Atomic Structure and Properties

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Questions and Answers

How did Rutherford's gold foil experiment contribute to our understanding of atomic structure?

  • It proved that electrons exist in fixed orbits around the nucleus.
  • It demonstrated that atoms are indivisible and solid spheres.
  • It revealed that the atom's mass is concentrated in a small, positively charged nucleus. (correct)
  • It confirmed the plum pudding model, showing electrons distributed evenly throughout the atom.

Why is the concept of isotopes important in understanding atomic mass?

  • Isotopes explain why all atoms of an element have the same mass.
  • Isotopes show that the number of electrons can vary within an element.
  • Isotopes account for the average atomic mass being a weighted average of different isotopes. (correct)
  • Isotopes prove that the number of protons and neutrons is always equal.

What is the significance of the principal quantum number ($n$) in describing the properties of an electron in an atom?

  • It specifies the spin of the electron.
  • It defines the orientation of the electron's orbital in space.
  • It determines the shape of the electron's orbital.
  • It primarily determines the energy level of the electron. (correct)

How does the azimuthal quantum number ($l$) relate to the shape of atomic orbitals?

<p>It delineates the three-dimensional shape of the orbital (e.g., s, p, d). (D)</p> Signup and view all the answers

Why does ionization energy generally increase across a period in the periodic table?

<p>The effective nuclear charge increases, holding electrons more tightly. (B)</p> Signup and view all the answers

How does the concept of electronegativity explain the formation of chemical bonds?

<p>It quantifies the ability of an atom to attract electrons in a chemical bond. (B)</p> Signup and view all the answers

Why is understanding electron configuration important for predicting an element's chemical behavior?

<p>It defines the arrangement of electrons, particularly valence electrons, which participate in bonding. (D)</p> Signup and view all the answers

What role does neutron-to-proton ratio play in the stability of a nucleus?

<p>An optimal neutron-to-proton ratio is required to balance the electrostatic repulsion of protons. (C)</p> Signup and view all the answers

How can half-life be used to determine the age of ancient artifacts?

<p>By comparing the remaining amount of a radioactive isotope to its original amount. (C)</p> Signup and view all the answers

In beta decay, a neutron transforms into which of the following?

<p>A proton, an electron, and an antineutrino (C)</p> Signup and view all the answers

Uranium-235 undergoes nuclear fission when bombarded with neutrons. What implications does this process have for nuclear power generation?

<p>It creates a self-sustaining chain reaction, releasing large amounts of energy. (D)</p> Signup and view all the answers

How do elements in the same group (vertical column) of the periodic table generally exhibit similar chemical properties?

<p>They have the same number of valence electrons. (D)</p> Signup and view all the answers

Which subatomic particles contribute significantly to the mass of an atom?

<p>Protons and neutrons (B)</p> Signup and view all the answers

How does the concept of electron shielding affect the effective nuclear charge experienced by valence electrons?

<p>Shielding decreases the effective nuclear charge. (B)</p> Signup and view all the answers

What is the relationship between wavelength and energy of electromagnetic radiation?

<p>Energy is inversely proportional to wavelength. (D)</p> Signup and view all the answers

Flashcards

Electron

Negatively charged subatomic particle.

Proton

Positively charged subatomic particle.

Neutron

Neutrally charged subatomic particle.

Nucleus

Central part of an atom, containing protons and neutrons.

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Plum Pudding Model

J.J. Thomson's model where electrons are scattered within a positive sphere.

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Gold Foil Experiment

Experiment involving alpha particles scattering off gold foil, revealing the nucleus.

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Planetary Model

Atomic model with electrons orbiting the nucleus in fixed paths.

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Atomic Number

Number of protons in an atom's nucleus.

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Mass Number

Total number of protons and neutrons in an atom's nucleus.

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Isotopes

Atoms with the same number of protons but different numbers of neutrons.

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Alpha Particle

A positively charged particle emitted from the nucleus of an atom during radioactive decay, consisting of two protons and two neutrons.

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Principal Quantum Number

Describes the energy level or shell of an electron.

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Azimuthal Quantum Number

Determines the shape of an electron's orbital (s, p, d, f).

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Magnetic Quantum Number

Defines the orientation of an electron's orbital in space.

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Half-Life

Time it takes for half of a radioactive substance to decay.

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Study Notes

Basic Concepts

  • J.J. Thomson discovered the electron.
  • A proton has a charge of +1.
  • A neutron has a neutral charge.
  • The electron is the lightest subatomic particle.
  • Ernest Rutherford discovered the nucleus of the atom.

Atomic Models

  • J.J. Thomson proposed the plum pudding model of the atom.
  • The gold foil experiment led to the discovery of the nucleus.
  • Niels Bohr proposed the planetary model of the atom.
  • Bohr's atomic model is characterized by electrons revolving in fixed orbits.
  • Erwin Schrödinger proposed the quantum mechanical model of the atom.

Atomic Structure and Properties

  • Carbon has an atomic number of 6.
  • An atom with 6 protons and 7 neutrons has a mass number of 13.
  • Isotopes have the same number of protons and electrons.
  • An alpha particle has a +2 charge.
  • Isotopes are atoms with the same atomic number but different mass numbers.

Quantum Numbers & Electron Configuration

  • Four quantum numbers are required to describe an electron.
  • The principal quantum number (n) describes the energy level.
  • The azimuthal quantum number (l) determines the shape of the orbital.
  • The magnetic quantum number (m) defines the orientation of the orbital.
  • The maximum number of electrons in an orbital is 2.
  • Dmitri Mendeleev is the father of the periodic table.
  • Elements in the same group have the same number of valence electrons.
  • Fluorine has the highest electronegativity.
  • Atomic radius decreases across a period due to an increase in nuclear charge.
  • Ionization energy increases across a period because atoms gain more protons.

Radioactivity & Nuclear Chemistry

  • James Chadwick discovered the neutron.
  • Gamma radiation has the highest energy.
  • The half-life of a radioactive substance is the time taken for half of the substance to decay.
  • An electron is emitted in beta decay.
  • Uranium is commonly used in nuclear reactors.

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