?

<p>9 (A)</p> Signup and view all the answers

Considering the Aufbau principle, which orbital is expected to be filled immediately before the 4d orbitals?

<p>5s (A)</p> Signup and view all the answers

How does the spin quantum number ($m_s$) influence the electron occupancy within a single atomic orbital?

<p>It allows for two electrons with opposite spins (+1/2 and -1/2) to occupy the same orbital. (C)</p> Signup and view all the answers

Which of the following designations of quantum numbers (n, l, $m_l$) is permissible?

<p>n = 3, l = 1, $m_l$ = -1 (D)</p> Signup and view all the answers

If an electron is described by the quantum numbers n = 3, l = 2, $m_l$ = -1, and $m_s$ = +1/2, which of the following best describes the electron's state??

<p>It is a 3d electron in a specific orbital with spin up. (B)</p> Signup and view all the answers

How does the potential energy of an electron change as its orbital moves further from the nucleus?

<p>The potential energy increases exponentially with the distance from the nucleus. (A)</p> Signup and view all the answers

Which of the following electron configurations represents an atom in its excited state?

<p>1s² 2s² 2p⁶ 3s² 3p⁴ 4s¹ (C)</p> Signup and view all the answers

According to Hund's rule, which electron configuration for a carbon atom ($2p^2$) is the most stable in the ground state?

<p>↑ ↑ _ (C)</p> Signup and view all the answers

Which element is represented by the noble gas notation [Kr] 5s² 4d¹⁰ 5p³?

<p>Antimony (Sb) (B)</p> Signup and view all the answers

Which of the following atoms would be classified as paramagnetic?

<p>Nitrogen (N) (B)</p> Signup and view all the answers

How does the presence of unpaired electrons affect atomic properties?

<p>It makes the atom paramagnetic, attracting it to magnetic fields. (A)</p> Signup and view all the answers

Consider an element with the electron configuration [Ar] 4s² 3d⁵. Which block of the periodic table does this element belong to?

<p>d-block (C)</p> Signup and view all the answers

Which electron configuration violates Hund's rule for the ground state of an atom?

<p>$2p_x^2 2p_y^0 2p_z^0$ (C)</p> Signup and view all the answers

How does the filling of electron orbitals explain the chemical properties of elements in the same group?

<p>Elements in the same group have similar valence electron configurations, resulting in similar chemical properties. (B)</p> Signup and view all the answers

Why is it important to consider both electron configuration and orbital diagrams when predicting an element's magnetic properties?

<p>Electron configurations only show the total number of electrons, failing to indicate how they are distributed within orbitals, which is crucial for determining magnetic properties. (C)</p> Signup and view all the answers

Flashcards

J.J. Thomson

Discovered electrons in 1897. Used cathode ray tubes.

Ernest Rutherford

Discovered protons in 1919. Experimented with alpha particles and gold foil.

James Chadwick

Discovered neutrons in 1932. Worked with Beryllium radiation.

Michael Faraday's Contribution

Showed that chemical reactions occur during the electricity flowthrough certain chemical solutions.

Signup and view all the flashcards

William Crookes' Experiment

Passed High voltage through gas discharged tube, cathode rays move from the negative electrode (cathode) to the posteive electrode( anode).

Signup and view all the flashcards

Roentgen's Discovery

Discovered X-rays

Signup and view all the flashcards

Eugen Goldstein

Discovered protons using a cathode ray tube. Rays traveled opposite to cathode rays.

Signup and view all the flashcards

Atomic Number

Number of protons in the nucleus of an atom.

Signup and view all the flashcards

Atomic Mass Number

Total number of protons and neutrons in an atom's nucleus.

Signup and view all the flashcards

Relative Atomic Mass

The average mass of an element's atoms, considering the relative abundance of isotopes.

Signup and view all the flashcards

Mass Spectrometer

Determines the types of isotopes, their exact masses, and their relative abundance in an element.

Signup and view all the flashcards

Electron Shells & Subshells

Space around the nucleus divided into shells (main energy levels) and subshells (sublevels).

Signup and view all the flashcards

Principal Quantum Number (n)

Indicates the size and energy level of an orbital.

Signup and view all the flashcards

Secondary Quantum Number (l)

Defines the shape of the orbital (sublevels/subshells).

Signup and view all the flashcards

Magnetic Quantum Number

Specifies the orientation of the orbital in space.

Signup and view all the flashcards

Spin Quantum Number

Describes the spin of the electron (+1/2 or -1/2).

Signup and view all the flashcards

Electron Capacity per Energy Level

The maximum number of electrons allowed in a single energy level.

Signup and view all the flashcards

Orbital Shapes (s, p, d)

s = spherical, p = dumbbell, d = four-lobe shape.

Signup and view all the flashcards

Magnetic Quantum Number Function

Splits subshells into individual orbitals, placing electrons.

Signup and view all the flashcards

Electron Spin

Describes the spin of an electron about its own axis.

Signup and view all the flashcards

What is the 4d subshell?

The subshell with quantum numbers n=4 and l=2.

Signup and view all the flashcards

What is the 5f subshell?

The subshell with quantum numbers n=5 and l=3.

Signup and view all the flashcards

What are the magnetic values for a d orbital?

The magnetic quantum number (ml) values for a d orbital are -2, -1, 0, +1, +2.

Signup and view all the flashcards

What are the magnetic values for a f orbital?

The magnetic quantum number (ml) values for an f orbital are -3, -2, -1, 0, +1, +2, +3.

Signup and view all the flashcards

Allowed l values for n=2

For the shell with n=2, the allowed values of l are 0 and 1 (s and p orbitals).

Signup and view all the flashcards

Allowed l values for n=4

For the shell with n=4, the allowed values of l are 0, 1, 2, and 3 (s, p, d, and f orbitals).

Signup and view all the flashcards

Electron capacity of n=4 orbitals

All of the n=4 orbitals can hold a maximum of 32 electrons.

Signup and view all the flashcards

Electron capacity of n=2 orbitals

All of the n=2 orbitals can hold a maximum of 8 electrons.

Signup and view all the flashcards

Aufbau principle

Electrons first occupy the lowest-energy orbitals available in the ground state of an atom.

Signup and view all the flashcards

Pauli Exclusion Principle

No two electrons can have the same quantum state simultaneously.

Signup and view all the flashcards

Electron

A subatomic particle with a negative charge and negligible mass, orbiting the nucleus.

Signup and view all the flashcards

Proton

A subatomic particle with a positive charge, located in the nucleus.

Signup and view all the flashcards

Neutron

A subatomic particle with no charge (neutral), located in the nucleus.

Signup and view all the flashcards

Atomic Mass

Total number of protons and neutrons in an atom's nucleus.

Signup and view all the flashcards

Isotopes

Atoms of the same element with different numbers of neutrons.

Signup and view all the flashcards

Isobars

Atoms with same mass number but different atomic number.

Signup and view all the flashcards

Isotones

Atoms with the same number of neutrons but different number of protons.

Signup and view all the flashcards

Electronic Configuration

Arrangement of electrons in the energy levels and sublevels within an atom.

Signup and view all the flashcards

Electron Shell

The main energy levels around the nucleus where electrons reside.

Signup and view all the flashcards

Subshells

The sublevels within the main energy levels, denoted by letters like s, p, d, and f.

Signup and view all the flashcards

Shape of s orbital

The s orbital has a spherical shape.

Signup and view all the flashcards

Shape of p orbital

The p orbital has a dumbbell shape.

Signup and view all the flashcards

Electron capacity of N=1

The maximum number of electrons allowed in the first energy level (n=1).

Signup and view all the flashcards

Electron capacity of N=3

The maximum number of electrons allowed in the third energy level (n=3).

Signup and view all the flashcards

Hund's Rule

For degenerate orbitals, electrons fill each orbital singly before pairing up.

Signup and view all the flashcards

Condensed Electron Configuration

A notation shortening the full electron configuration by using the previous noble gas configuration.

Signup and view all the flashcards

Rectangular Arrow Method

A way of visualizing electron configuration using boxes to represent orbitals and arrows to represent electrons.

Signup and view all the flashcards

Element Chart

A chart showing the number of protons, electrons, and neutrons in an atom.

Signup and view all the flashcards

S Sublevel Boxes

S subshells has 1 box.

Signup and view all the flashcards

P Sublevel Boxes

P subshells has 3 box.

Signup and view all the flashcards

D Sublevel Boxes

D subshells has 5 box.

Signup and view all the flashcards

F Sublevel Boxes

F subshells has 7 box.

Signup and view all the flashcards

S Sublevel Arrows

S subshells has max 2 arrows.

Signup and view all the flashcards

P Sublevel Arrows

P subshells has max 6 arrows.

Signup and view all the flashcards

Magnetic Quantum Number (ml)

Specifies the orientation of the orbital in space.

Signup and view all the flashcards

Spin Quantum Number (ms)

Describes the intrinsic angular momentum of an electron which is quantized.

Signup and view all the flashcards

Michael Faraday

Showed chemical reactions occur when electricity passes through chemical solutions, suggesting atoms contain smaller charged particles.

Signup and view all the flashcards

William Crookes

Showed that cathode rays move from the negative electrode (cathode) to the positive electrode (anode) in a vacuum tube.

Signup and view all the flashcards

Roentgen

Discovered X-rays.

Signup and view all the flashcards

Electron (e-)

A subatomic particle with a charge of -1 and negligible mass.

Signup and view all the flashcards

Proton (p+)

A subatomic particle with a charge of +1 and a mass of approximately 1 u.

Signup and view all the flashcards

Neutron (n)

A subatomic particle with no charge (neutral) and a mass of approximately 1 u.

Signup and view all the flashcards

Condensed Configuration

A short way to write out an element's electron configuration.

Signup and view all the flashcards

S Sublevel Max Arrows

s subshells has max 2 arrows.

Signup and view all the flashcards

P Sublevel Max Arrows

P subshells has max 6 arrows.

Signup and view all the flashcards

Orbital Diagram

Visual aid that shows electron occupancy in each orbital.

Signup and view all the flashcards

Atomic Orbital

A region of space around the nucleus where an electron is likely to be found.

Signup and view all the flashcards

Mass Spectrometer Use

Determines the types of isotopes present, their exact masses, and their relative abundance in an element

Signup and view all the flashcards

Electron Organization

The main energy levels (shells) and sublevels (subshells) around the nucleus where electrons reside.

Signup and view all the flashcards

S Sublevel: Number of Boxes

s subshells has a 1 box.

Signup and view all the flashcards

P Sublevel: Number of Boxes

p subshells have 3 boxes.

Signup and view all the flashcards

D Sublevel: Number of Boxes

d subshells has 5 box.

Signup and view all the flashcards

F Sublevel: Number of Boxes

f subshells has 7 box.

Signup and view all the flashcards

الأعداد الكمية

تصف أربعة أعداد كمية موقع وطاقة الإلكترون داخل الذرة، وتحدد مدارات ذرية مختلفة.

Signup and view all the flashcards

المدار الذري

المنطقة ثلاثية الأبعاد حول النواة حيث يكون احتمال وجود الإلكترون فيها هو الأعلى.

Signup and view all the flashcards

أنواع المدارات الذرية (s, p, d, f)

S (كروي)، p (فصي)، d (أشكال معقدة)، f (أكثر تعقيدًا). لكل منها أشكال واتجاهات مختلفة في الفضاء.

Signup and view all the flashcards

سعة المدار الإلكترونية

يمكن لكل مدار ذري أن يستوعب إلكترونين كحد أقصى.

Signup and view all the flashcards

عدد الكم الرئيسي (n)

عدد صحيح موجب يحدد مستوى الطاقة الرئيسي للإلكترون. كلما زادت قيمته، ابتعد المدار عن النواة وزادت طاقته.

Signup and view all the flashcards

عدد الكم الزخم الزاوي (l)

يحدد شكل المدار الذري. تتراوح قيمه من 0 إلى n-1. (l=0 مدار s, l=1 مدار p, إلخ.)

Signup and view all the flashcards

العدد الكمي المغناطيسي (ml)

يحدد عدد المدارات ذات الطاقة المتساوية المتاحة ضمن مستوى طاقة فرعي معين. تتراوح قيمه من -l إلى +l.

Signup and view all the flashcards

قيم (l) الممكنة عندما (n = 3)?

إذا كانت قيمة n = 3، فإن قيم l الممكنة هي 0 و 1 و 2.

Signup and view all the flashcards

قيم (ml) الممكنة عندما (l = 2)?

إذا كانت قيمة l = 2 ، فإن قيم ml الممكنة هي -2 و -1 و 0 و +1 و +2.

Signup and view all the flashcards

Quantum Numbers

Numbers that define the state of an electron, including its energy and location.

Signup and view all the flashcards

Angular Momentum Quantum Number (l)

The second quantum number, that determines the shape of the orbital (s, p, d, f).

Signup and view all the flashcards

Shape of l=0 orbital

s orbitals are spherical.

Signup and view all the flashcards

Shape of l=1 orbital

p orbitals have a dumbbell shape, aligned on three axes.

Signup and view all the flashcards

Filling Order of Orbitals

The order in which electron orbitals are filled, starting with the lowest energy levels.

Signup and view all the flashcards

Shorthand Notation

Uses the preceding noble gas symbol in brackets to represent core electrons.

Signup and view all the flashcards

Paramagnetic Atoms

Atoms with unpaired electrons, attracted to magnetic fields.

Signup and view all the flashcards

Diamagnetic Atoms

Atoms with all electrons paired, not affected by magnetic fields.

Signup and view all the flashcards

Azimuthal Quantum Number (l)

Indicates the shape of the electron's orbital (s, p, d, f).

Signup and view all the flashcards

Magnetic Quantum Number (m sub l)

Indicates the spatial orientation of an electron's orbital.

Signup and view all the flashcards

Spin Quantum Number (m sub s)

Describes the intrinsic angular momentum of an electron. ( +1/2 or -1/2)

Signup and view all the flashcards

Quantum Numbers for 1s Orbital

n=1, l=0, ml=0

Signup and view all the flashcards

Quantum Numbers for 2s and 2p Orbitals

n=2, l=0 and n=2, l=1

Signup and view all the flashcards

Orbital Energy Levels

Orbitals farther from the nucleus have greater potential energy.

Signup and view all the flashcards

Electron Filling Order

The sequence in which electron orbitals are populated with electrons.

Signup and view all the flashcards

'n' Value

Indicates the energy level of the orbital (e.g., 1, 2, 3...).

Signup and view all the flashcards

Superscript in Configuration

The number of electrons occupying a specific type of orbital.

Signup and view all the flashcards

Periodic Table Blocks

Sections of the periodic table relating to the filling of specific orbitals.

Signup and view all the flashcards

Noble Gas Abbreviation

Represent electron configurations using the previous noble gas in brackets.

Signup and view all the flashcards

Paramagnetic

Atoms with unpaired electrons that are attracted to magnetic fields.

Signup and view all the flashcards

Diamagnetic

Atoms where all electrons are paired, and not affected by magnetic fields.

Signup and view all the flashcards

Study Notes

Rectangular Arrow Method

  • Used to understand how electrons are configured in each orbital
  • S sublevel uses only 1 box and there are 2 max arrows
  • P sublevel uses 3 boxes and there are 6 max arrows
  • D sublevel uses 5 boxes and there are 10 max arrows
  • F sublevel uses 7 boxes and 14 max arrows
  • It is "correct" with 1 electron in the p sublevel as it can be either "spin-up" or "spin-down"
  • It is "incorrect" as the spin of the 2nd electron depends on the spin of the 1st electron, even though they aren't in the same orbital"
  • It is "correct", as long as the first electron in each orbital is drawn as "spin-up", you will draw a correct orbital diagram

Examples of Figuring Electrons in Atoms

1s 2s 2p Expanded Condensed
H 1s¹
He ↑↓ 1s²
Li ↑↓ 1s²2s¹
Be ↑↓ ↑↓ 1s²2s²
B ↑↓ ↑↓ 1s²2s²2p¹
C ↑↓ ↑↓ ↑↑ 1s²2s²2p¹2p¹ 1s²2s²2p²
N ↑↓ ↑↓ ↑↑↑ 1s²2s²2p¹2p¹2p¹ 1s²2s²2p³
O ↑↓ ↑↓ ↑↓↑↑ 1s²2s²2p²2p¹2p¹ 1s²2s²2p4
F ↑↓ ↑↓ ↑↓↑↓↑ 1s²2s²2p²2p²2p1 1s²2s²2p5
Ne ↑↓ ↑↓ ↑↓↑↓↑↓ 1s²2s²2p²2p²2p² 1s²2s²2p6
  • n=4
  • n=4, l=3
    • N=1
    • Tell us which sublevel is described by the given
    • N=5, l=3
      • N=4 , l=0

Predicting Electrons

  • Si sharon pumunta sa party si daddy
  • Pumunta sa disco pano si frankie daddy
    • Pano si frankie daddy
      • S: 1s²2s²2p63s²3p4
      • K: 1s²2s²2p63s²3p94s¹
      • Ti: 1s²2s²2p63s²3p 3d24s²
      • Sn: 1s²2s²2p63s²3p 3d104s24p4d105s25p2

Studying That Suits You

Use AI to generate personalized quizzes and flashcards to suit your learning preferences.

Quiz Team

Related Documents

More Like This

Quantum Numbers and Atomic Structure
40 questions

Quantum Numbers and Atomic Structure

FlourishingRetinalite8910 avatar
FlourishingRetinalite8910
Atomic Structure and Properties
15 questions

Atomic Structure and Properties

EncouragingManganese9169 avatar
EncouragingManganese9169
Use Quizgecko on...
Browser
Browser